KR930008013A - 불포화 폴리에스테르 및 그로부터 제조된, 방향족 화합물/포화 화합물의 분리를 위한 가교결합된 멤브레인 - Google Patents

불포화 폴리에스테르 및 그로부터 제조된, 방향족 화합물/포화 화합물의 분리를 위한 가교결합된 멤브레인 Download PDF

Info

Publication number
KR930008013A
KR930008013A KR1019920018585A KR920018585A KR930008013A KR 930008013 A KR930008013 A KR 930008013A KR 1019920018585 A KR1019920018585 A KR 1019920018585A KR 920018585 A KR920018585 A KR 920018585A KR 930008013 A KR930008013 A KR 930008013A
Authority
KR
South Korea
Prior art keywords
chloride
diol
aromatic
mixtures
group
Prior art date
Application number
KR1019920018585A
Other languages
English (en)
Inventor
살토리 기도
윈스톤 호 윈-소우
에드먼느 누운 로버트
Original Assignee
앤 허쉬코비쯔 제이콥슨
엑손 리써치 앤드 엔지니어링 캄파니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 앤 허쉬코비쯔 제이콥슨, 엑손 리써치 앤드 엔지니어링 캄파니 filed Critical 앤 허쉬코비쯔 제이콥슨
Publication of KR930008013A publication Critical patent/KR930008013A/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/144—Purification; Separation; Use of additives using membranes, e.g. selective permeation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/48—Polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

불포화 폴리에스테르 및 그로부터 제조된, 방향족 화합물/포화 화합물의 분리를 위한 가교결합된 멤브레인 본 발명은 불포화 지방족 폴리에스테르의 합성 방법, 열 처리에 의한 이들의 가교결합 및 포화 화합물로부터 방향족 화합물을 분리시키기 위한 상응하는 가교결합된 멤브레인의 용도를 개시한다.

Description

불포화 폴리에스테르 및 그로부터 제조된, 방향족 화합물/포화 화합물의 분리를 위한 가교결합된 멤브레인
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 폴리고머성 폴리에스테르 디올과 불포화 이산 클로라이드를 반응시킴을 포함하는 불포화 지방족 폴리에스테르의 합성 방법.
  2. 제1항에 있어서, 상기 반응을 트리에틸아민, 트리에틸렌 디아민, 피리딘 및 이들의 혼합물로 이루어진 그룹으로부터 선택된 3급 아민의 존재하에서 수행하는 방법.
  3. 제1항에 있어서, 상기 반응을 클로로포름, 1,2-디클로로에탄, 염화메틸렌, 벤젠, 톨루앤, 크실렌 및 클로로벤젠, 및 이들의 혼합물로 이루어진 그룹으로부터 선택된 용매의 존지하에서 수행하는 방법.
  4. 제1항에 있어서, 상기 폴리에스테르 디올이 폴리에틸렌아디페이트디올, 폴리에틸렌숙시네이트디올, 폴리말로네이트디올, 폴리 옥살레이트디올, 폴리글루타레이트디올 및 이들의 혼합물로 이루어진 그룹으로부터 선택되는 방법.
  5. 제1항에 있어서, 상기 불포화 이산 클로라이드가 말레일 클로라이드, 푸마릴 클로라이드, 이타코닐 클로라이드, 메사코닐 클로라이드, 5-노르보넨-2,3-디카보닐 클로라이드 및 이들의 혼합물로 이루어진 그룹으로부터 선택되는 방법.
  6. 제1항에 있어서, 불포화 지방족 폴리에스테르를 열처리하여 가교결합시키는 단계를 또한 포함하는 방법.
  7. 제6항에 따라 제조된 가교결합된 지방족 폴리에스테르를 포함하는 조성물.
  8. a) 방향족/비-방향족 혼합물을, 올리고머성 폴리에스테르 디올과 불포화 이산 클로라이드를 반응시킴으로써 제조된 가교결합된 멤브레인의 하면과 접촉시키고, b) 상기 혼합물의 방향족 성분을 상기 멤브레인을 통해 선택적으로 투과시킴을 포함하는, 상기 방향족과 비-방향족 혼합물을 방향족 혼합물이 풍부한 스트림과 비-방향족 화합물이 풍부한 스트림으로 분리시키는 방법.
  9. 제8항에 있어서, 상기 폴리에스테르 디올이 폴리에틸렌아디페이트디올, 폴리에틸렌숙시네이트디올, 폴리말로네이트디올, 폴리 옥살레이트디올, 폴리글루타레이트디올 및 이들의 혼합물로 이루어진 그룹으로부터 선택되는 방법.
  10. 제8항에 있어서, 상기 불포화 이산 클로라이드가 발레일 클로라이드, 푸마릴 클로라이드, 이타코닐 클로라이드, 메사코닐 클로라이드, 5-노르보넨-2,3-디카보닐 클로라이드 및 이들의 혼합물로 이루어진 그룹으로부터 선택되는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920018585A 1991-10-11 1992-10-09 불포화 폴리에스테르 및 그로부터 제조된, 방향족 화합물/포화 화합물의 분리를 위한 가교결합된 멤브레인 KR930008013A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/775,887 US5138023A (en) 1991-10-11 1991-10-11 Unsaturated polyesters and crosslinked membranes therefrom for aromatics/saturates separation
US775,887 1991-10-11

Publications (1)

Publication Number Publication Date
KR930008013A true KR930008013A (ko) 1993-05-20

Family

ID=25105845

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019920018585A KR930008013A (ko) 1991-10-11 1992-10-09 불포화 폴리에스테르 및 그로부터 제조된, 방향족 화합물/포화 화합물의 분리를 위한 가교결합된 멤브레인

Country Status (9)

Country Link
US (1) US5138023A (ko)
EP (1) EP0536994B1 (ko)
JP (1) JPH05247189A (ko)
KR (1) KR930008013A (ko)
CA (1) CA2078744C (ko)
DE (1) DE69228435T2 (ko)
ES (1) ES2130160T3 (ko)
MX (1) MX9205756A (ko)
MY (1) MY108361A (ko)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0516684B1 (en) * 1990-02-27 1997-01-15 Orbital Engine Company (Australia) Pty. Ltd. Treatment of fuel vapour emissions
US5401796A (en) * 1993-04-02 1995-03-28 Mitsui Toatsu Chemicals, Inc. Aliphatic polyester and preparation process thereof
US6001891A (en) * 1996-06-14 1999-12-14 Mitsui Chemicals, Inc. Biodegradable aliphatic polyester elastomer and preparation process of same
US7638053B2 (en) * 2005-06-22 2009-12-29 General Electric Company Poly(meth)acrylate membranes for separation of hydrocarbon mixtures
US8083946B2 (en) * 2006-08-08 2011-12-27 Exxonmobil Research And Engineering Company Chemically cross-linked polymeric membranes and method of use
US7749387B2 (en) * 2006-08-08 2010-07-06 Exxonmobil Research And Engineering Company Integrally-layered polymeric membranes and method of use
US7785471B2 (en) * 2006-08-08 2010-08-31 Exxonmobil Research And Engineering Company Chromatographic membrane separation
US7708151B2 (en) * 2006-08-08 2010-05-04 Exxonmobil Research And Engineering Company Membrane for separating aromatic and aliphatic compounds
US20080035574A1 (en) * 2006-08-08 2008-02-14 Sabottke Craig Y Membrane Barrier films and method of use
US20080035567A1 (en) * 2006-08-08 2008-02-14 Sabottke Craig Y Enhanced membrane separation system
KR20180023972A (ko) 2015-07-01 2018-03-07 쓰리엠 이노베이티브 프로퍼티즈 컴파니 Pvp-함유 및/또는 pvl-함유 복합막 및 사용 방법
US10618008B2 (en) 2015-07-01 2020-04-14 3M Innovative Properties Company Polymeric ionomer separation membranes and methods of use
EP3316998A1 (en) 2015-07-01 2018-05-09 3M Innovative Properties Company Composite membranes with improved performance and/or durability and methods of use

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2930754A (en) * 1954-07-16 1960-03-29 Pan American Refining Corp Method of separating hydrocarbons
US2958656A (en) * 1954-07-16 1960-11-01 American Oil Co Method of separating hydrocarbons using ethyl cellulose permselective membrane
US3370102A (en) * 1967-05-05 1968-02-20 Abcor Inc Isothermal-liquid-liquid permeation separation systems
US4051107A (en) * 1975-01-20 1977-09-27 Hooker Chemicals & Plastics Corporation Microstructured high molecular weight-low viscosity polyester polymers
DE2627629C3 (de) * 1976-06-19 1979-12-20 Bayer Ag, 5090 Leverkusen Verfahren zur Abtrennung von aromatischen* Kohlenwasserstoffen aus Gemischen mit anderen organischen Verbindungen mit Hilfe von Kunststoffmembranen
US4342859A (en) * 1980-05-27 1982-08-03 Ihara Chemical Industry Co., Ltd. Bis(aminophenylthioalkyl)terephthalate and hardener for polyurethane elastomer thereof
US5019666A (en) * 1988-08-04 1991-05-28 Exxon Research And Engineering Company Non-porous polycarbonate membranes for separation of aromatics from saturates
US4968331A (en) * 1989-05-15 1990-11-06 Nippon Steel Corporation Organic polymer separation membrane having fluorene skeleton and oxygen enrichment device utilizing same
US4946594A (en) * 1989-10-16 1990-08-07 Exxon Research And Engineering Company Crosslinked copolymers of aliphatic polyester diols and dianhydrides
US4990275A (en) * 1989-10-16 1991-02-05 Exxon Research And Engineering Company Polyimide aliphatic polyester copolymers (C-2356)
US4976868A (en) * 1989-10-16 1990-12-11 Exxon Research And Engineering Company Polyester membranes for aromatics/saturates separation
US4997906A (en) * 1989-10-16 1991-03-05 Exxon Research & Engineering Company Crosslinked copolymers of aliphatic polyester diols and dianhydrides
US4944880A (en) * 1989-10-16 1990-07-31 Exxon Research And Engineering Company Polyimide/aliphatic polyester copolymers
US5012036A (en) * 1990-07-11 1991-04-30 Exxon Research And Engineering Company Polyarylate membranes or aromatics/saturates separation (C-2415)
US5012035A (en) * 1990-07-11 1991-04-30 Exxon Research And Engineering Company Polyphthalatecarbonate membranes for aromatics/saturates separation

Also Published As

Publication number Publication date
MY108361A (en) 1996-09-30
CA2078744A1 (en) 1993-04-12
DE69228435D1 (de) 1999-03-25
EP0536994B1 (en) 1999-02-17
CA2078744C (en) 2003-04-08
US5138023A (en) 1992-08-11
MX9205756A (es) 1993-05-01
ES2130160T3 (es) 1999-07-01
JPH05247189A (ja) 1993-09-24
EP0536994A3 (en) 1993-05-19
DE69228435T2 (de) 1999-09-02
EP0536994A2 (en) 1993-04-14

Similar Documents

Publication Publication Date Title
KR930008013A (ko) 불포화 폴리에스테르 및 그로부터 제조된, 방향족 화합물/포화 화합물의 분리를 위한 가교결합된 멤브레인
KR930008018A (ko) 포화 폴리에스테르 및 그로부터 제조된, 방향족 화합물/포화 화합물의 분리를 위한 가교결합된 멤브레인
US5670052A (en) Separating aromatics from non-aromatics by polyimide-polyester membrane
KR880011274A (ko) 열가소성 수지 조성물의 제조법
KR960017767A (ko) 할로겐 함유 중합체를 포함하고, 그라프트화 지방족 폴리에스테르로 상용화된 중합체의 혼합물
EP0372761A3 (en) Process for separating extractable organic material from compositions comprising said extractable organic material intermixed with solids and water
FR2452948A1 (fr) Membrane semipermeable composite et procede pour la fabriquer
KR910008019A (ko) 폴리이미드/지방족 폴리에스테르 공중합체
DE69106815D1 (de) Verfahren zur Herstellung von veränderten Kohlenstoffmolekularsieben zur Gastrennung.
MY111135A (en) Highly selective asymmetric membranes for gas separation and method for the manufacture thereof.
DK0634433T3 (da) Anvendelse af blandinger som bindemiddel til fremstilling af sammensatte materialer.
US5073176A (en) Dicarboxylic acid polyesters and polyamides for fluid separation membranes
EP0347669A3 (de) Verfahren zur Herstellung von aromatischen Polyethersulfonen
KR920009770A (ko) 열가소성 폴리에스테르 폐기물로부터 방향족산의 메틸 에스테르 및 글리콜을 회수하는 방법
Pithan et al. Synthesis of highly fluorinated copolyimide membranes for the removal of high boiling organics from process water and wastewater by pervaporation
RU98116120A (ru) Способ разделения с применением мембраны
Yoshikawa et al. Specialty polymeric membranes. 9. Separation of benzene/cyclohexane mixtures through poly (vinyl chloride)–graft–poly (butyl methacrylate)
US5093003A (en) Halogenated polyurethanes
US5241039A (en) Polyimide/aliphatic polyester copolymers without pendent carboxylic acid groups (C-2662)
TH39009EX (th) พอลิเอสเทอร์ที่ไม่อิ่มตัวและเมมเบรนของสารนั้นที่เชื่อมขวางแล้วสำหรับแยกสารแอโรแมทิค/สารอิ่มตัว
TH39009A (th) พอลิเอสเทอร์ที่ไม่อิ่มตัวและเมมเบรนของสารนั้นที่เชื่อมขวางแล้วสำหรับแยกสารแอโรแมทิค/สารอิ่มตัว
KR960703970A (ko) 유변성이 개선된 폴리아미드 수지(polyamide resins with improved rheological properties)
TH34239EX (th) พอลิเอสเทอร์ที่อิ่มตัวและเมมเบรนของสารนั้นที่เชื่อมขวางแล้วสำหรับแยกสารแอโนแมทิค/สารอิ่มตัว
Yoshikawa et al. Specialty polymeric membranes. XIV. Pervaporation of benzene/cyclohexane mixtures through modified polyamide membranes
TH26372A (th) เยื่อกึ่งซึมได้ซึ่งขึ้นกับพอลิเอสเทอร์ของเททราโบรโมบิสฟีนอล เอ

Legal Events

Date Code Title Description
WITN Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid