KR930008018A - 포화 폴리에스테르 및 그로부터 제조된, 방향족 화합물/포화 화합물의 분리를 위한 가교결합된 멤브레인 - Google Patents
포화 폴리에스테르 및 그로부터 제조된, 방향족 화합물/포화 화합물의 분리를 위한 가교결합된 멤브레인 Download PDFInfo
- Publication number
- KR930008018A KR930008018A KR1019920018584A KR920018584A KR930008018A KR 930008018 A KR930008018 A KR 930008018A KR 1019920018584 A KR1019920018584 A KR 1019920018584A KR 920018584 A KR920018584 A KR 920018584A KR 930008018 A KR930008018 A KR 930008018A
- Authority
- KR
- South Korea
- Prior art keywords
- chloride
- saturated
- aromatic
- mixtures
- diol
- Prior art date
Links
- 229920006395 saturated elastomer Polymers 0.000 title claims abstract 11
- 239000012528 membrane Substances 0.000 title claims abstract 6
- 229920000728 polyester Polymers 0.000 title claims abstract 3
- 150000001491 aromatic compounds Chemical class 0.000 title abstract 3
- 150000001875 compounds Chemical class 0.000 title abstract 3
- 238000000926 separation method Methods 0.000 title abstract 2
- 125000003118 aryl group Chemical group 0.000 claims abstract 10
- 238000000034 method Methods 0.000 claims abstract 10
- 229920003232 aliphatic polyester Polymers 0.000 claims abstract 9
- 150000002009 diols Chemical class 0.000 claims abstract 9
- 125000001931 aliphatic group Chemical group 0.000 claims abstract 4
- 150000001805 chlorine compounds Chemical class 0.000 claims abstract 3
- 238000004132 cross linking Methods 0.000 claims abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 12
- 239000000203 mixture Substances 0.000 claims 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims 3
- JDTUPLBMGDDPJS-UHFFFAOYSA-N 2-methoxy-2-phenylethanol Chemical compound COC(CO)C1=CC=CC=C1 JDTUPLBMGDDPJS-UHFFFAOYSA-N 0.000 claims 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims 2
- 239000004698 Polyethylene Substances 0.000 claims 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims 2
- PWAXUOGZOSVGBO-UHFFFAOYSA-N adipoyl chloride Chemical compound ClC(=O)CCCCC(Cl)=O PWAXUOGZOSVGBO-UHFFFAOYSA-N 0.000 claims 2
- FDQSRULYDNDXQB-UHFFFAOYSA-N benzene-1,3-dicarbonyl chloride Chemical compound ClC(=O)C1=CC=CC(C(Cl)=O)=C1 FDQSRULYDNDXQB-UHFFFAOYSA-N 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 claims 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 claims 2
- DXGPLGPVXNBIQZ-UHFFFAOYSA-L copper;2-hydroxybenzoate;methyl n-(1h-benzimidazol-2-yl)carbamate;6-methyl-n-phenyl-2,3-dihydro-1,4-oxathiine-5-carboxamide;quinolin-8-olate Chemical group [Cu+2].OC1=CC=CC=C1C([O-])=O.C1=CN=C2C([O-])=CC=CC2=C1.C1=CC=C2NC(NC(=O)OC)=NC2=C1.S1CCOC(C)=C1C(=O)NC1=CC=CC=C1 DXGPLGPVXNBIQZ-UHFFFAOYSA-L 0.000 claims 2
- LVIMBOHJGMDKEJ-UHFFFAOYSA-N heptanedioyl dichloride Chemical compound ClC(=O)CCCCCC(Cl)=O LVIMBOHJGMDKEJ-UHFFFAOYSA-N 0.000 claims 2
- 125000000346 malonyl group Chemical group C(CC(=O)*)(=O)* 0.000 claims 2
- YVOFTMXWTWHRBH-UHFFFAOYSA-N pentanedioyl dichloride Chemical compound ClC(=O)CCCC(Cl)=O YVOFTMXWTWHRBH-UHFFFAOYSA-N 0.000 claims 2
- -1 polyethylene Polymers 0.000 claims 2
- 229920000573 polyethylene Polymers 0.000 claims 2
- LXEJRKJRKIFVNY-UHFFFAOYSA-N terephthaloyl chloride Chemical compound ClC(=O)C1=CC=C(C(Cl)=O)C=C1 LXEJRKJRKIFVNY-UHFFFAOYSA-N 0.000 claims 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 claims 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 claims 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 238000003786 synthesis reaction Methods 0.000 claims 1
- 150000003512 tertiary amines Chemical class 0.000 claims 1
- 239000008096 xylene Substances 0.000 claims 1
- 230000002194 synthesizing effect Effects 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/48—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
Abstract
포화 폴리에스테르 및 그로부터 제조된, 방향족 화합물/포화 화합물의 분리를 위한 가교결합된 멤브레인 본 발명은 포화 또는 방향족 이산 클로라이드와 올리고머성 지방족 폴리에스테르 디올을 반응시킴으로써 포화 지방족 폴리에스테르를 합성하는 방법, 상기 포화 지방족 폴리 에스테르로부터 제조한 멤브레인을 열적으로 가교결합 시키는 방법 및 포화 화합물로부터 방향족 화합물을 분리시키기 위한 가교결합된 멤브레인의 용도를 개시한다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- 올리고머성 지방족 폴리에스테르 디올과 포화 또는 방향족 이산 클로라이드를 반응시킴을 포함하는 고분자량의 포화 지방족 폴리에스테르의 합성방법.
- 제1항에 있어서, 상기 반응을 피리딘, 트리에틸렌 디아민, 트리에틸아민 및 이들의 혼합물로 이루어진 그룹으로부터 선택된 3급 아민의 존재하에서 수행하는 방법.
- 제1항에 있어서, 상기 반응을 클로로포름, 1,2-디클로로에탄, 염화메틸렌, 벤젠, 톨루엔, 크실렌, 클로로벤젠, 및 이들의 혼합물로 이루어진 그룹으로부터 선택된 용매의 존재하에서 수행하는 방법.
- 제1항에 있어서, 상기 올리고머성 지방족 폴리에스테르 디올이 폴리에틸렌 아디페이트디올, 폴리에틸렌숙시네이트디올, 폴리말로네이트디올, 폴리옥살레이트디올, 폴리글루타레이트디올 및 이들의 혼합물로 이루어진 그룹으로부터 선택되는 방법.
- 제1항에 있어서, 상기 포화 또는 방향족 이산 클로라이드가 옥살린 클로라이드, 말로닐, 클로라이드, 숙시닐 클로라이드, 글루타릴 클로라이드, 아디포일 클로라이드, 피멜로일 클로라이드, 수베로일 클로라이드, 아젤라오일 클로라이드, 세바코일 클로라이드, 이소프탈로일 클로라이드, 테레프탈로일 클로라이드 및 이들의 혼합물로 이루어진 그룹으로부터 선택되는 방법.
- 제1항에 있어서, 포화 지방족 폴리에스테르를 열처리하여 가교결합시키는 단계를 추가로 포함하는 방법.
- 제6항에 따라 제조된 가교결합된 포화 지방족 폴리에스테르를 포함하는 조성물.
- a) 방향족/비-방향족 혼합물을, 올리고머성 지방족 폴리에스테르 디올과 포화 또는 방향족 이산 클로라이드를 반응시킴으로써 제조된 가교결합된 멤브레인의 한면과 접촉시키고, b) 상기 혼합물의 방향족 성분을 상기 멤브레인을 통해 선택적으로 투과시킴을 포함하는, 상기 방향족과 비-방향족 혼합물을 방향족 화합물이 풍부한 스트림과 비-방향족 화합물이 풍부한 스트림으로 분리시키는 방법.
- 제8항에 있어서, 상기 올리고머성 폴리에스테르 디올이 폴리에틸렌 아디페이트디올, 폴리에틸렌숙시네이트디올, 폴리말로네이트디올, 폴리옥살레이트디올, 폴리글루타레이트디올 및 이들의 혼합물로 이루어진 그룹으로부터 선택되는 방법.
- 제8항에 있어서, 상기 포화 또는 방향족 이산 클로라이드가 옥살린 클로라이드, 말로닐, 클로라이드, 숙시닐 클로라이드, 글루타릴 클로라이드, 아디포일 클로라이드, 피멜로일 클로라이드, 수베로일 클로라이드, 아젤라오일 클로라이드, 세바코일 클로라이드, 이소프탈로일 클로라이드, 테레프탈로일 클로라이드 및 이들의 혼합물로 이루어진 그룹으로부터 선택되는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US775,886 | 1991-10-11 | ||
| US07/775,886 US5128439A (en) | 1991-10-11 | 1991-10-11 | Saturated polyesters and crosslinked membranes therefrom for aromatics/saturates separation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR930008018A true KR930008018A (ko) | 1993-05-20 |
Family
ID=25105842
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019920018584A KR930008018A (ko) | 1991-10-11 | 1992-10-09 | 포화 폴리에스테르 및 그로부터 제조된, 방향족 화합물/포화 화합물의 분리를 위한 가교결합된 멤브레인 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5128439A (ko) |
| EP (1) | EP0543492B1 (ko) |
| JP (1) | JPH05214084A (ko) |
| KR (1) | KR930008018A (ko) |
| CA (1) | CA2078974C (ko) |
| DE (1) | DE69228651T2 (ko) |
| ES (1) | ES2131061T3 (ko) |
| MX (1) | MX9205754A (ko) |
| MY (1) | MY107998A (ko) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5231161A (en) | 1992-10-22 | 1993-07-27 | General Electric Company | Method for preparation of macrocyclic poly(alkylene dicarboxylate) oligomers from bis(hydroxyalkyl) dicarboxylates |
| US5714230A (en) * | 1993-11-18 | 1998-02-03 | Mitsui Toatsu Chemicals, Inc. | Degradable aliphatic polyester formed products |
| KR100366484B1 (ko) | 1999-12-11 | 2003-01-14 | 주식회사 이래화학 | 코폴리에스테르 수지 조성물 및 그 제조방법 |
| KR100366483B1 (ko) * | 1999-12-17 | 2003-01-14 | 주식회사 이래화학 | 코폴리에스테르 수지 조성물 및 그 제조방법 |
| US6369157B1 (en) | 2000-01-21 | 2002-04-09 | Cyclics Corporation | Blend material including macrocyclic polyester oligomers and processes for polymerizing the same |
| US6420047B2 (en) | 2000-01-21 | 2002-07-16 | Cyclics Corporation | Macrocyclic polyester oligomers and processes for polymerizing the same |
| EP1313789B1 (en) | 2000-09-01 | 2006-07-19 | Cyclics Corporation | Methods for converting linear polyesters to macrocyclic oligoester compositions and macrocyclic oligoesters |
| US6436548B1 (en) | 2000-09-12 | 2002-08-20 | Cyclics Corporation | Species modification in macrocyclic polyester oligomers, and compositions prepared thereby |
| US6420048B1 (en) | 2001-06-05 | 2002-07-16 | Cyclics Corporation | High molecular weight copolyesters from macrocyclic oligoesters and cyclic esters |
| CN1547577A (zh) | 2001-06-27 | 2004-11-17 | 大环低聚酯的分离、配制及成型加工 | |
| US6436549B1 (en) | 2001-07-16 | 2002-08-20 | Cyclics Corporation | Block copolymers from macrocyclic oligoesters and dihydroxyl-functionalized polymers |
| US7638053B2 (en) * | 2005-06-22 | 2009-12-29 | General Electric Company | Poly(meth)acrylate membranes for separation of hydrocarbon mixtures |
| JP6838819B2 (ja) | 2015-07-01 | 2021-03-03 | スリーエム イノベイティブ プロパティズ カンパニー | 向上した性能及び／又は耐久性を有する複合膜並びに使用方法 |
| WO2017004492A1 (en) | 2015-07-01 | 2017-01-05 | 3M Innovative Properties Company | Pvp- and/or pvl-containing composite membranes and methods of use |
| KR20180023971A (ko) | 2015-07-01 | 2018-03-07 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 중합체성 이오노머 분리막 및 사용 방법 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2958656A (en) * | 1954-07-16 | 1960-11-01 | American Oil Co | Method of separating hydrocarbons using ethyl cellulose permselective membrane |
| US2930754A (en) * | 1954-07-16 | 1960-03-29 | Pan American Refining Corp | Method of separating hydrocarbons |
| US3037960A (en) * | 1958-01-09 | 1962-06-05 | Du Pont | Linear segmented copolyester and articles formed therefrom |
| US3370102A (en) * | 1967-05-05 | 1968-02-20 | Abcor Inc | Isothermal-liquid-liquid permeation separation systems |
| US4051107A (en) * | 1975-01-20 | 1977-09-27 | Hooker Chemicals & Plastics Corporation | Microstructured high molecular weight-low viscosity polyester polymers |
| DE2627629C3 (de) * | 1976-06-19 | 1979-12-20 | Bayer Ag, 5090 Leverkusen | Verfahren zur Abtrennung von aromatischen* Kohlenwasserstoffen aus Gemischen mit anderen organischen Verbindungen mit Hilfe von Kunststoffmembranen |
| US4342859A (en) * | 1980-05-27 | 1982-08-03 | Ihara Chemical Industry Co., Ltd. | Bis(aminophenylthioalkyl)terephthalate and hardener for polyurethane elastomer thereof |
| US5019666A (en) * | 1988-08-04 | 1991-05-28 | Exxon Research And Engineering Company | Non-porous polycarbonate membranes for separation of aromatics from saturates |
| US4968331A (en) * | 1989-05-15 | 1990-11-06 | Nippon Steel Corporation | Organic polymer separation membrane having fluorene skeleton and oxygen enrichment device utilizing same |
| US4976868A (en) * | 1989-10-16 | 1990-12-11 | Exxon Research And Engineering Company | Polyester membranes for aromatics/saturates separation |
| US4946594A (en) * | 1989-10-16 | 1990-08-07 | Exxon Research And Engineering Company | Crosslinked copolymers of aliphatic polyester diols and dianhydrides |
| US4990275A (en) * | 1989-10-16 | 1991-02-05 | Exxon Research And Engineering Company | Polyimide aliphatic polyester copolymers (C-2356) |
| US4944880A (en) * | 1989-10-16 | 1990-07-31 | Exxon Research And Engineering Company | Polyimide/aliphatic polyester copolymers |
| US4997906A (en) * | 1989-10-16 | 1991-03-05 | Exxon Research & Engineering Company | Crosslinked copolymers of aliphatic polyester diols and dianhydrides |
| US5012035A (en) * | 1990-07-11 | 1991-04-30 | Exxon Research And Engineering Company | Polyphthalatecarbonate membranes for aromatics/saturates separation |
| US5012036A (en) * | 1990-07-11 | 1991-04-30 | Exxon Research And Engineering Company | Polyarylate membranes or aromatics/saturates separation (C-2415) |
-
1991
- 1991-10-11 US US07/775,886 patent/US5128439A/en not_active Expired - Lifetime
-
1992
- 1992-09-23 CA CA002078974A patent/CA2078974C/en not_active Expired - Lifetime
- 1992-09-23 MY MYPI92001696A patent/MY107998A/en unknown
- 1992-10-06 JP JP4267235A patent/JPH05214084A/ja active Pending
- 1992-10-07 MX MX9205754A patent/MX9205754A/es not_active IP Right Cessation
- 1992-10-08 DE DE69228651T patent/DE69228651T2/de not_active Expired - Lifetime
- 1992-10-08 ES ES92309146T patent/ES2131061T3/es not_active Expired - Lifetime
- 1992-10-08 EP EP92309146A patent/EP0543492B1/en not_active Expired - Lifetime
- 1992-10-09 KR KR1019920018584A patent/KR930008018A/ko not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| MY107998A (en) | 1996-07-15 |
| US5128439A (en) | 1992-07-07 |
| EP0543492A1 (en) | 1993-05-26 |
| CA2078974C (en) | 2003-04-08 |
| EP0543492B1 (en) | 1999-03-17 |
| MX9205754A (es) | 1993-04-01 |
| DE69228651T2 (de) | 1999-10-21 |
| ES2131061T3 (es) | 1999-07-16 |
| JPH05214084A (ja) | 1993-08-24 |
| DE69228651D1 (de) | 1999-04-22 |
| CA2078974A1 (en) | 1993-04-12 |
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