KR930006109A - 열경화성 반응 혼합물 이의 제조방법 및 성형품 및 성형 재료를 제조하기 위한 이의 용도 - Google Patents

열경화성 반응 혼합물 이의 제조방법 및 성형품 및 성형 재료를 제조하기 위한 이의 용도 Download PDF

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KR930006109A
KR930006109A KR1019920016540A KR920016540A KR930006109A KR 930006109 A KR930006109 A KR 930006109A KR 1019920016540 A KR1019920016540 A KR 1019920016540A KR 920016540 A KR920016540 A KR 920016540A KR 930006109 A KR930006109 A KR 930006109A
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South Korea
Prior art keywords
resin mixture
mixture
thermosetting reaction
room temperature
liquid resin
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KR1019920016540A
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KR100236371B1 (ko
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야콥 한스-디이터
프란케 요아힘
뮐러 한스-페터
슈라더 루츠
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롤프 브라운, 요아힘 그렘
바이엘 아크티엔게젤샤프트
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
    • C08G59/4014—Nitrogen containing compounds
    • C08G59/4028—Isocyanates; Thioisocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/003—Polymeric products of isocyanates or isothiocyanates with epoxy compounds having no active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1875—Catalysts containing secondary or tertiary amines or salts thereof containing ammonium salts or mixtures of secondary of tertiary amines and acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C08G59/688—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C08G59/72—Complexes of boron halides

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Epoxy Resins (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)

Abstract

본 발명에 이르러, 언제라도 경화를 중단시킬 필요없이, 실온에서 충분히 저장-안정성이고, 이소시아누레이트 및 옥사졸리딘온 그룹을 갖는 고품질의 플라스틱으로 열-경화될 수 있으며, 유기 폴리이소시아네이트 및 유기 폴리에폭사이드를 기본으로 하는 반응 수지 혼합물을 제공하여, 시스템이 중간 "B-단계"상태(즉, 상온 또는 경미한 승온에서도 고체이지만 다소 용융성인 상태)에서 존재할 수 있어, 시간 경과후, 즉 적합한 용매중에서 연마하거나 용해시킨 후 상기 수지는 성형 및 추가의 열작용에 의해 이들의 최종적인 가교결합된, 더 이상 용융되지 않는 최종 상태로 전환될 수 있게 되었다.

Description

열경화성 반응 혼합물 이의 제조방법 및 성형품 및 성형 재료를 제조하기 위한 이의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (4)

  1. a) 하나이상의 유기 폴리이소시아네이트와 b) 이소시아네이트 그룹 대 에폭사이드 그룹의 당량비가 1.2:1 내지 70:1에 상응하는 양으로 존재하는 2개 이상의 에폭사이드 그룹을 함유하는 하나이상의 유기 화합물을, c) c1)-3급 아민인 비-잠복성 촉매 0.1 내지 1.0중량%(전체 혼합물 중량기준), 및 c2) ⅰ) 알킬화 반응중에서 활성인, 유기 포스폰산 또는 인산의 산 에스테르로부터 형성된 3급 또는 4급 암모늄염 및 ⅱ) 보론 트리할라이드-3급 아민 착물로 이루어진 그룹중에서 선택된 열적으로 잠복성인 촉매로 이루어진 촉매 혼합물 및 d) 임의로, 추가의 공정 보조제 및 부가제의 존재하에서, 반응시켜 열경화성 반응 수지 혼합물을 제조하는데 있어서, 2가지 촉매 c1) 및 c2) 혼합물이, ⅰ) 실온에서 고체이고 저장-안정성이 있으며, ⅱ) 언제나 가열에 의해 최종적으로 가교결합된 상태로 전환될 수 있는 B-단계 수지를 제공함을 특징으로 하는 열경화성 반응 수지 혼합물.
  2. 제1항에 있어서, 충진제, 착색제, 가공보조제 및 부가제를 추가로 함유하는, 연마성, 용융성 및 가용성 수지 혼합물.
  3. 제1항에 있어서, 충진제, 착색제, 가공보조제 및 부가제를 임의로 부가한 후에, 부을 수 있는 (pourable)저장-안정성 재료로 전환되고, 이후에 성형품으로 가공되는 액체수지 혼합물.
  4. 제1항에 있어서, 지지재에 가하여 실온에서 B-단계로 반응하고, 이후에 성형품으로 가압되는 액체 수지 혼합물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920016540A 1991-09-12 1992-09-09 열경화성 반응 수지 혼합물, 이의 제조방법, 및 성형품 및 성형 재료를 제조하기 위한 이의 용도 KR100236371B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4130329A DE4130329A1 (de) 1991-09-12 1991-09-12 Waermehaertbare reaktionsharzgemische, ein verfahren zu ihrer herstellung und die verwendung zur herstellung von press-massen und formkoerpern
DEP4130329.6 1991-09-12

Publications (2)

Publication Number Publication Date
KR930006109A true KR930006109A (ko) 1993-04-20
KR100236371B1 KR100236371B1 (ko) 1999-12-15

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KR1019920016540A KR100236371B1 (ko) 1991-09-12 1992-09-09 열경화성 반응 수지 혼합물, 이의 제조방법, 및 성형품 및 성형 재료를 제조하기 위한 이의 용도

Country Status (7)

Country Link
US (1) US5266662A (ko)
EP (1) EP0531844B1 (ko)
JP (1) JP3196860B2 (ko)
KR (1) KR100236371B1 (ko)
CA (1) CA2077804A1 (ko)
DE (2) DE4130329A1 (ko)
ES (1) ES2096688T3 (ko)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4327570A1 (de) * 1993-08-17 1995-04-20 Bayer Ag Rieselfähige Preßmassen, Verfahren zu deren Herstellung und ihre Verwendung
DE19654149A1 (de) * 1996-12-23 1998-06-25 Basf Ag Oxazolidon- und Urethangruppen enthaltende, unter Druck stehende isocyanatterminierte Prepolymere für Einkomponenten-Schäume
TWI279408B (en) * 2000-01-31 2007-04-21 Vantico Ag Epoxy resin composition
US6833629B2 (en) 2001-12-14 2004-12-21 National Starch And Chemical Investment Holding Corporation Dual cure B-stageable underfill for wafer level
US20030129438A1 (en) * 2001-12-14 2003-07-10 Becker Kevin Harris Dual cure B-stageable adhesive for die attach
US7176044B2 (en) * 2002-11-25 2007-02-13 Henkel Corporation B-stageable die attach adhesives
DE102005045150A1 (de) * 2005-09-22 2007-04-05 Basf Coatings Ag Verwendung von Phosphonsäurediestern und Diphosphonsäurediestern sowie thermisch härtbare Gemische, enthaltend Phosphonsäurediester und Diphosphonsäurediester
US7887687B2 (en) 2006-08-22 2011-02-15 Deere & Company Method and system for coating a workpiece
DE102014226838A1 (de) 2014-12-22 2016-06-23 Henkel Ag & Co. Kgaa Oxazolidinon- und Isocyanurat-vernetzte Matrix für faserverstärktes Material
DE102014226842A1 (de) 2014-12-22 2016-06-23 Henkel Ag & Co. Kgaa Katalysator-Zusammensetzung zur Härtung von Epoxidgruppen-haltigen Harzen
EP3305863A1 (de) * 2016-10-07 2018-04-11 Basf Se Verfahren zur herstellung von in lösungsmitteln flockulationsstabilen polyisocyanaten von (cyclo)aliphatischen diisocyanaten

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2655367C2 (de) * 1976-12-03 1978-12-07 Siemens Ag, 1000 Berlin Und 8000 Muenchen Heißhärtende Reaktionsharzmischung zur Imprägnierung von Isolierungen elektrischer Geräte und zur Herstellung von Formstoffen mit oder ohne Einlagen
DE3323153A1 (de) * 1983-06-27 1985-01-03 Siemens AG, 1000 Berlin und 8000 München Hitzehaertbare reaktionsharzmischungen
DE3323084A1 (de) * 1983-06-27 1985-01-10 Siemens AG, 1000 Berlin und 8000 München Verfahren zur herstellung von formstoffen
DE3323122A1 (de) * 1983-06-27 1985-05-23 Siemens AG, 1000 Berlin und 8000 München Verfahren zur herstellung von reaktionsharzformstoffen
DE3323123A1 (de) * 1983-06-27 1985-01-10 Siemens AG, 1000 Berlin und 8000 München Hitzehaertbare reaktionsharzmischungen
DE3600764A1 (de) * 1986-01-14 1987-07-16 Bayer Ag Waermehaertbare reaktionsharzgemische und ein verfahren zur herstellung von formkoerpern unter verwendung dieser gemische
DE3644382A1 (de) * 1986-12-24 1988-07-07 Bayer Ag Verfahren zur zweistufigen herstellung von formkoerpern
DE3904156A1 (de) * 1989-02-11 1990-08-16 Bayer Ag Kalthaertende reaktionsharzmischung und deren verwendung

Also Published As

Publication number Publication date
JPH05295077A (ja) 1993-11-09
EP0531844A1 (de) 1993-03-17
CA2077804A1 (en) 1993-03-13
EP0531844B1 (de) 1996-12-27
US5266662A (en) 1993-11-30
DE59207754D1 (de) 1997-02-06
DE4130329A1 (de) 1993-03-18
ES2096688T3 (es) 1997-03-16
JP3196860B2 (ja) 2001-08-06
KR100236371B1 (ko) 1999-12-15

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