KR870011177A - 베타-히드록시알킬카르바밀메틸레이티드아미노트리아진 및 상기화합물을 함유한 경화성 조성물 - Google Patents

베타-히드록시알킬카르바밀메틸레이티드아미노트리아진 및 상기화합물을 함유한 경화성 조성물 Download PDF

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KR870011177A
KR870011177A KR870004897A KR870004897A KR870011177A KR 870011177 A KR870011177 A KR 870011177A KR 870004897 A KR870004897 A KR 870004897A KR 870004897 A KR870004897 A KR 870004897A KR 870011177 A KR870011177 A KR 870011177A
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살바토어 훠어젼 피이터
싱 발완트
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존 제이 헤이간
아메리칸 사이아나밋드 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22C—FOUNDRY MOULDING
    • B22C1/00—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
    • B22C1/16—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents
    • B22C1/20—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of organic agents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/14—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom
    • C07D251/16—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom to only one ring carbon atom
    • C07D251/18—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom to only one ring carbon atom with nitrogen atoms directly attached to the two other ring carbon atoms, e.g. guanamines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
    • C07D251/40—Nitrogen atoms
    • C07D251/54—Three nitrogen atoms
    • C07D251/70—Other substituted melamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
    • C08G12/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
    • C08G18/3842—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring
    • C08G18/3851—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring containing three nitrogen atoms in the ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31942—Of aldehyde or ketone condensation product

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Paints Or Removers (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

내용 없음

Description

베타-히드록시알킬카르바밀메틸레이티드아미노트리아진 및 상기 화합물을 함유한 경화성 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 하기(i)-(iv)로부터 선택된 트리아진 화합물
    (i) 일반식C3N6(CH2OR)6-X(CH2NHCOOR1)|X의 트리아미노트리아진 화합물;
    (ii) 일반식C3N5(C6H5)(CH2OR)4-y(CH2NHCOOR1)y의 벤조구아민 화합물;
    (iii) (i)또는(ii)의 올리고머;또는
    (iv) (i),(ii)및(iii)중 최소한 두개의 혼합물.
    (R기들은 독립적으로 수소 또는 탄소원자 1내지 12개를 갖는 알킬,R1기들은 독립적으로 탄소원자 2내지 18개를 갖는 -베타히드록시알킬 혼자 또는 탄소원자 1내지 18개를 갖는 알킬과 조합한 것이며, X는 약 3내지 약6의 범위이고, Y는 약2내지약4의 범위이다)
  2. 제 1 항에 있어서, X가 약5내지 약6의 범위, R이 C1-C12알킬이고, R1이 베타-히드록시에틸베타-히드록시프로필또는 베타-히드록시프로필과 C1-C18알킬 카르바메이트와의 혼합물인 트리아노미트리아진 화합물(i)
  3. 제 1 항에 있어서, Y가 약 3내지 약4의 범위, R이 메틸이고, R´이 베타-히드록시에틸 또는 베타-히드록시프로필인 벤조구안아민 화합물(ii).
  4. 제 1 항에 있어서, R이 메틸이고, R′이 베타-히드록시에틸 또는 베타-히드록시프로필인 트리아미노트리아진 화합물(iii)(i)의 올리고머.
  5. 하기(a)-(c)로 이루어진 경화성 조성물:
    (a) 하기(i)-(iv)로부터 선택된 트리아진 화합물
    (i) 일반식C3N6(CH2OR)6-X(CH2NHCOOR1)|X의 트리아미노트리아진 화합물;
    (ii) 일반식C3N5(C6H5)(CH2OR)4-Y(CH2NHCOOR1)Y의 벤조구아민 화합물;
    (iii) (i)또는(ii)의 올리고머;또는
    (iv) (i),(ii)및(iii)중 최소한 두개의 혼합물.
    (R기들은 독립적으로, 수소 또는 탄소원자 1내지 12개를 갖는 알킬, R′기들은 독립적으로 탄소원자 2내지 18개를 갖는 베타-히드록시알킬 혼자 또는 탄소원자 1내지 18개를 갖는 알킬과 조합한 것이고 X는 약 2내지 약6의 범위이고, Y는 약2내지약4의 범위이다)과 : 임의에 따라,
    (b) 아미노 수지 또는 활성 수소-함유물질:과, 임의에 따라,
    (c) 경화촉매
  6. 제 5 항에 있어서, 아미노 수지가 히드록시메틸 또는 메톡시메틸기를 포함하고, 활성수소-함유물질이 카르복실기, 알콜릭 히드록시기, 아미노기, 아니드기 또는 이러한 기의 혼합물로부터 선택된 반응성기중 최소한 하나를 포함하는 중합체 물질인 경화성 조성물.
  7. 제 5 항에 있어서, 트리아진 화합물이 x가 약 5 내지 약 6 의 범위, R이 메틸이고 R′이 베타-히드록시에틸, 베타-히드록시프로필 또는 베타히드록시프로필과 C1-C18알킬 카르바메이트의 혼합물인 트리아미노트리아진 화합물인 경화성 조성물.
  8. 제 7 항에 있어서, 경화촉매가 산인 경화성 조성물.
  9. 제 5 항에서 정의한 바와 같은 베이크 및 경화된 조성물을 보호적으로 피복시킨 기질.
  10. 가열하에서 압밀된 제 5 항에서 정의한 바와같은 조성물과 혼합된 강화제 또는 충전대를 포함하는 제품.
  11. 하기(a)-(c)로 이루어진 경화성 조성물을 제조하는 방법.
    (a) 하기(i)-(iv)로부터 선택된 트리아진 화합물
    (i) 일반식C3N6(CH2OR)6-X(CH2NHCOOR1)|X의 트리아미노트리아진 화합물;
    (ii) 일반식C3N5(C6H5)(CH2OR)4-Y(CH2NHCOOR1)Y의 벤조구아민 화합물;
    (iii) (i)또는(ii)의 올리고머 ; 또는
    (iv) (i),(ii)및(iii)중 최소한 두개의 혼합물.
    (R기들은 독립적으로, 수소 또는 탄소원자 1내지 12개를 갖는 알킬, R′기들은 독립적으로 탄소원자 2내지 18개를 갖는 베타-히드록시알킬 혼자 또는 탄소원자 1내지 18개를 갖는 알킬과 조합한 것이고 X는 약 2 내지 약 6 의 범위이고, Y는 약2내지약4의 범위이다)과 ; 임의에 따라,
    (b) 아미노 수지 또는 활성 수소-함유물질;과, 임의에 따라,
    (c) 경화촉매
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870004897A 1986-05-16 1987-05-15 베타-히드록시알킬카르바밀메틸레이티드 아미노트리아진 KR950008781B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US864626 1986-05-16
US06/864,626 US4708984A (en) 1986-05-16 1986-05-16 Beta-hydroxyalkylcarbamyl-methylated aminotrizines and curable compositions containing the same
US06/864,626 1986-05-16

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KR870011177A true KR870011177A (ko) 1987-12-21
KR950008781B1 KR950008781B1 (ko) 1995-08-08

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US (1) US4708984A (ko)
EP (1) EP0245701B1 (ko)
JP (1) JPH0751569B2 (ko)
KR (1) KR950008781B1 (ko)
AT (1) ATE98233T1 (ko)
BR (1) BR8702267A (ko)
CA (1) CA1306256C (ko)
DE (1) DE3788368T2 (ko)
ES (1) ES2061449T3 (ko)
GR (1) GR3010330T3 (ko)
MX (2) MX167084B (ko)
NO (1) NO176243C (ko)

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EP0245701A2 (en) 1987-11-19
KR950008781B1 (ko) 1995-08-08
DE3788368T2 (de) 1994-06-23
MX167084B (es) 1993-03-03
ATE98233T1 (de) 1993-12-15
JPH0751569B2 (ja) 1995-06-05
NO176243B (no) 1994-11-21
EP0245701B1 (en) 1993-12-08
GR3010330T3 (ko) 1994-03-31
EP0245701A3 (en) 1989-06-21
BR8702267A (pt) 1988-02-17
NO872043D0 (no) 1987-05-15
NO872043L (no) 1987-11-17
ES2061449T3 (es) 1994-12-16
MX9300033A (es) 1994-07-29
CA1306256C (en) 1992-08-11
DE3788368D1 (de) 1994-01-20
US4708984A (en) 1987-11-24
JPS6333370A (ja) 1988-02-13
NO176243C (no) 1995-03-01

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