KR920012269A - Thermosetting Epoxy Resin Composition - Google Patents

Thermosetting Epoxy Resin Composition Download PDF

Info

Publication number
KR920012269A
KR920012269A KR1019900022921A KR900022921A KR920012269A KR 920012269 A KR920012269 A KR 920012269A KR 1019900022921 A KR1019900022921 A KR 1019900022921A KR 900022921 A KR900022921 A KR 900022921A KR 920012269 A KR920012269 A KR 920012269A
Authority
KR
South Korea
Prior art keywords
epoxy resin
resin composition
thermosetting epoxy
weight
compounding amount
Prior art date
Application number
KR1019900022921A
Other languages
Korean (ko)
Other versions
KR940001072B1 (en
Inventor
강면의
장진원
유창준
Original Assignee
김충세
고려화학 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 김충세, 고려화학 주식회사 filed Critical 김충세
Priority to KR1019900022921A priority Critical patent/KR940001072B1/en
Publication of KR920012269A publication Critical patent/KR920012269A/en
Application granted granted Critical
Publication of KR940001072B1 publication Critical patent/KR940001072B1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Epoxy Resins (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

내용 없음No content

Description

열경화성 에폭시 수지 조성물Thermosetting Epoxy Resin Composition

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

제1도는 주제 침강법으로 침강성을 측정하기 위한 장치도이다.1 is an apparatus diagram for measuring sedimentation by the main sedimentation method.

Claims (9)

비스페놀 A형 에폭시 수지, 디 브로모 글리시딜 에테르와 폴리부타디엔의 예비반응물, 에폭시계 반응성 희석제 및 폴리에스테르 변성 폴리우레탄계 습윤분산제등의 유기첨가제로 구성되는 혼합물과 결정성 실리카, 산화안티몬과 수산화 알루미늄을 포함하는 복합충진제로 구성되는 주제와 경화촉진제 및 산무수물계 충진제인 경화제로 구성됨을 특징으로 하는 고전압 전기부품용 2액형 열경화성 에폭시 수지조성물.A mixture consisting of organic additives such as bisphenol A epoxy resin, pre-reactant of dibromo glycidyl ether and polybutadiene, epoxy reactive diluent and polyester-modified polyurethane-based dispersant, crystalline silica, antimony oxide and aluminum hydroxide A two-component thermosetting epoxy resin composition for a high voltage electric component, comprising a main body composed of a composite filler including a curing accelerator and an acid anhydride-based filler. 제1항에 있어서, 비스페놀 A형 에폭시 수지는 에폭시 당량이 180∼210인 것이며, 그 배합량은 전체 주제성분의 20∼40중량%임을 특징으로 하는 열경화성 에폭시 수지 조성물.The thermosetting epoxy resin composition according to claim 1, wherein the bisphenol A epoxy resin has an epoxy equivalent of 180 to 210, and the compounding amount thereof is 20 to 40% by weight of the total main components. 제1항에 있어서, 예비반응물의 디 브로모 글리시딜 에테르는 에폭시 당량이 300∼400이고, Br함량이 35∼55%인 것이며, 폴리부타디엔은 분자량이 1,600∼4,000정도인 것이고, 예비반응물의 배합량은 전체주제성분의 2∼20중량%임을 특징으로 하는 열경화성 에폭시 수지 조성물.The dibromo glycidyl ether of the prereactant is an epoxy equivalent of 300-400, a Br content of 35-55%, the polybutadiene has a molecular weight of about 1,600-4,000, and Thermosetting epoxy resin composition, characterized in that the compounding amount is 2 to 20% by weight of the total main ingredient. 제1항 또는 제3항에 있어서, 예비반응물은 50∼85wt%의 디브로모 글리시딜에테르와 15∼50중량%의 폴리부타디엔으로 구성됨을 특징으로 하는 열경화성 에폭시 수지 조성물.The thermosetting epoxy resin composition according to claim 1 or 3, wherein the pre-reactant is composed of 50-85 wt% dibromo glycidyl ether and 15-50 wt% polybutadiene. 제1항에 있어서, 에폭시계 반응성 희석제는 에폭시 관능기가 1개이상이며 에폭시 당량이 100∼300정도인 것이고, 이의 배합량은 전제주제성분의 1∼10중량%임을 특징으로 하는 열경화성 에폭시 수지 조성물.The thermosetting epoxy resin composition according to claim 1, wherein the epoxy-based reactive diluent has one or more epoxy functional groups and an epoxy equivalent of about 100 to 300, and a compounding amount thereof is 1 to 10% by weight of the total main ingredient. 제1항에 있어서, 폴리에스테르 변성 폴리우레탄계 습윤 분산제로는 일반식(Ⅰ)로 표현되는 화합물을 전체유기 첨가제의 30∼50중량%로 첨가됨을 특징으로 하는 열경화성 에폭시 수지 조성물.The thermosetting epoxy resin composition according to claim 1, wherein the polyester-modified polyurethane-based wet dispersant is added with 30 to 50% by weight of the total organic additive. 여기에서, Rn은 폴리에스테르 변성 폴리우레탄이고, R1은 C1∼C6의 알킬로서 할로겐 치환제이며, R2는 C1∼C6의 알킬로서 하이드록시 또는 할로겐 치환체이고, R3는 C12∼C30의 알킬, 알킬렌, 방향족 또는 헤테로 싸이클릭 화합물로서 하이드록시 또는 할로겐 치환체이다.Wherein Rn is a polyester-modified polyurethane, R 1 is a halogen substituent as C 1 -C 6 alkyl, R 2 is a hydroxy or halogen substituent as C 1 -C 6 alkyl, and R 3 is C Alkyl, alkylene, aromatic or heterocyclic compounds of 12 to C 30 are hydroxy or halogen substituents. 제1항에 있어서, 복합충진제는 구성성분 각각의 평균입자 크기가 0.5∼20㎛인이며, 10∼60중량%의 결정성 실리카, 1∼20중량%의 산화안티몬과 30∼80중량%의 수산화 알루미늄으로 구성된 것이고, 그 배합량은 전체 주제성분의 40∼80중량%임을 특징으로 하는 열경화성 에폭시 수지 조성물.The composite filler according to claim 1, wherein the composite filler has an average particle size of 0.5 to 20 µm of each component, 10 to 60 wt% of crystalline silica, 1 to 20 wt% of antimony oxide, and 30 to 80 wt% of hydroxide. It consists of aluminum, and the compounding quantity is 40 to 80 weight% of all the main components, The thermosetting epoxy resin composition characterized by the above-mentioned. 제1항에 있어서, 경화제는 상온에서 액상인 메틸테트라 하이드로 프탈릭 안하이드라이드, 메틸헥사하이드로 프탈릭 안하이드라이드 또는 메틸싸이클로 펜타디엔 프탈릭 안하이드라이드이고, 그 배합량은 주제성분중 에폭시 1당량에 대해 산무수몰을 0.7∼1.3당량로 배합함을 특징으로하는 열경화성 에폭시 수지 조성물.The method of claim 1, wherein the curing agent is a liquid methyltetra hydro phthalic anhydride, methylhexahydro phthalic anhydride or methyl cyclopentadiene phthalic anhydride at room temperature, the compounding amount is 1 equivalent of epoxy in the main component A thermosetting epoxy resin composition comprising an acid anhydride in an amount of 0.7 to 1.3 equivalents. 제1항에 있어서, 경화촉진제는 3급아민계 화합물, 이미다졸계 화합물 또는 BF3-착염계 화합물이며, 그 배합량은 경화제로 사용되는 산무수물에 대하여 0.5∼1.0중량%임을 특징으로 하는 열경화성 에폭시 수지 조성물The thermosetting epoxy resin according to claim 1, wherein the curing accelerator is a tertiary amine compound, an imidazole compound, or a BF 3 -complex salt compound, and the compounding amount is 0.5 to 1.0 wt% based on the acid anhydride used as the curing agent. Resin composition ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019900022921A 1990-12-31 1990-12-31 Thermosetting epoxy resin composition KR940001072B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019900022921A KR940001072B1 (en) 1990-12-31 1990-12-31 Thermosetting epoxy resin composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019900022921A KR940001072B1 (en) 1990-12-31 1990-12-31 Thermosetting epoxy resin composition

Publications (2)

Publication Number Publication Date
KR920012269A true KR920012269A (en) 1992-07-25
KR940001072B1 KR940001072B1 (en) 1994-02-12

Family

ID=19309326

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019900022921A KR940001072B1 (en) 1990-12-31 1990-12-31 Thermosetting epoxy resin composition

Country Status (1)

Country Link
KR (1) KR940001072B1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100485962B1 (en) * 2001-11-14 2005-04-29 정도화성 주식회사 Weather-proof Epoxy Composition for Outdoor Insulator against Electricity
KR100835842B1 (en) * 2007-04-12 2008-06-09 함성복 Two-type epoxy resin composition

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6440642B1 (en) 1999-09-15 2002-08-27 Shipley Company, L.L.C. Dielectric composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100485962B1 (en) * 2001-11-14 2005-04-29 정도화성 주식회사 Weather-proof Epoxy Composition for Outdoor Insulator against Electricity
KR100835842B1 (en) * 2007-04-12 2008-06-09 함성복 Two-type epoxy resin composition

Also Published As

Publication number Publication date
KR940001072B1 (en) 1994-02-12

Similar Documents

Publication Publication Date Title
KR880007589A (en) Multifunctional Epoxide Resin
ATE247326T1 (en) EPOXY RESIN CASTING COMPOUND
DE3689869T2 (en) Resin compositions and processes for making laminates therefrom.
KR910008003A (en) Curing agent composition, method for preparing the same and thermosetting epoxy resin composition
KR880004031A (en) Resin composition with good storage stability
KR920012269A (en) Thermosetting Epoxy Resin Composition
KR910009837A (en) Stabilizer Mixtures for Elastomers
JPS57147513A (en) Varnish composition
KR930006070A (en) Novel Imide Epoxy Resin and Its Manufacturing Method
JPS6249293B2 (en)
ES8400757A1 (en) Process for increasing the viscosity of mixtures containing epoxy resins.
KR930012972A (en) Thermosetting epoxy resin composition for high voltage electric parts
JPS5582138A (en) Polyolefin resin composition
KR910012059A (en) Thermosetting Epoxy Resin Compositions for High Voltage Electrical Components
JPS5693749A (en) Epoxy resin composition
JPS6327373B2 (en)
KR930010077A (en) Epoxy Imidazole Additives and Epoxy Resin Compositions
KR940014616A (en) Thermosetting Epoxy Resin Composition
KR950018262A (en) Thermosetting epoxy resin composition for high voltage electric parts
JPH06192394A (en) Thermosetting resin composition having low shrinkage and adhesive using the same
KR900004841A (en) Epoxy resin powder coating composition
JPS57190018A (en) Epoxy resin composition
JPS57139117A (en) Epoxy resin composition
JPS54131699A (en) Curable epoxy resin composition
JPS5778454A (en) Cold-setting organopolysiloxane composition

Legal Events

Date Code Title Description
A201 Request for examination
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
LAPS Lapse due to unpaid annual fee