KR910015649A - 내충격성 및 표면 광택이 우수한 열가소성 수지의 제조방법 - Google Patents

내충격성 및 표면 광택이 우수한 열가소성 수지의 제조방법 Download PDF

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Publication number
KR910015649A
KR910015649A KR1019900002664A KR900002664A KR910015649A KR 910015649 A KR910015649 A KR 910015649A KR 1019900002664 A KR1019900002664 A KR 1019900002664A KR 900002664 A KR900002664 A KR 900002664A KR 910015649 A KR910015649 A KR 910015649A
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South Korea
Prior art keywords
weight
graft
monomers
rubber
thermoplastic resin
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KR1019900002664A
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English (en)
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KR920005677B1 (ko
Inventor
김동렬
이찬홍
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최근선
주식회사 럭 키
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Application filed by 최근선, 주식회사 럭 키 filed Critical 최근선
Priority to KR1019900002664A priority Critical patent/KR920005677B1/ko
Priority to DE69115159T priority patent/DE69115159T2/de
Priority to US08/071,045 priority patent/US5352728A/en
Priority to EP91904899A priority patent/EP0470229B1/en
Priority to PCT/KR1991/000006 priority patent/WO1991013118A1/en
Priority to AT91904899T priority patent/ATE131194T1/de
Priority to ES91904899T priority patent/ES2082197T3/es
Priority to JP3504624A priority patent/JP2608219B2/ja
Publication of KR910015649A publication Critical patent/KR910015649A/ko
Publication of KR920005677B1 publication Critical patent/KR920005677B1/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

내용 없음

Description

내충격성 및 표면 광택이 우수한 열가소성 수지의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (4)

  1. 겔 함량이 70-95%이고, 중량 평균입경이 0.03~0.2㎛인 고무질 10~40 중량부에 비닐방향족 화합물과 비닐화합물의 구성비가 60/40~100/0으로 혼합된 단량체혼합물을 그라프트 공중합시켜 그라프트율이 60~120%이고, 그라프트된 공중합체의 분자량이 40,000~120,000인 그라프트 공중합체(A)와 중량 평균입경이 0.25~1.0㎛인 고무질 40~80중량부에 상기의 단량체 혼합물을 그라프트 공중합시 단량체 전부를 연속적으로 투여하는 방법으로는 반응시작 후 3시간 동안 반응온도 42~70℃에서 총단량체의 50~80중량%를 투입하고, 반응온도 70~80℃에서 20~50중량%의 나머지 단량체를 1.5시간 동안 투입하며, 단량체 일부를 일괄투여한 후 나머지 단량체를 연속적으로 투여하는 방법에서는 단량체 일부의 일괄투여 시의 양 대 고무질의 비는 0.16~0.35이고, 전환율이 65%까지 62℃이하로 유지하고, 65% 이상에서 반응온도를 68℃이하로 유지시켜 그라프트 중합을 행하고, 나머지 단량체를 연속적으로 투여시 반응온도를 68~80℃에서 그라프트 공중합을 시켜 그라프트율이 25~45%이고, 그라프된 공중합체의 분자량이 40,000~120,000인 그라프트 공중합체(B)를 혼합함을 특징으로 하는 내충격성 및 표면광택이 우수한 열가소성 수지의 제조방법.
  2. 제 1항에 있어서, 제조된 수지내 소구경 고무질과 대구경 고무질의 무게비가 30/70~5/95임을 특징으로 하는 내충격성 및 표면광택이 우수한 열가소성 수지의 제조방법.
  3. 제 1항에 있어서, (A)그라프트 공중합체와 (B)그라프트 공중합체의 혼합시 고무질 함량이 30~55%임을 특징으로 하는 내충격성 및 표면광택이 우수한 열가소성 수지의 제조방법.
  4. 제 1항에 있어서, (B)그라프트 공중합체 제조시 분자량 조절제 사용량은 그라프트 단량체 100 중량부당 0.6~1.2 중량부임을 특징으로 하는 내충격성 및 표면광택이 우수한 열가소성 수지의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900002664A 1990-02-28 1990-02-28 내충격성 및 표면 광택이 우수한 열가소성 수지의 제조방법 KR920005677B1 (ko)

Priority Applications (8)

Application Number Priority Date Filing Date Title
KR1019900002664A KR920005677B1 (ko) 1990-02-28 1990-02-28 내충격성 및 표면 광택이 우수한 열가소성 수지의 제조방법
PCT/KR1991/000006 WO1991013118A1 (en) 1990-02-28 1991-02-28 A process for the preparation of impact resistant and high gloss thermoplastic resin
US08/071,045 US5352728A (en) 1990-02-28 1991-02-28 Process for preparation of impact resistance and high gloss thermoplastic resin
EP91904899A EP0470229B1 (en) 1990-02-28 1991-02-28 A process for the preparation of impact resistant and high gloss thermoplastic resin
DE69115159T DE69115159T2 (de) 1990-02-28 1991-02-28 Verfahren zur Herstellung von Stossresistenten Thermoplastischen Harzen mit Hochglänzender Oberfläche.
AT91904899T ATE131194T1 (de) 1990-02-28 1991-02-28 Verfahren zur herstellung von stossresistenten thermoplastischen harzen mit hochglänzender oberfläche.
ES91904899T ES2082197T3 (es) 1990-02-28 1991-02-28 Un procedimiento para la preparacion de resina termoplastica de gran brillo y resistente al choque.
JP3504624A JP2608219B2 (ja) 1990-02-28 1991-02-28 耐衝撃性及び光沢性熱可塑性樹脂の製造方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019900002664A KR920005677B1 (ko) 1990-02-28 1990-02-28 내충격성 및 표면 광택이 우수한 열가소성 수지의 제조방법

Publications (2)

Publication Number Publication Date
KR910015649A true KR910015649A (ko) 1991-09-30
KR920005677B1 KR920005677B1 (ko) 1992-07-13

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ID=19296563

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Application Number Title Priority Date Filing Date
KR1019900002664A KR920005677B1 (ko) 1990-02-28 1990-02-28 내충격성 및 표면 광택이 우수한 열가소성 수지의 제조방법

Country Status (8)

Country Link
US (1) US5352728A (ko)
EP (1) EP0470229B1 (ko)
JP (1) JP2608219B2 (ko)
KR (1) KR920005677B1 (ko)
AT (1) ATE131194T1 (ko)
DE (1) DE69115159T2 (ko)
ES (1) ES2082197T3 (ko)
WO (1) WO1991013118A1 (ko)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0746576B1 (en) * 1994-02-22 1998-11-18 The Dow Chemical Company Process for the preparation of multimodal abs polymers
DE19518025A1 (de) * 1995-05-17 1996-11-21 Bayer Ag Thermoplastische ABS-Formmassen
DE19649249A1 (de) * 1996-11-28 1998-06-04 Bayer Ag Verbesserte thermoplastische Formmassen vom ABS-Typ
DE19649255A1 (de) * 1996-11-28 1998-06-04 Bayer Ag Thermoplastische Hochglanz-Formmassen vom ABS-Typ
DE19853107A1 (de) 1998-11-18 2000-05-25 Bayer Ag ABS-Formmassen mit verbesserter Eigenschaftskombination
DE10008418A1 (de) * 2000-02-23 2001-08-30 Bayer Ag ABS-Formmassen mit verbesserter Verarbeitbarkeit und hohem Glanz
DE10060411A1 (de) 2000-12-05 2002-06-06 Bayer Ag Thermoplastische Formmassen
DE10060410A1 (de) 2000-12-05 2002-06-06 Bayer Ag Thermoplastische Formmassen
EP1752478A1 (en) * 2005-08-08 2007-02-14 Basf Aktiengesellschaft A process for the production of a graft copolymer having a bimodal particle distribution.
FR3042437B1 (fr) * 2015-10-16 2018-02-09 Toray Film Europe Film composite polyester/primaire/metal perfectionne cohesif et impermeable aux gaz, son procede de fabrication et le primaire mis en oeuvre dans ce procede

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3304544A1 (de) * 1983-02-10 1984-08-16 Bayer Ag, 5090 Leverkusen Abs-formmassen
DE3629152A1 (de) * 1986-08-27 1988-03-03 Basf Ag Thermoplastische formmasse auf basis von abs
US4753988A (en) * 1987-02-18 1988-06-28 The Dow Chemical Company High gloss acrylate rubber-modified weatherable resins
JPH0742384B2 (ja) * 1987-04-21 1995-05-10 日本合成ゴム株式会社 熱可塑性樹脂組成物

Also Published As

Publication number Publication date
ATE131194T1 (de) 1995-12-15
EP0470229A1 (en) 1992-02-12
JP2608219B2 (ja) 1997-05-07
EP0470229B1 (en) 1995-12-06
DE69115159D1 (de) 1996-01-18
US5352728A (en) 1994-10-04
KR920005677B1 (ko) 1992-07-13
ES2082197T3 (es) 1996-03-16
DE69115159T2 (de) 1996-08-01
JPH04505944A (ja) 1992-10-15
WO1991013118A1 (en) 1991-09-05

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