KR910009756A - α-올레핀-알케닐실란 공중합체 및 그 제조법 - Google Patents

α-올레핀-알케닐실란 공중합체 및 그 제조법 Download PDF

Info

Publication number
KR910009756A
KR910009756A KR1019900018414A KR900018414A KR910009756A KR 910009756 A KR910009756 A KR 910009756A KR 1019900018414 A KR1019900018414 A KR 1019900018414A KR 900018414 A KR900018414 A KR 900018414A KR 910009756 A KR910009756 A KR 910009756A
Authority
KR
South Korea
Prior art keywords
alkenylsilane
olefin
copolymer
measured
propylene
Prior art date
Application number
KR1019900018414A
Other languages
English (en)
Other versions
KR930004415B1 (ko
Inventor
타다시 아사누마
카오루 가와니시
Original Assignee
사와무라 하루오
미쓰이도오아쓰 가가쿠 가부시키가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 사와무라 하루오, 미쓰이도오아쓰 가가쿠 가부시키가이샤 filed Critical 사와무라 하루오
Publication of KR910009756A publication Critical patent/KR910009756A/ko
Application granted granted Critical
Publication of KR930004415B1 publication Critical patent/KR930004415B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F228/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
    • C08F230/08—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Abstract

내용 없음.

Description

α-올레핀 알케닐실란 공중합체 및 그 제조법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (7)

  1. 실질적으로 α-올레핀의 연쇄가 입체규칙성이고, 알케닐실란단위의 함량이 0.01-50wt%이며, 135℃테트라린 용액에서 측정한 극한 점도가 0.01 이상인 입체규칙성 α-올레핀-알케닐실란 공중합체.
  2. 시클로펜타디엔 혹은 그 유도체를 배위자로 하는 천이금속화합물과 알루미늄옥산에서 만들어지는 촉매를 사용하여 탄소수 3-25의 α-올레핀과 알케닐실란을 공중합시키는 것을 특징으로 하는 입체규칙성 α-올레핀-알케닐실란 공중합체 제조방법.
  3. 실질적으로 α-올레핀의 연쇄가 신디오탁틱 구조이고, 알케닐실란 단위의 함량이 0.01-50wt%이고, 135℃ 테트라린 용액에서 측정한 극한점도가 0.01 이상인 신디오탁틱 α-올레핀-알케닐실란 공중합체.
  4. 시클로펜타디엔 혹은 그 유도체에서 선택되는 비대칭적으로 상호 결합한 2개의 배위자를 갖는 천이금속화합물과 알루미늄옥산에서 만들어지는 촉매를 사용하여 α-올레핀과 알케닐실란을 공중합시키는 것을 특징으로 하는 신디오탁틱 α-올레핀-알케닐실란 공중합체 제조방법.
  5. 13C-NMR에서 측정한 프로필렌 단위의 메틸기에 귀속되는 피크중 약 20.2ppm에서 관측되는 피크의 강도가 프로필렌 단위에 귀속되는 전체 메틸기의 피크강도의 0.3이상, 알케닐실란 단위의 함량이 0.01-40wt%이고, 135℃ 테트라린 용액에서 측정한 극한점도가 0.01이상인 신디오탁틱프로필렌-알케닐실란 공중합체.
  6. 실질적으로 α-올레핀의 연쇄가 아이소탁틱 구조이고, 알케닐실란 단위의 함량이 0.01-50wt%이고, 135℃ 테트라린 용액에서 측정한 극한점도가 0.01 이상인 아이소탁틱 α-올레핀-알케닐실란 공중합체.
  7. 인데닐기, 혹은 그 수소화물, 혹은 알킬치환 시클로펜타디에닐기에서 선택된 상호 대칭으로 결합한 2개의 배위자를 갖는 천이금속화합물과 알루미늄옥산에서 만들어지는 촉매를 사용하여 프로필렌과 알케닐실란을 공중합시키는 것을 특징으로 하는 아이소탁틱 프로필렌-알케닐실란 공중합체 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900018414A 1989-11-28 1990-11-14 α-올레핀 알케닐실란 공중합체 및 그 제조법 KR930004415B1 (ko)

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
JP30640289 1989-11-28
JP306402 1989-11-28
JP1-306402 1989-11-28
JP30764489 1989-11-29
JP307644 1989-11-29
JP1-307644 1989-11-29
JP326169 1989-12-18
JP1-326169 1989-12-18
JP32616989 1989-12-18

Publications (2)

Publication Number Publication Date
KR910009756A true KR910009756A (ko) 1991-06-28
KR930004415B1 KR930004415B1 (ko) 1993-05-27

Family

ID=27338834

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019900018414A KR930004415B1 (ko) 1989-11-28 1990-11-14 α-올레핀 알케닐실란 공중합체 및 그 제조법

Country Status (7)

Country Link
US (1) US5334684A (ko)
EP (1) EP0430112B1 (ko)
JP (1) JP3024685B2 (ko)
KR (1) KR930004415B1 (ko)
CA (1) CA2030946C (ko)
DE (1) DE69018027T2 (ko)
ES (1) ES2071726T3 (ko)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0546690B1 (en) * 1991-11-12 1998-03-04 Nippon Oil Co. Ltd. Catalyst components for polymerization of olefins
EP1259556B1 (en) * 1999-07-29 2006-06-07 Dow Global Technologies Inc. Improved derivatives of silane functionalized olefin interpolymers
US7348388B2 (en) * 2001-11-16 2008-03-25 E.I. Du Pont De Nemours And Company Copolymers of olefins and vinyl- and allylsilanes
WO2012099882A2 (en) * 2011-01-19 2012-07-26 Dow Corning Corporation Method for producing silyl-functionalized polyolefins and silyl-functionalized polyolefins with silyl monomer incorporation
CN103012641A (zh) * 2012-12-31 2013-04-03 天津市职业大学 一种含有机硅的油品输送减阻剂的制备方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE574128A (ko) * 1957-12-23
US3125554A (en) * 1958-11-25 1964-03-17 Olefinic hydrocarbons
IT609922A (ko) * 1959-06-06
US3240768A (en) * 1961-06-09 1966-03-15 Exxon Research Engineering Co Copolymers of alpha olefin and reactive omega alkenyl silanes
GB1143570A (ko) * 1966-11-30
GB1415194A (en) * 1972-03-23 1975-11-26 Dow Corning Ltd Preparation of copolymers containing silicon
CA1312166C (en) * 1987-12-16 1992-12-29 Mitsui Chemicals, Incorporated Polyolefin resin composition
JP2667676B2 (ja) * 1988-07-11 1997-10-27 三井東圧化学株式会社 プロピレンの共重合体の製造方法
US4892851A (en) * 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
EP0363990A3 (en) * 1988-10-14 1991-09-11 Aristech Chemical Corporation Incorporation of functional groups in polymers
JP2974404B2 (ja) * 1989-12-28 1999-11-10 三井化学株式会社 新規な重合体およびそれを含むポリプロピレン樹脂組成物

Also Published As

Publication number Publication date
CA2030946A1 (en) 1991-05-29
JP3024685B2 (ja) 2000-03-21
ES2071726T3 (es) 1995-07-01
EP0430112A2 (en) 1991-06-05
JPH03231905A (ja) 1991-10-15
EP0430112A3 (en) 1992-01-08
DE69018027T2 (de) 1995-11-02
EP0430112B1 (en) 1995-03-22
US5334684A (en) 1994-08-02
KR930004415B1 (ko) 1993-05-27
DE69018027D1 (de) 1995-04-27
CA2030946C (en) 1996-12-03

Similar Documents

Publication Publication Date Title
KR970042568A (ko) 사이클로올레핀 공중합체의 제조방법
WO1990011305A1 (en) Styrenic copolymer and production thereof
KR880013990A (ko) 올레핀 중합용 고체촉매
KR890013064A (ko) 환상올레핀계 랜덤 공중합체 및 그 제조법
CA2147589A1 (en) Process for production of cyclic olefin copolymer and copolymer produced by said process
KR970706347A (ko) 에틸렌계 중합체 조성물
DE3856554D1 (de) Ungeordnete Cycloolefincopolymerzusammensetzungen und deren Anwendung
EP1008607A4 (en) PROPYLENE COPOLYMERS AND METHOD FOR THE PRODUCTION THEREOF
KR870004062A (ko) 저분자량의 에틸렌-알파올레핀 공중합체 중간물
KR850001231A (ko) 신규의 중합공정과 이로부터 제조되는 중합체
ATE38044T1 (de) Buten-1-polymer und seine verwendung.
KR940009217A (ko) 에틸렌 중합용 티타늄 촉매성분, 에틸렌 중합촉매 및 그를 사용한 에틸렌중합방법
SE7710705L (sv) Polymerisationsforfarande och katalysator
ATE18412T1 (de) Modifizierte copolymere von aethylen mit zumindest einem alpha-olefin und verfahren zu deren herstellung.
FI832012A0 (fi) Etylenpolymerblandningar avsedda foer framstaellning av filmer
TW331569B (en) Unsaturated copolymer based on olefin and production and use
AR246277A1 (es) Solido catalitico utilizable para la polimerizacion estereoespecifica de alfa-olefinas, procedimiento para prepararlo y procedimiento para polimerizar alfa-olefinas en su presencia.
FI893623A0 (fi) Dendritresistenta sammansaettningar.
KR890013063A (ko) 올레핀 중합용 촉매 및 올레핀의 중합방법
RO72800B (ro) Procedeu de polimerizare a alfa-olefinelor
KR970001378A (ko) 전이금속 화합물
KR910009756A (ko) α-올레핀-알케닐실란 공중합체 및 그 제조법
NO874493L (no) Kopolymerer av karbonmonoksyd og minst to aaa-oljefinisk umettede forbindelser, samt fremgangsmaate for fremstilling av slike kopolymerer.
KR940007046A (ko) 유기 전이금속착제
KR910018422A (ko) 신디오탁틱폴리프로필렌 공중합체의 제조방법 및 그것을 함유하는 수지조성물

Legal Events

Date Code Title Description
A201 Request for examination
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20100525

Year of fee payment: 18

EXPY Expiration of term