KR910007987A - 부텐-1 공중합체 및 이를 포함하는 수지조성물 - Google Patents

부텐-1 공중합체 및 이를 포함하는 수지조성물 Download PDF

Info

Publication number
KR910007987A
KR910007987A KR1019900015899A KR900015899A KR910007987A KR 910007987 A KR910007987 A KR 910007987A KR 1019900015899 A KR1019900015899 A KR 1019900015899A KR 900015899 A KR900015899 A KR 900015899A KR 910007987 A KR910007987 A KR 910007987A
Authority
KR
South Korea
Prior art keywords
copolymer
butene
propylene
resin composition
side chain
Prior art date
Application number
KR1019900015899A
Other languages
English (en)
Other versions
KR930004273B1 (ko
Inventor
타다시 아사누마
테츠노스케 시오무라
타테요 사사키
Original Assignee
사와무라 하루오
미쓰이도오아쓰 가가쿠 가부시키가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 사와무라 하루오, 미쓰이도오아쓰 가가쿠 가부시키가이샤 filed Critical 사와무라 하루오
Publication of KR910007987A publication Critical patent/KR910007987A/ko
Application granted granted Critical
Publication of KR930004273B1 publication Critical patent/KR930004273B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Abstract

내용 없음.

Description

부텐-1 공중합체 및 이를 포함하는 수지조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 부텐-1가 프로필렌의 공중합체에 있어서, 13c-NMR에 의하여 1,2,4-트리클로로벤젠 용액의 형태로 측정된 상기 공중합체의 부텐-1 유닛트의 측쇄 메틸렌기에 대한 흡수중에서, 테트라메틸실란을 기준으로 26.9ppm에서 관측되는 흡수강도가 테트라메틸실란을 기준으로 27.8-26.0ppm에서 관측된 측쇄 메틸렌기의 전체 흡수강도의 0.3이상이며, 프로필렌 유닛트의 함량은 0.1wt.%와 20wt.%의 범위에 있으며, 테트랄린 용액에서 측정된 135℃에서의 고유점성도는 0.05이상임을 특징으로 하는 부텐-1과 프로필렌의 공중합체.
  2. 제1항에 있어서, 프로필렌 유닛트의 함량은 1wt.%-20wt.%의 범위내에 있음을 특징으로 하는 공중합체.
  3. 제1항에 있어서, 공중합체는 프로필렌의 겔 투과 크로마토그래피에 의하여 측정되어 수평균 분자량이 1000이상임을 특징으로 하는 공중합체.
  4. 제1항에 있어서, 공중합체의 중량평균분자량대 수평균분자량의 비는 1.5-10임을 특징으로 하는 공중합체.
  5. 98-80wt.% 프로필렌 유닛트, 4-12개의 탄소원자를 지니는 0-18wt.%의 α-올레핀 유닛트, 2-20wt.% 에틸렌 유닛트로 구성되고 230℃에서의 용융유동지수가 0.1-100g/10분인 입체규칙성이고 결정성 폴리프로필렌 95-50중량부와, 13c-NMR로 1,2,4-트리클로로벤젠 용액의 형태로 측정된 부텐-1과 프로필렌의 공중합체의 부텐-1을 유닛트중 측쇄 메틸렌기에 대한 흡수중에서 테트라메틸실란을 기준으로 26.9ppm에서 관측된 흡수강도가 테트라메틸실란을 기준으로 27.8-26.0ppm에서 관측된 측쇄메틸기의 전체 흡수강도의 0.3이상이며, 프로필렌 유닛트의 함량은 0.1wt.%-20wt.%의 범위에 있으며 테트랄린 용액에서 측정된 135℃에서의 고유점성도는 0.05이상인 부텐-1과 프로필렌의 공중합체 5-50wt.%로 구성됨을 특징으로 하는 쉽게 열접착되는 폴리프로필렌수지.
  6. 제5항에 있어서, 입체규칙성이고 결정성인 폴리프로필렌 90-60wt.%와 부텐-1 공중합체 10-40wt.%로 구성됨을 특징으로 하는 수지 조성물.
  7. 제5항에 있어서, 입체규칙성이고 결정성인 폴리프로필렌은 이소택틱구조임을 특징으로 하는 수지 조성물.
  8. 제5항에 있어서, 입체규칙성이고 결정성인 폴리프로필렌은 신디오택틱 구조임을 특징으로 하는 수지조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900015899A 1989-10-06 1990-10-06 부텐-i 공중합체 및 이를 포함하는 수지조성물 KR930004273B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP1-260202 1989-10-06
JP26020289 1989-10-06

Publications (2)

Publication Number Publication Date
KR910007987A true KR910007987A (ko) 1991-05-30
KR930004273B1 KR930004273B1 (ko) 1993-05-22

Family

ID=17344755

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019900015899A KR930004273B1 (ko) 1989-10-06 1990-10-06 부텐-i 공중합체 및 이를 포함하는 수지조성물

Country Status (6)

Country Link
US (1) US5206324A (ko)
EP (2) EP0422498B1 (ko)
KR (1) KR930004273B1 (ko)
CA (1) CA2026896C (ko)
DE (2) DE69032273T2 (ko)
ES (2) ES2115829T3 (ko)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0669348B1 (en) * 1994-02-25 1998-06-10 Sumitomo Chemical Company Limited Propylene random copolymer and film laminate thereof
JPH07330829A (ja) * 1994-06-09 1995-12-19 Sumitomo Chem Co Ltd シンジオタクチック構造を有する結晶性プロピレン／１−ブテン共重合体
CA2395532A1 (en) 1999-12-22 2001-06-28 A. G. Karandinos Polypropylene-based adhesive compositions
US7067603B1 (en) 1999-12-22 2006-06-27 Exxonmobil Chemical Patents Inc. Adhesive alpha-olefin inter-polymers
KR20070084308A (ko) 2004-11-25 2007-08-24 미쓰이 가가쿠 가부시키가이샤 프로필렌계 수지 조성물 및 그 용도
DE102008005945A1 (de) 2008-01-24 2009-07-30 Evonik Degussa Gmbh Verfahren zur Herstellung von Polyolefinen mit syndiotaktischen Strukturelementen, Polyolefine und deren Verwendung
US8735498B2 (en) 2009-11-17 2014-05-27 Basell Poliolefine Italia S.R.L. Soft polyolefin compositions with improved processability
JP5695076B2 (ja) 2009-11-24 2015-04-01 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ 改良したシール性を示すポリオレフィン組成物
SG11201501899UA (en) * 2012-09-14 2015-05-28 Mitsui Chemicals Inc 1-BUTENE • a-OLEFIN COPOLYMER COMPOSITION
WO2016018523A1 (en) * 2014-07-31 2016-02-04 Exxonmobil Chemical Patents Inc. Syndiotactic propylene polymers and lubricating oils comprising the same
US20230357550A1 (en) * 2022-05-03 2023-11-09 Equistar Chemicals, Lp Polyolefin compositions and products

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3332921A (en) * 1963-11-01 1967-07-25 Phillips Petroleum Co 1-butene-propylene copolymers
US3464962A (en) * 1965-06-07 1969-09-02 Mobil Oil Corp Copolymers of butene-1 and propylene
JPS6038414A (ja) * 1983-08-12 1985-02-28 Mitsui Petrochem Ind Ltd 熱可塑性樹脂共重合体
US4726999A (en) * 1984-10-31 1988-02-23 Shell Oil Company Laminated structure comprising a substrate layer composed of a crystalline propylene resin and a heat-sealable layer composed of a crystalline propylene random copolymer composition
JPH06104699B2 (ja) * 1985-11-20 1994-12-21 三井石油化学工業株式会社 １―ブテン系ランダム共重合体およびそれからなる熱可塑性樹脂用ヒートシール性改善剤
EP0233400B1 (en) * 1985-11-25 1992-07-15 Shell Oil Company Butene-1/propylene copolymer blends
CN1018926B (zh) * 1987-07-14 1992-11-04 出光石油化学株式会社 丁烯-1共聚物组合物
MY103812A (en) * 1988-02-12 1993-09-30 Mitsui Chemicals Inc Olefin polymerization catalyst and process for the polymerization of olefins.
CA1308857C (en) * 1988-03-30 1992-10-13 Brian J. Pellon Propylene copolymerization process
US4892851A (en) * 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins

Also Published As

Publication number Publication date
DE69025531D1 (de) 1996-04-04
ES2115829T3 (es) 1998-07-01
DE69032273D1 (de) 1998-05-28
EP0422498A3 (en) 1992-11-25
DE69032273T2 (de) 1998-09-17
EP0627464B1 (en) 1998-04-22
CA2026896C (en) 1995-08-01
EP0422498B1 (en) 1996-02-28
EP0422498A2 (en) 1991-04-17
EP0627464A2 (en) 1994-12-07
ES2084632T3 (es) 1996-05-16
US5206324A (en) 1993-04-27
DE69025531T2 (de) 1996-09-26
KR930004273B1 (ko) 1993-05-22
EP0627464A3 (en) 1995-02-22

Similar Documents

Publication Publication Date Title
DE69303881D1 (de) Polypropylene Zusammensetzung mit guter Durchsichtigkeit und Schlagfestigkeit
KR950005896A (ko) 치수 안정성을 갖는 고체 폴리머 배합물과 이를 함유하는 윤활유 조성물
KR910011922A (ko) 내 방사선 폴리프로필렌 수지 조성물
KR910007987A (ko) 부텐-1 공중합체 및 이를 포함하는 수지조성물
KR950003369A (ko) 폴리프로필렌 수지조성물 및 그 용도
KR920702710A (ko) 핫멜트 접착제
TW357177B (en) Composition of irradiated and non-irradiated olefin polymer materials with reduced gloss
RU2002105980A (ru) Полиолефиновая композиция, содержащая пропиленовый гомополимер низкой вязкости, волокно и растяжимый нетканый материал, получаемый из него
KR950005897A (ko) 강성과 내충격강도가 잘 조화된 폴리올레핀 조성물
ES2146563T3 (es) Composiciones de polimero de etileno y articulo fabricado a partir de las mismas.
ATE38044T1 (de) Buten-1-polymer und seine verwendung.
KR880001729A (ko) 폴리프로필렌 다층 필름
KR910009977A (ko) 폴리올레핀을 섬광 방사시키는 방법
KR950011419A (ko) 광택이 감소된 프로필렌 중합체 물질과 올레핀 중합체 물질의 조성물
KR920000854A (ko) 에틸렌/펜텐- 1 공중합체 조성물 및 그의 용도
ES8706764A1 (es) Procedimiento para la preparacion de composiciones polimericas aptas para utilizarse como aditivos en bitumen
FI832012L (fi) Etylenpolymerblandningar avsedda foer framstaellning av filmer
KR940007121A (ko) 비튜멘 및 비튜멘의 개질용으로 적당한 중합체 조성물의 혼합물
KR890010057A (ko) 부텐-i중합체계 필름 및 그 적층필름
KR930701502A (ko) 폴리프로필렌계 수지 및 그의 조성물
KR900003273A (ko) 개선된 굴곡 특성을 갖는 도장성 열가소성 폴리올레핀 조성물
KR920700262A (ko) 2성분 폴리프로필렌/폴리에틸렌 접착섬유
KR910004348A (ko) 불투명한 적층연산물 및 그것의 제조방법
EP0171199A3 (en) Crystalline polypropylene sheet
KR930019747A (ko) 가황 고무 조성물

Legal Events

Date Code Title Description
A201 Request for examination
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20040507

Year of fee payment: 12

LAPS Lapse due to unpaid annual fee