KR910006519A - 파라-아미노페놀의 제조방법 - Google Patents

파라-아미노페놀의 제조방법 Download PDF

Info

Publication number
KR910006519A
KR910006519A KR1019890012903A KR890012903A KR910006519A KR 910006519 A KR910006519 A KR 910006519A KR 1019890012903 A KR1019890012903 A KR 1019890012903A KR 890012903 A KR890012903 A KR 890012903A KR 910006519 A KR910006519 A KR 910006519A
Authority
KR
South Korea
Prior art keywords
electrode
spe
rde
copper
aminophenol
Prior art date
Application number
KR1019890012903A
Other languages
English (en)
Other versions
KR910005058B1 (ko
Inventor
윤경석
조병원
Original Assignee
박원희
한국과학기술연구원
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 박원희, 한국과학기술연구원 filed Critical 박원희
Priority to KR1019890012903A priority Critical patent/KR910005058B1/ko
Priority to US07/460,625 priority patent/US5066369A/en
Priority to CN90100499A priority patent/CN1038053C/zh
Priority to DE4003004A priority patent/DE4003004A1/de
Priority to JP2233447A priority patent/JPH03100191A/ja
Publication of KR910006519A publication Critical patent/KR910006519A/ko
Application granted granted Critical
Publication of KR910005058B1 publication Critical patent/KR910005058B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/25—Reduction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C213/02—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reactions involving the formation of amino groups from compounds containing hydroxy groups or etherified or esterified hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C25B11/034—Rotary electrodes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • C25B9/23—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms comprising ion-exchange membranes in or on which electrode material is embedded
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/30—Cells comprising movable electrodes, e.g. rotary electrodes; Assemblies of constructional parts thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음.

Description

파라-아미노페놀의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명의 제조과정을 개략적으로 보인 공정도.
제2도는 본 발명의 실시에 사용되는 전해조의 구조를 예시한 평면도.
제3도는 제2도의 종단면도.

Claims (8)

  1. 니트로벤젠으로부터 파라-아미노페놀을 전해합성함에 있어서, 다수의 원판전극으로 이루어진 RDE와 SPE 전극을 일전극으로 하여 용매나 계면활성제 없이 황산 1.5-3.0M 및 니트로벤젠 0.5-2.0M의 농도를 갖는 음극실용액을 전해합성하여 제조함을 특징으로 하는 파라-아미노페놀의 제조방법.
  2. 제1항에 있어서, RDE의 재질이 흑연, 구리, 비스무트로 피복된 흑연, 아말감구리 또는 비스무트로 피복된 구리인 것을 특징으로 하는 파라-아미노페놀의 제조방법.
  3. 제1항에 있어서, SPE 전극이 SPE 구리, 비스무트전극, SPE 구리전극, 또는 SPE 비스무트전극인 것을 특징으로 하는 파라-아미노페놀의 제조방법.
  4. 제1항에 있어서, RDE의 전류밀도는 20-20mA/Cm2이고 SPE 전극의 전류밀도는 RDE 전류밀도의 1/5-1/100인 것을 특징으로 하는 파라-아미노페놀의 제조방법.
  5. 제1항에 있어서, 전해온도가 80-95℃인 것을 특징으로 하는 파라-아미노페놀의 제조방법.
  6. 제1항에 있어서, RDE의 회전속도가 300-3600rpm인 것을 특징으로 하는 파라-아미노페놀의 제조방법.
  7. 제1항에 있어서, 양극으로 Pb-Ag 또는 DSA(Ti/IrO2) 전극을 사용함을 특징으로 하는 파라-아미노페놀의 제조방법.
  8. 제1항에 있어서, 전해완결여부를 음극의 기준전극에 대한 전위상승으로 측정함을 특징으로 하는 파라-아미노페놀의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890012903A 1989-09-06 1989-09-06 파라-아미노페놀의 제조방법 KR910005058B1 (ko)

Priority Applications (5)

Application Number Priority Date Filing Date Title
KR1019890012903A KR910005058B1 (ko) 1989-09-06 1989-09-06 파라-아미노페놀의 제조방법
US07/460,625 US5066369A (en) 1989-09-06 1990-01-03 Process for preparing para-aminophenol
CN90100499A CN1038053C (zh) 1989-09-06 1990-01-30 制备对氨基苯酚用方法
DE4003004A DE4003004A1 (de) 1989-09-06 1990-02-01 Verfahren zur herstellung von p-aminophenol aus nitrobenzol
JP2233447A JPH03100191A (ja) 1989-09-06 1990-09-05 パラ―アミノフェノールの製造方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019890012903A KR910005058B1 (ko) 1989-09-06 1989-09-06 파라-아미노페놀의 제조방법

Publications (2)

Publication Number Publication Date
KR910006519A true KR910006519A (ko) 1991-04-29
KR910005058B1 KR910005058B1 (ko) 1991-07-22

Family

ID=19289691

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019890012903A KR910005058B1 (ko) 1989-09-06 1989-09-06 파라-아미노페놀의 제조방법

Country Status (5)

Country Link
US (1) US5066369A (ko)
JP (1) JPH03100191A (ko)
KR (1) KR910005058B1 (ko)
CN (1) CN1038053C (ko)
DE (1) DE4003004A1 (ko)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101100759B (zh) * 2007-08-15 2010-04-07 安徽天润得生物工程有限公司 电还原制备医药中间体乙酰氨基丙二酸二乙酯
KR102229442B1 (ko) * 2016-09-22 2021-03-17 주식회사 엘지화학 수계 레독스 플로우 전지용 유기계 양극 활물질
CN112501641B (zh) * 2020-11-30 2021-09-03 苏州大学张家港工业技术研究院 一种电催化制备偶氮苯和氧化偶氮苯类化合物的方法
CN114481173B (zh) * 2022-03-01 2023-06-13 哈尔滨工业大学（深圳） 一种苯胺衍生物的制备方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1501472A (en) * 1920-01-24 1924-07-15 Charles J Thatcher Process of producing paramidophenol and its compounds
US1536419A (en) * 1922-01-26 1925-05-05 Arthur W Burwell Process of effecting organic reactions
US2925371A (en) * 1956-06-01 1960-02-16 Carwin Company Electrolytic cell
US2998450A (en) * 1958-05-19 1961-08-29 Warner Lambert Pharmaceutical Process of preparing nu-acetyl-p-amino phenol
US3338806A (en) * 1961-08-21 1967-08-29 Continental Oil Co Process of preparing p-aminophenol by electrolytically reducing nitrobenzene
GB1308042A (en) * 1969-05-28 1973-02-21 Brown John Constr Process for the preparation of rho-amino phenol by the electrolytic reduction of nitrobenzene
US4386987A (en) * 1981-06-26 1983-06-07 Diamond Shamrock Corporation Electrolytic cell membrane/SPE formation by solution coating
US4445985A (en) * 1983-03-25 1984-05-01 Ppg Industries, Inc. Electro organic method and apparatus for carrying out same
US4584070A (en) * 1985-03-29 1986-04-22 Ppg Industries, Inc. Process for preparing para-aminophenol

Also Published As

Publication number Publication date
CN1038053C (zh) 1998-04-15
KR910005058B1 (ko) 1991-07-22
DE4003004C2 (ko) 1992-04-09
CN1050057A (zh) 1991-03-20
US5066369A (en) 1991-11-19
JPH03100191A (ja) 1991-04-25
DE4003004A1 (de) 1991-03-14

Similar Documents

Publication Publication Date Title
KR830005397A (ko) 개량된 전극
JPH0722075B2 (ja) 固体電解コンデンサの半導体層形成方法
ES464252A1 (es) Procedimiento mejorado para preparar un electrodo.
JPS526374A (en) Anode structure for electrolysis
JPH0336916B2 (ko)
KR910006519A (ko) 파라-아미노페놀의 제조방법
GB1472028A (en) Process for the manufacture of electrodes for electrolytic purposes and electrodes so manufactured
KR940013301A (ko) 전해에 의한 금속 포일 제조 방법
ATE103883T1 (de) Verfahren zur herstellung von feinteiligem, elektrisch leitfaehigem zinn-iv-oxid.
JPH02213487A (ja) 電解二酸化マンガンの製造法
US2572079A (en) Radiation-sensitive cells and method of making same
Reddy et al. Electrochemical reduction of DDT at the hanging mercury drop electrode
Liu et al. Oxygen overvoltage on SnO2-based anodes in Naf AlF3 Al2O3 melts. Electrocatalytic effects of doping agents
KR850700045A (ko) 전기 야금 공정용 전극
JPH0336910B2 (ko)
SU585236A1 (ru) Электрохимический способ получени надсерной кислоты
SU380106A1 (ko)
US935250A (en) Electrolytic winning of zinc from solutions of zinc sulfate.
EP0032787A3 (en) Method of manufacturing a catalytic electrode and a fuel cell containing an electrode manufactured by the method
JPS5798685A (en) Electrolytic production of cysteine having high purity
SU827600A1 (ru) Способ получени неорганическогопЕРЕКиСНОгО СОЕдиНЕНи
JPS54134088A (en) Preparation of manganese dioxide catalyst
SU582245A1 (ru) Способ получени 4-аминодифениламина
SU143391A1 (ru) Способ получени изомасл ной кислоты
JPS57143481A (en) Manufacture of 3-phenyl-1-propanols

Legal Events

Date Code Title Description
A201 Request for examination
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 19970619

Year of fee payment: 7

LAPS Lapse due to unpaid annual fee