KR900018223A - 시안아미드를 함유하는 에폭사이드 경화제에 대한 촉진제 - Google Patents
시안아미드를 함유하는 에폭사이드 경화제에 대한 촉진제 Download PDFInfo
- Publication number
- KR900018223A KR900018223A KR1019890006003A KR890006003A KR900018223A KR 900018223 A KR900018223 A KR 900018223A KR 1019890006003 A KR1019890006003 A KR 1019890006003A KR 890006003 A KR890006003 A KR 890006003A KR 900018223 A KR900018223 A KR 900018223A
- Authority
- KR
- South Korea
- Prior art keywords
- promoter
- curing agent
- accelerator
- promoter according
- epoxide
- Prior art date
Links
- 150000002118 epoxides Chemical class 0.000 title claims 4
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 title claims 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims 6
- 239000003795 chemical substances by application Substances 0.000 claims 3
- 150000007524 organic acids Chemical class 0.000 claims 3
- 150000008065 acid anhydrides Chemical class 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims 2
- 239000007787 solid Substances 0.000 claims 2
- 125000001424 substituent group Chemical group 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 238000001816 cooling Methods 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 235000005985 organic acids Nutrition 0.000 claims 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
- 229960004889 salicylic acid Drugs 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
- C08G59/686—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
- C08G59/4014—Nitrogen containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Epoxy Resins (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (14)
- (a)하기 일반식의 이미다졸과 (b)0.5 내지 5.0의PKA치를 갖는 유기산의 부가물 및/또는 반응 생성물을 사용하는 시안아미드를 함유하는 에폭사이드 경화제에 대한 촉진제.상기식에서, R1,R2,R3및 R4는 수소이거나, 또는 탄소수 1내지 3의 알킬, 또는 페닐이다.
- 제1항에 있어서, 이미다졸의 알킬 래디칼이 불포화된 촉진제.
- 제1항 또는 제2항에 있어서, 알킬 및/또는 페닐 래디칼이 치환된 촉진제.
- 제3항에 있어서, 알킬 래디칼에 대한 치환체(들)가 CH, OH, OCH3, 페닐 또는 방향족 헤테로 사이클인 촉진제.
- 제3항에 있어서, 페닐 래디칼에 대한 치환체(들)가 OH, OCH3, NH2할로겐 또는 CN인 촉진제.
- 제1항 내지 제5항중 어느 한 항에 있어서, 살리실산이 유기산으로 사용된 촉진제.
- 제1항 내지 제5항중 어느 한 항에 있어서, 유기산 대신 이의 염 및/또는 산 무수물이 사용된 촉진제.
- 제7항에 있어서, 말레인산 무수물이 산 무수물로 사용된 촉진제.
- 성분 a) 및 b)를 고체 상태로 철저히 혼합시키고, 필요할 경우 계속해서 분쇄시켜, 제1항 내지 제8항중 어느 한항에 따르는 촉진제를 제조하는 방법.
- 성분 a) 및 b)를 고체 상태로 철저히 혼합시킨 후, 용융 가열시키고, 필요할 경우 냉각시킨 후 분쇄시켜, 제1항 내지 제8항중 어느 한 항에 따르는 촉진제를 제조하는 방법.
- 성분 a) 및 b)를 가열하면서 적합한 용매에 용해시키고, 생성물을 냉각하면서 결정화시켜, 제1항 내지 제8항중 어느 한 항에 따르는 촉진제를 제조하는 방법.
- 경화제로서 시안아미드를 사용하여, 경화제를 기준으로 하여 1내지 10중량%의 양으로 에폭사이드를 경화시키기 위한 제1항 내지 제8항중 어느 한 항에 따르는 촉진제의 용도.
- 제12항에 있어서, 입자 크기<150㎛를 갖는, 촉진제의 용도.
- 제12항 또는 제13항에 있어서, 에폭사이드의 경화를 100내지 200℃, 바람직하게는 140내지 180℃의 온도에서 수행하는 용도.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP3815234.7 | 1988-05-05 | ||
DE3815234A DE3815234A1 (de) | 1988-05-05 | 1988-05-05 | Beschleuniger fuer cyanamid enthaltende epoxidhaerter |
Publications (1)
Publication Number | Publication Date |
---|---|
KR900018223A true KR900018223A (ko) | 1990-12-20 |
Family
ID=6353647
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019890006003A KR900018223A (ko) | 1988-05-05 | 1989-05-04 | 시안아미드를 함유하는 에폭사이드 경화제에 대한 촉진제 |
Country Status (4)
Country | Link |
---|---|
US (1) | US4933422A (ko) |
JP (1) | JPH01318034A (ko) |
KR (1) | KR900018223A (ko) |
DE (1) | DE3815234A1 (ko) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5001211A (en) * | 1989-10-26 | 1991-03-19 | Texaco Chemical Company | Salicylate of 1-isopropyl-2-methyl imidazole as an epoxy resin curative |
GB9112051D0 (en) * | 1991-06-05 | 1991-07-24 | Shell Int Research | Epoxy resin powder coating composition |
EP0523001A1 (de) * | 1991-06-20 | 1993-01-13 | Ciba-Geigy Ag | Härtbare Epoxidharz-Zusammensetzung enthaltend einen blockierten Beschleuniger |
US5620831A (en) * | 1994-04-05 | 1997-04-15 | Taiyo Ink Manufacturing Co., Ltd. | Cyanoguanidine derivatives, and thermosetting or photocurable, thermosetting resin composition using the same |
CN101613321A (zh) * | 2002-03-05 | 2009-12-30 | 特兰斯泰克制药公司 | 抑制配体与高级糖化终产物受体相互作用的单和双环吡咯衍生物 |
WO2005000295A1 (en) * | 2003-05-20 | 2005-01-06 | Transtech Pharma, Inc. | Rage antagonists as agents to reverse amyloidosis and diseases associated therewith |
DE102005024255A1 (de) * | 2005-05-27 | 2006-11-30 | Henkel Kgaa | Imidazol-Salze, Verfahren zu ihrer Herstellung, ihre Verwendung und diese Salze enthaltende Epoxidharze |
DK200500840A (da) * | 2005-06-09 | 2006-12-10 | Banke Stefan Ovesen | Raman minispektrometer tilpasset SSRS metode |
CA2772797C (en) | 2009-09-30 | 2018-09-25 | Transtech Pharma, Inc. | Substituted imidazole derivatives |
EP2678368B1 (de) | 2011-02-23 | 2015-05-06 | AlzChem AG | Neue härter für epoxidharze |
WO2014020072A2 (de) * | 2012-08-02 | 2014-02-06 | Alzchem Ag | Flüssige härter zur härtung von epoxidharzen (ii) |
WO2018119250A1 (en) * | 2016-12-21 | 2018-06-28 | Huntsman Advanced Materials Licensing (Switzerland) Gmbh | Latent curing accelerators |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4358571A (en) * | 1981-03-10 | 1982-11-09 | Mobil Oil Corporation | Chemically modified imidazole curing catalysts for epoxy resin and powder coatings containing them |
-
1988
- 1988-05-05 DE DE3815234A patent/DE3815234A1/de not_active Withdrawn
-
1989
- 1989-05-02 JP JP1112281A patent/JPH01318034A/ja active Pending
- 1989-05-04 KR KR1019890006003A patent/KR900018223A/ko not_active Application Discontinuation
- 1989-05-15 US US07/351,789 patent/US4933422A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JPH01318034A (ja) | 1989-12-22 |
US4933422A (en) | 1990-06-12 |
DE3815234A1 (de) | 1989-11-16 |
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WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |