KR900012951A - 내산소성 및 내수성 dcpd중합촉매인 불연속 텅스텐 착물 - Google Patents
내산소성 및 내수성 dcpd중합촉매인 불연속 텅스텐 착물 Download PDFInfo
- Publication number
- KR900012951A KR900012951A KR1019900002281A KR900002281A KR900012951A KR 900012951 A KR900012951 A KR 900012951A KR 1019900002281 A KR1019900002281 A KR 1019900002281A KR 900002281 A KR900002281 A KR 900002281A KR 900012951 A KR900012951 A KR 900012951A
- Authority
- KR
- South Korea
- Prior art keywords
- carbon atoms
- oxygen
- alkyl group
- polymerization catalyst
- water resistant
- Prior art date
Links
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 title claims 4
- 229910052721 tungsten Inorganic materials 0.000 title claims 4
- 239000010937 tungsten Substances 0.000 title claims 4
- HECLRDQVFMWTQS-UHFFFAOYSA-N Dicyclopentadiene Chemical compound C1C2C3CC=CC3C1C=C2 HECLRDQVFMWTQS-UHFFFAOYSA-N 0.000 title 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title 1
- 229910052760 oxygen Inorganic materials 0.000 title 1
- 239000001301 oxygen Substances 0.000 title 1
- 239000002685 polymerization catalyst Substances 0.000 title 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title 1
- -1 4-ethoxyphenoxy Chemical group 0.000 claims 10
- 125000004432 carbon atom Chemical group C* 0.000 claims 5
- 125000000217 alkyl group Chemical group 0.000 claims 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 2
- 239000012190 activator Substances 0.000 claims 2
- 239000003054 catalyst Substances 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 2
- UGRMITBWUVWUEB-UHFFFAOYSA-N 1-$l^{1}-oxidanyl-3-methylbenzene Chemical group CC1=CC=CC([O])=C1 UGRMITBWUVWUEB-UHFFFAOYSA-N 0.000 claims 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 claims 1
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 239000012018 catalyst precursor Substances 0.000 claims 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims 1
- DBGVGMSCBYYSLD-UHFFFAOYSA-N tributylstannane Chemical compound CCCC[SnH](CCCC)CCCC DBGVGMSCBYYSLD-UHFFFAOYSA-N 0.000 claims 1
- NFHRNKANAAGQOH-UHFFFAOYSA-N triphenylstannane Chemical compound C1=CC=CC=C1[SnH](C=1C=CC=CC=1)C1=CC=CC=C1 NFHRNKANAAGQOH-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
- C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
- C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
- B01J31/0214—Aryloxylates, e.g. phenolates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/122—Metal aryl or alkyl compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/66—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/34—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of chromium, molybdenum or tungsten
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polyethers (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (3)
- 순수한 디시크로펜타디엔을 텅스텐함유 촉매전구체 및 일반식 R3SnH (여기에서, R은 1내지 10의 탄소원자를 갖는 알킬기 또는 페닐기이다)의 주석활성화제 화합물과 접촉시키는 것으로 구성되는 중합체의 제조방법에 있어서, 상기 촉매가 하기 일반식의 거의 순수한 텅스텐 착물인 것을 특징으로 하는 방법 :식중, X는C1 또는 Br이고, n은 2 또는 3이며, R1은 H, C1 1내지 10의 탄소원자를 갖는 알킬기, 1내지 8의 탄소원자를 갖는 알콕시기 또는 페닐기이고, R2는 또는 1내지 9의 탄소원자를 갖는 알킬기이며, R3는 H또는 1내지 10의 탄소원자를 갖는 알킬기이다.
- 제1항에 있어서, 상기 텅스텐 촉매착물이 WC12(4-에톡시페녹시)4, WC12(4-부톡시페녹시)4, WC13(2,6-디-t-부틸페녹시)3, WC12(페녹시)4, WC12(3-메틸페녹시)4, WC12(4-메틸페녹시), WC12(3.5-디메틸페녹시)4, WC12(4-부틸페녹시)4, WC12(4-클로로페녹시)4, WC13(2,6-디메틸페녹시)4, WC12(2,4,6-트리메틸페녹시)3, WC12(4-페닐페녹시)4, WC12(4-메톡시페녹시)4, 및 WC12(2,6-디-이소플필페녹시)3,로 이루어지는 군에서 선택되는 것을 특징으로 하는 방법.
- 제1항 또는 제2항에 있어서, 상기 주석활성화제 화합물이 트리-n-부틸주석 히드라이드 또는 트리페닐주석 히드라이드인 것을 특징으로 하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US315.075 | 1989-02-24 | ||
US07/315,075 US4981931A (en) | 1989-02-24 | 1989-02-24 | Discrete tungsten complexes as oxygen and water resistant DCPD polymerization catalysts |
Publications (1)
Publication Number | Publication Date |
---|---|
KR900012951A true KR900012951A (ko) | 1990-09-03 |
Family
ID=23222777
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019900002281A KR900012951A (ko) | 1989-02-24 | 1990-02-23 | 내산소성 및 내수성 dcpd중합촉매인 불연속 텅스텐 착물 |
Country Status (8)
Country | Link |
---|---|
US (1) | US4981931A (ko) |
EP (1) | EP0385274A3 (ko) |
JP (1) | JPH03729A (ko) |
KR (1) | KR900012951A (ko) |
AU (1) | AU628134B2 (ko) |
BR (1) | BR9000846A (ko) |
CA (1) | CA2010779A1 (ko) |
MX (1) | MX166334B (ko) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5218065A (en) * | 1991-08-30 | 1993-06-08 | Shell Oil Company | Polymerization process |
US5198511A (en) * | 1991-12-20 | 1993-03-30 | Minnesota Mining And Manufacturing Company | Polymerizable compositions containing olefin metathesis catalysts and cocatalysts, and methods of use therefor |
USH1388H (en) * | 1992-12-23 | 1994-12-06 | Hercules Incorporated | Polyolefin polymer and method of making same |
CA2112146A1 (en) * | 1992-12-23 | 1994-06-24 | Nitya P. Khasat | Polydicyclopentadiene having improved stability and toughened with polymeric particles |
US5276118A (en) * | 1992-12-31 | 1994-01-04 | Shell Oil Company | Diaryl carbinol metathesis catalysts for ring-opening polymerization of cyclic olefins |
US5278305A (en) * | 1992-12-31 | 1994-01-11 | Shell Oil Company | Catalysts for ring-opening, metathesis polymerization of cyclic olefins |
WO1994023836A1 (en) * | 1993-04-08 | 1994-10-27 | E.I. Du Pont De Nemours And Company | Catalyst composition and process for the production of unsaturated diesters |
JP2006117862A (ja) * | 2004-10-25 | 2006-05-11 | Nippon Zeon Co Ltd | ノルボルネン系開環重合体水素化物の製造方法 |
WO2008010973A1 (en) * | 2006-07-18 | 2008-01-24 | Dow Global Technologies, Inc. | Method for preparing poly(dicyclopentadiene) |
WO2013083172A1 (en) | 2011-12-05 | 2013-06-13 | Blue Wave Co S.A. | Method of fabricating a pressure vessel using a variable viscosity solventless prepolymer formulation |
US8859666B2 (en) | 2011-12-05 | 2014-10-14 | Spencer Composites Corporation | Variable viscosity solventless prepolymer formulation |
CN103242511B (zh) * | 2013-05-07 | 2015-07-01 | 黎明化工研究设计院有限责任公司 | 一种高效稳定的催化体系及其在环烯烃聚合配方中的应用 |
CN103665700B (zh) * | 2013-08-27 | 2015-10-07 | 河南科技大学 | 一种聚双环戊二烯复合材料及其制备方法 |
WO2015047009A1 (ko) * | 2013-09-30 | 2015-04-02 | 코오롱인더스트리 주식회사 | 환상올레핀계 고분자 화합물의 개환중합용 촉매 및 이를 이용한 환상올레핀계 고분자 화합물의 제조방법 |
KR101601493B1 (ko) * | 2013-09-30 | 2016-03-09 | 코오롱인더스트리 주식회사 | 환상올레핀계 고분자 화합물의 개환중합용 촉매 및 이를 이용한 환상올레핀계 고분자 화합물의 제조방법 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0084888B2 (en) * | 1982-01-25 | 1995-10-25 | Hercules Incorporated | A dicyclopentadiene thermoset polymer and a catalyst and a method for making it |
DE3460103D1 (en) * | 1983-06-15 | 1986-05-28 | Elf Aquitaine | Catalyst for olefin methathesis |
US4598102A (en) * | 1983-11-17 | 1986-07-01 | Hercules Incorporated | Method, composition and product produced by delayed gelation in the polymerization of cycloolefins |
GB8526539D0 (en) * | 1985-10-28 | 1985-12-04 | Shell Int Research | Bulk polymerization of dicyclopentadiene |
FR2603041B1 (fr) * | 1986-08-22 | 1988-12-02 | Elf Aquitaine | Polymerisation d'hydrocarbures insatures avec une periode d'induction |
FR2612422B1 (fr) * | 1987-03-20 | 1993-06-11 | Elf Aquitaine | Systemes catalytiques perfectionnes a duree de vie et de conservation prolongees pour la metathese d'olefines |
US4826942A (en) * | 1987-05-18 | 1989-05-02 | Hercules Incorporated | Process for preparing molded objects using a rate moderated two component metathesis catalyst system |
KR900007878A (ko) * | 1988-11-30 | 1990-06-02 | 오노 알버어스 | 촉매 조성물, 그를 사용한 시클릭 올레핀의 금형내의 중합방법 및 그로부터 제조된 중합체 |
-
1989
- 1989-02-24 US US07/315,075 patent/US4981931A/en not_active Expired - Fee Related
-
1990
- 1990-02-22 BR BR909000846A patent/BR9000846A/pt not_active Application Discontinuation
- 1990-02-22 EP EP19900103458 patent/EP0385274A3/en not_active Withdrawn
- 1990-02-23 MX MX019642A patent/MX166334B/es unknown
- 1990-02-23 KR KR1019900002281A patent/KR900012951A/ko not_active Application Discontinuation
- 1990-02-23 CA CA002010779A patent/CA2010779A1/en not_active Abandoned
- 1990-02-23 AU AU50151/90A patent/AU628134B2/en not_active Ceased
- 1990-02-23 JP JP2041381A patent/JPH03729A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
AU628134B2 (en) | 1992-09-10 |
EP0385274A2 (en) | 1990-09-05 |
AU5015190A (en) | 1990-08-30 |
US4981931A (en) | 1991-01-01 |
MX166334B (es) | 1992-12-29 |
JPH03729A (ja) | 1991-01-07 |
CA2010779A1 (en) | 1990-08-24 |
BR9000846A (pt) | 1991-02-05 |
EP0385274A3 (en) | 1990-10-31 |
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WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |