KR900012951A - 내산소성 및 내수성 dcpd중합촉매인 불연속 텅스텐 착물 - Google Patents

내산소성 및 내수성 dcpd중합촉매인 불연속 텅스텐 착물 Download PDF

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Publication number
KR900012951A
KR900012951A KR1019900002281A KR900002281A KR900012951A KR 900012951 A KR900012951 A KR 900012951A KR 1019900002281 A KR1019900002281 A KR 1019900002281A KR 900002281 A KR900002281 A KR 900002281A KR 900012951 A KR900012951 A KR 900012951A
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KR
South Korea
Prior art keywords
carbon atoms
oxygen
alkyl group
polymerization catalyst
water resistant
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KR1019900002281A
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English (en)
Inventor
벨 앤드류
Original Assignee
마리온 씨.스타브스
허큘레스 인코오포레이티드
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Publication of KR900012951A publication Critical patent/KR900012951A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0214—Aryloxylates, e.g. phenolates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/66—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/34—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of chromium, molybdenum or tungsten

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polyethers (AREA)

Abstract

내용 없음

Description

내산소성 및 내수성 DCPD중합촉매인 불연속 텅스텐 착물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. 순수한 디시크로펜타디엔을 텅스텐함유 촉매전구체 및 일반식 R3SnH (여기에서, R은 1내지 10의 탄소원자를 갖는 알킬기 또는 페닐기이다)의 주석활성화제 화합물과 접촉시키는 것으로 구성되는 중합체의 제조방법에 있어서, 상기 촉매가 하기 일반식의 거의 순수한 텅스텐 착물인 것을 특징으로 하는 방법 :
    식중, X는C1 또는 Br이고, n은 2 또는 3이며, R1은 H, C1 1내지 10의 탄소원자를 갖는 알킬기, 1내지 8의 탄소원자를 갖는 알콕시기 또는 페닐기이고, R2는 또는 1내지 9의 탄소원자를 갖는 알킬기이며, R3는 H또는 1내지 10의 탄소원자를 갖는 알킬기이다.
  2. 제1항에 있어서, 상기 텅스텐 촉매착물이 WC12(4-에톡시페녹시)4, WC12(4-부톡시페녹시)4, WC13(2,6-디-t-부틸페녹시)3, WC12(페녹시)4, WC12(3-메틸페녹시)4, WC12(4-메틸페녹시), WC12(3.5-디메틸페녹시)4, WC12(4-부틸페녹시)4, WC12(4-클로로페녹시)4, WC13(2,6-디메틸페녹시)4, WC12(2,4,6-트리메틸페녹시)3, WC12(4-페닐페녹시)4, WC12(4-메톡시페녹시)4, 및 WC12(2,6-디-이소플필페녹시)3,로 이루어지는 군에서 선택되는 것을 특징으로 하는 방법.
  3. 제1항 또는 제2항에 있어서, 상기 주석활성화제 화합물이 트리-n-부틸주석 히드라이드 또는 트리페닐주석 히드라이드인 것을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900002281A 1989-02-24 1990-02-23 내산소성 및 내수성 dcpd중합촉매인 불연속 텅스텐 착물 KR900012951A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US315.075 1989-02-24
US07/315,075 US4981931A (en) 1989-02-24 1989-02-24 Discrete tungsten complexes as oxygen and water resistant DCPD polymerization catalysts

Publications (1)

Publication Number Publication Date
KR900012951A true KR900012951A (ko) 1990-09-03

Family

ID=23222777

Family Applications (1)

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KR1019900002281A KR900012951A (ko) 1989-02-24 1990-02-23 내산소성 및 내수성 dcpd중합촉매인 불연속 텅스텐 착물

Country Status (8)

Country Link
US (1) US4981931A (ko)
EP (1) EP0385274A3 (ko)
JP (1) JPH03729A (ko)
KR (1) KR900012951A (ko)
AU (1) AU628134B2 (ko)
BR (1) BR9000846A (ko)
CA (1) CA2010779A1 (ko)
MX (1) MX166334B (ko)

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US5218065A (en) * 1991-08-30 1993-06-08 Shell Oil Company Polymerization process
US5198511A (en) * 1991-12-20 1993-03-30 Minnesota Mining And Manufacturing Company Polymerizable compositions containing olefin metathesis catalysts and cocatalysts, and methods of use therefor
USH1388H (en) * 1992-12-23 1994-12-06 Hercules Incorporated Polyolefin polymer and method of making same
CA2112146A1 (en) * 1992-12-23 1994-06-24 Nitya P. Khasat Polydicyclopentadiene having improved stability and toughened with polymeric particles
US5276118A (en) * 1992-12-31 1994-01-04 Shell Oil Company Diaryl carbinol metathesis catalysts for ring-opening polymerization of cyclic olefins
US5278305A (en) * 1992-12-31 1994-01-11 Shell Oil Company Catalysts for ring-opening, metathesis polymerization of cyclic olefins
WO1994023836A1 (en) * 1993-04-08 1994-10-27 E.I. Du Pont De Nemours And Company Catalyst composition and process for the production of unsaturated diesters
JP2006117862A (ja) * 2004-10-25 2006-05-11 Nippon Zeon Co Ltd ノルボルネン系開環重合体水素化物の製造方法
WO2008010973A1 (en) * 2006-07-18 2008-01-24 Dow Global Technologies, Inc. Method for preparing poly(dicyclopentadiene)
WO2013083172A1 (en) 2011-12-05 2013-06-13 Blue Wave Co S.A. Method of fabricating a pressure vessel using a variable viscosity solventless prepolymer formulation
US8859666B2 (en) 2011-12-05 2014-10-14 Spencer Composites Corporation Variable viscosity solventless prepolymer formulation
CN103242511B (zh) * 2013-05-07 2015-07-01 黎明化工研究设计院有限责任公司 一种高效稳定的催化体系及其在环烯烃聚合配方中的应用
CN103665700B (zh) * 2013-08-27 2015-10-07 河南科技大学 一种聚双环戊二烯复合材料及其制备方法
WO2015047009A1 (ko) * 2013-09-30 2015-04-02 코오롱인더스트리 주식회사 환상올레핀계 고분자 화합물의 개환중합용 촉매 및 이를 이용한 환상올레핀계 고분자 화합물의 제조방법
KR101601493B1 (ko) * 2013-09-30 2016-03-09 코오롱인더스트리 주식회사 환상올레핀계 고분자 화합물의 개환중합용 촉매 및 이를 이용한 환상올레핀계 고분자 화합물의 제조방법

Family Cites Families (8)

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EP0084888B2 (en) * 1982-01-25 1995-10-25 Hercules Incorporated A dicyclopentadiene thermoset polymer and a catalyst and a method for making it
DE3460103D1 (en) * 1983-06-15 1986-05-28 Elf Aquitaine Catalyst for olefin methathesis
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Publication number Publication date
AU628134B2 (en) 1992-09-10
EP0385274A2 (en) 1990-09-05
AU5015190A (en) 1990-08-30
US4981931A (en) 1991-01-01
MX166334B (es) 1992-12-29
JPH03729A (ja) 1991-01-07
CA2010779A1 (en) 1990-08-24
BR9000846A (pt) 1991-02-05
EP0385274A3 (en) 1990-10-31

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