KR900007783A - 2-아미노데칼린 유도체류 및 이들의 용도 - Google Patents

2-아미노데칼린 유도체류 및 이들의 용도 Download PDF

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KR900007783A
KR900007783A KR1019890016568A KR890016568A KR900007783A KR 900007783 A KR900007783 A KR 900007783A KR 1019890016568 A KR1019890016568 A KR 1019890016568A KR 890016568 A KR890016568 A KR 890016568A KR 900007783 A KR900007783 A KR 900007783A
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alkenyl
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치프리스 마트히아스
치페어 베른하르트
자우터 후베르트
괴츠 노르베르트
로엘 프란츠
암메르만 에베르하르트
로렌츠 기젤라
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하우프터, 라이싱어
바스트 악티엔 게젤샤프트
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Publication of KR900007783A publication Critical patent/KR900007783A/ko

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Abstract

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Description

2-아미노데칼린 유도체류 및 이들의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 하기 일반식(Ⅰ)의 2-아미노데칼린 유도체류 및 식물에 의해 허용되는 이들의 염과 N-산화물류 :
    상기식에서 R1, R2및 R3는 같거나 다르며 각각은 H 또는 메틸기이고, A는 H, OH, O-C1-C4-알킬카르보닐기, O-벤조일기 또는 O-CH3이고 R4는 H, C1-C4-알킬기, C2-C4-알켄일기, C3-C4-알킨일기 또는 시클로프로필기이고, R5는 C3-C18-알켄일기 또는 C3-C18-알킨일기(이 기는 치환되지 않거나 C1-C8-알콕시기로 단일치환 내지 삼치환된다), C5-C12-시클로알킬기 또는 C5-C12-시클로알켄일기(이 기는 치환되지 않거나 C3-C8-알킬기, C3-C8-알켄일기 또는 C3-C8-알콜시로 단일치화 내지 삼치환된다)이거나, 또는
    인데, 여기서 R6는 C1-C5-알킬렌기이거나 C1-C5-알켄일렌기이고, R7은 C3-C8-알킬기, C3-C8-알켄일기, C3-C8-알콕시기, C1-C3-알콕시 -C2-C5-알킬기, C3-C5-알킬티오기 또는 트리메틸실릴기이고 R8는 H 또는 CH3이고, R9는 C6-C10-비시클로알킬기 또는 C6-C10-비시클로알켄일기(이 기는 치환되지 않거나 2 또는 3개의 메틸기로 치환된다)이고, W, X, Y 및 Z는 각각 방향족 5-원 헤테로환 고리에서의 고리원자, 즉 O, S, N, NH, N-R7으로 구성된 그룹에서 선택된 1 또는 2개의 기 그리고 2 또는 3개의 CH 및 C-R7기로 이루어진 고리원자이고, m은 0,1 또는 2(그러므로 5b기는 시클로헥실기, 시클로헵틸기 또는 시클로펜틸기를 이룬다)이고, R4및 R5는 또한 질소원자와 함께 하기 일반식(e) 또는 (f)의 5-원고리 또는 6-원고리((e) 또는 (f)), 즉
    을 형성할 수 있고, 여기서 R10은 H 또는 (CH2)q기 (여기서 q는 0,1,2,3 또는 4이다), 또는 메틸기이거나 에틸기 또는 측쇄의 C3-C8-알킬기이고, R11은 H 또는 C1-C5-알킬기이고, R12은 R10이 H가 아닌 경우 H 또는 페닐기이고, R13은 R12가 페닐기인 경우에 C3-C6-알킬기이고 n은 0 또는 1(따라서 5e기 또는 5f기는 6-원 또는 5-원 헤테로환고리를 형성한다)이다.
  2. 트란스-데칼린 골격을 가지고, A와 R3는 시스방향에 위치하고, R2및 NR4R9는 트란스방향에 위치하며, 그리고 R1내지 R5및 A는 제1항에서 정의된 바와 같은 의미를 가지는 하기 일반식(Ⅱ)의 2-아미노데칼린 유도체류 및 식물에 의해 허용되는 이들의 염과 N-산화물률 :
  3. 살균적으로 효과적인 양만큼 하기 일반식(Ⅰ)의 화합물 또는 식물에 의해 허용되는 이들의 염이나 N-산화물류, 및 고형물이나 액체 담체를 함유하는 살균제 :
    상기식에서 R1, R2및 R3는 같거나 다르며 각각은 H 또는 메틸기이고, A는 H, OH, O-C1-C4-알킬카르보닐기, O-벤조일기 또는 O-CH3이고, R4는 H, C1-C4-알킬카르보닐기, O-벤조일기 또는 O-CH3이고, R5는 C3-C18-알킬기, C3-C18-알켄일기 또는 C3-C18-알킨일기(이 기는 치환되지 않거나 C1-C8-알콕시기로 단일치환 내지 삼치환된다), C5-C12-시클로알킬기 또는 C5-C12-시클로알켄일기(이 기는 치환되지 않거나 C3-C8-알킬기, C3-C8-알켄일기 또는 C3-C8-알콕시기로 단일치환 내지 삼치환된다)이거나, 또는
    인데, 여기서 R6는 C1-C5-알킬렌기이거나 C1-C5-알켄일렌기이고, R7은 C3-C8-알킬기, C3-C8-알켄일기, C3-C8-알콕시기, C1-C3-알콕시 -C2-C5-알킬기, C3-C5-알킬티오기 또는 트리메틸실릴기이고, R8는 H 또는 CH이고, R9는 C6-C10-비시클로알킬기 또는 C6-C10-비시클로알켄일기(이 기는 치환되지 않거나 2 또는 3개의 메틸기로 치환된다)이고, W, X, Y 및 Z는 각각 방향족 5-원 헤테로환 고리에서의 고리원자, 즉 O, S, N, NH, N-R7으로 구성된 그룹에서 선택된 1 또는 2개의 기 그리고 2 또는 3개의 CH 및 C-R7기로 이루어진 고리원자이고, m은 0, 1 또는 2(그러므로 5b기는 시클로헥실기, 시클로헵틸기 또는 시클로펜틸기를 이룬다)이고, R4및 R5는 또한 질소원자와 함께 하기 일반식(e) 또는 (f)의 5-원 고리 또는 6-원고리((e) 또는 (f)), 즉
    을 형성할 수 있고, 여기서 R10은 H 또는 (CH2)q기 (여기서 q는 0,1,2,3 또는 4이다), 또는 메틸기이거나 에틸기 또는 측쇄의 C3-C8-알킬기이고, R11은 H 또는 C1-C5-알킬기이고, R12은 R10이 H가 아닌 경우 H 또는 페닐기이고, R13은 R12가 페닐기인 경우에 C3-C6-알킬기이고 n은 0 또는 1(따라서 5e기 또는 5f기는 6-원 또는 5-원 헤테로환 고리를 형성한다)이다.
  4. 살균적으로 효과적인 양의 하기 일반식(Ⅰ)의 화합물 또는 식물에 의해 허용되는 이들의 염 또는 이들의 N-산화물류를 군류, 또는 균류침입의 징후를 보이는 물질, 지면, 식물 또는 종자에 작용하도록 함을 특징으로 하는 균류퇴치방법 :
    상기식에서 R1, R2및 R3는 같거나 다르며 각각은 H 또는 메틸기이고, A는 H, OH, O-C1-C4-알킬카르보닐기, O-벤조일기 또는 O-CH3이고, R4는 H, C1-C4-알킬기, C2-C4-알켄일기 또는 C3-C4-알킨일기 또는 시클로프로필기이고, R5는 C3-C18-알킬기, C3-C18-알켄일기 또는 C3-C18-알킨일기 (이 기는 치환되지 않거나 C1-C8-알콕시기로 단일치환 내지 삼치환된다), C5-C12-시클로알킬기 또는 C5-C12-시클로알켄일기(이 기는 치환되지 않거나 C3-C8-알킬기, C3-C8-알켄일기 또는 C3-C8-알콕시기로 단일치환 내지 삼치환 된다)이거나, 또는
    인데, 여기서 R6는 C1-C5-알킬렌기이거나 C1-C5-알켄일렌기이고, R7은 C3-C8-알킬기, C3-C8-알켄일기, C3-C8-알콕시기, C1-C3-알콕시-C2-C5-알킬티오기 또는 트리메틸실릴기이고, R8는 H 또는 CH이고, R9는 C6-C10-비시클로알킬기 또는 C6-C10-비시클로알켄일기(이 기는 치환되지 않거나 2 또는 3개의 메틸기로 치환된다)이고, W, X, Y 및 Z는 각각 방향족 5-원 헤테로환 고리에서의 고리원자, 즉 O, S, N, NH, N-R7으로 구성된 그룹에서 선택된 1 또는 2개의 기 그리고 2 또는 3개의 CH 및 C-R7기로 이루어진 고리원자이고, m은 0, 1 또는 2(그러므로 5b기는 시클로헥실기, 시클로헵틸기 또는 시클로펜틸기를 이룬다)이고, R4및 R5는 또한 질소원자와 함께 하기 일반식(e) 또는 (f)의 5-원고리 또는 6-원고리 ((e) 또는 (f), 즉
    을 형성할 수 있고, 여기서 R10은 H 또는 (CH2)q기(여기서 q는 0,1,2,3 또는 4이다), 또는 메틸기이거나 에틸기 또는 측쇄의 C3-C8-알킬기이고, R11은 H 또는 C1-C5-알킬기이고, R12은 R10이 H가 아닌 경우 H 또는 페닐기이고, R13은 R12가 페닐기인 경우에 C3-C6-알킬기이고, n은 0 또는 1(따라서 5e기 또는 5f 기는 6-원 또는 5-원 헤테로환 고리를 형성한다)이다.
  5. 제1항에 있어서, A, R1, R2, R3및 R4는 수소원자이며 R5는 3, 7-디메틸-옥틸기임을 특징으로 하는 일반식(Ⅰ)의 화합물.
  6. 제1항에 있어서, A는 수소원자이고, R1, R2, R3및 R4는 메틸기이며 R5는 4-tert. 부톡시-시클로헥실-메틸기임을 특징으로 하는 일반식(Ⅰ)의 화합물.
  7. 제1항에 있어서, A 및 R4는 수소원자이고, R1, R2및 R3는 메틸기이며 R5는 4-tert. 부톡시-벤진기임을 특징으로 하는 일반식(Ⅰ)의 화합물.
  8. 제1항에 있어서, A, R1, R2및 R3는 수소원자이며 R4및 R5는 질소원자와 함께 4-tert. 부틸-피페리딘일기를 형성함을 특징으로 하는 일반식(Ⅰ)의 화합물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890016568A 1988-11-15 1989-11-15 2-아미노데칼린 유도체류 및 이들의 용도 KR900007783A (ko)

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US4214094A (en) * 1977-03-30 1980-07-22 Fujisawa Pharmaceutical Co., Ltd. Substituted-phenyl substituted-alkyl ethers and the preparation thereof
US4332807A (en) * 1981-01-26 1982-06-01 Merck & Co., Inc. N-Substituted-benzyl-11-endo-amino-5,6,7,8,9,10-hexahydro-2-hydroxy (or methoxy)-6,9-methanobenzocyclooctene (or nonene) centrally-acting analgesics
JPH0676285B2 (ja) * 1985-11-01 1994-09-28 三井東圧化学株式会社 ベンジルアミン誘導体、その製造法およびその用途
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DE3624648A1 (de) * 1986-07-22 1988-01-28 Bayer Ag Decahydronaphth-2-yl-alkylamine
DE3732930A1 (de) * 1987-09-30 1989-04-20 Basf Ag Fungizide n-substituierte 3-aryl-pyrrolidin-derivate
DE3732910A1 (de) * 1987-09-30 1989-04-20 Basf Ag Fungizide n-substituierte 3-alkyl-4-aryl-pyrrolidin-derivate
DE8903326U1 (ko) * 1988-07-27 1989-05-24 Herzberg, Wolfgang, Dr. Med., 2000 Wedel, De
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