KR900006400A - 방향족 폴리하이드록시 폴리아민, 이의 제조방법 및 포리우레탄 가소성물질을 제조하기 위한 이의 용도 - Google Patents

방향족 폴리하이드록시 폴리아민, 이의 제조방법 및 포리우레탄 가소성물질을 제조하기 위한 이의 용도 Download PDF

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KR900006400A
KR900006400A KR1019890014461A KR890014461A KR900006400A KR 900006400 A KR900006400 A KR 900006400A KR 1019890014461 A KR1019890014461 A KR 1019890014461A KR 890014461 A KR890014461 A KR 890014461A KR 900006400 A KR900006400 A KR 900006400A
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compound
average value
hydrogen
functional
general formula
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KR1019890014461A
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티리 우어스
산더스 요세프
디테리히 디터
그뢰글러 게르하르트
라이프 헬무트
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요아힘 그렘, 크라우스 대너
바이엘 아크티엔 게젤샤프트
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Publication of KR900006400A publication Critical patent/KR900006400A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
    • C08G18/5024—Polyethers having heteroatoms other than oxygen having nitrogen containing primary and/or secondary amino groups
    • C08G18/5027—Polyethers having heteroatoms other than oxygen having nitrogen containing primary and/or secondary amino groups directly linked to carbocyclic groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C217/00—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
    • C07C217/78—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton
    • C07C217/80—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings
    • C07C217/82—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings of the same non-condensed six-membered aromatic ring
    • C07C217/84—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings of the same non-condensed six-membered aromatic ring the oxygen atom of at least one of the etherified hydroxy groups being further bound to an acyclic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3271—Hydroxyamines
    • C08G18/329—Hydroxyamines containing aromatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/321—Polymers modified by chemical after-treatment with inorganic compounds
    • C08G65/322—Polymers modified by chemical after-treatment with inorganic compounds containing hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/333—Polymers modified by chemical after-treatment with organic compounds containing nitrogen
    • C08G65/33379—Polymers modified by chemical after-treatment with organic compounds containing nitrogen containing nitro group
    • C08G65/33386—Polymers modified by chemical after-treatment with organic compounds containing nitrogen containing nitro group cyclic
    • C08G65/33389—Polymers modified by chemical after-treatment with organic compounds containing nitrogen containing nitro group cyclic aromatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00—Manufacture of cellular products

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyamides (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

Abstract

내용 없음

Description

방향족 폴리하이드록시 폴리아민, 이의 제조방법 및 포리우레탄 가소성물질을 제조하기 위한 이의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (16)

  1. 하기 일반식(I)의 화합물.
    상기식에서, R1은 분자량이 약 400 내지 약 8000인 m-작용성 폴리하이드록실 화합물의 m-작용성 잔기이고, R2는 수소 또는 메틸이고, m은 2내지 4의 정수이며, n은 약 0.05m 내지 약 0.73m의 평균값을 갖는 양수이다.
  2. 제1항에 있어서, 폴리하이드록실 화합물이 폴리알킬렌 폴리에테르인 화합물.
  3. 제1항에 있어서, 일반식(I)에서 R2가 수소이고, NH2그룹이 오르토 또는 파라 위치에 존재하는 하기 일반식(I') 또는 (I")의 화합물.
    또는
    상기식에서, R1, m 및 n은 제1항에서 정의한 바와 같다.
  4. 제1항에 있어서, n가 0.3m 내지 0.6m의 평균값을 갖는 양수인 화합물.
  5. 제1항에 있어서, n가 0.15m 내지 0.70m의 평균값을 갖는 양수인 화합물.
  6. 제1항에 있어서, m가 2 또는 3인 화합물.
  7. (a) 알칼리성 화합물의 존재하에서, 비교적 고분자량의 일반식(II)와 m-작용성 폴리하이드록실 화합물(i)을 일반식(III)의 화합물(ii) n몰량과 반응시켜 일반식(IV)의 (m-n)-하이드록시 n-니트로펜옥시 부가물을 형성시키고, (b) 상기한 (m-n)-하이드록시 n-니트로펜옥시 부가물을 수소화함을 특징으로 하여, 일반식(I)의 화합물을 제조하는 방법.
    상기식에서, R1은 분자량이 약 400 내지 약 8000인 m-작용성 폴리하이드록실 화합물의 m-작용성 잔기이고, R2는 수소 또는 메틸이고, m은 2내지 4의 정수이며, n은 약 0.05m 내지 약 0.73m의 평균값을 갖는 양수이고, X는 할로겐이다.
  8. 제7항에 있어서, X가 불소 또는 염소인 방법.
  9. 제7항에 있어서, 알칼리성 화합물이 단계(a)의 반응중에 방출되는 할로겐화수소를 중화시키기에 충분한 양인 수산화나트륨 또는 수산화칼륨 분말인 방법.
  10. 제9항에 있어서, 단계(a)에서 성분(ii) 1몰당 알칼리성 화합물 약 1 내지 3몰 당량을 사용하는 방법.
  11. 제7항에 있어서, 단계(a)를 용매의 부재하에 수행하는 방법.
  12. 제7항에 있어서, 단계(a)에서 유기용매를 사용하는 방법.
  13. 제12항에 있어서, 유기용매가 디메틸설폭사이드 또는 방향족 탄화수소인 방법.
  14. 제7항에 있어서, 단계(a)에서 상전이 촉매가 사용되는 방법.
  15. 제14항에 있어서, 상전이 촉매가 N-벤질-N,N,N-트리메틸암모늄 클로라이드, N-벤질-N,N,N-트리에틸암모늄 클로라이드, 또는 N-헥사데실-N,N,N-트리메틸암모늄 브라마이드인 방법.
  16. 이소시아네이트 중부가반응 공정에서 합성성분으로서 제1항에 따른 화합물을 사용함을 특징으로 하여, 폴리우레탄 가소성 물질을 제조하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890014461A 1988-10-12 1989-10-10 방향족 폴리하이드록시 폴리아민, 이의 제조방법 및 포리우레탄 가소성물질을 제조하기 위한 이의 용도 KR900006400A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP3834749.0 1988-10-12
DE3834749A DE3834749A1 (de) 1988-10-12 1988-10-12 Aromatische polyhydroxypolyamine, ein verfahren zu ihrer herstellung und ihre verwendung zur herstellung von polyurethan-kunststoffen

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KR900006400A true KR900006400A (ko) 1990-05-08

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KR1019890014461A KR900006400A (ko) 1988-10-12 1989-10-10 방향족 폴리하이드록시 폴리아민, 이의 제조방법 및 포리우레탄 가소성물질을 제조하기 위한 이의 용도

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EP (1) EP0363758B1 (ko)
JP (1) JPH02169614A (ko)
KR (1) KR900006400A (ko)
AT (1) ATE83231T1 (ko)
AU (1) AU619903B2 (ko)
BR (1) BR8905157A (ko)
CA (1) CA1334104C (ko)
DD (1) DD288385A5 (ko)
DE (2) DE3834749A1 (ko)
ES (1) ES2053901T3 (ko)
ZA (1) ZA897690B (ko)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4022931A1 (de) * 1990-07-19 1992-01-23 Bayer Ag Verfahren zur herstellung von aminophenoxygruppen aufweisenden polyethern, die nach diesem verfahren erhaltenen verbindungen und ihre verwendung als reaktionspartner fuer organische polyisocyanate
JPH05156002A (ja) * 1991-06-04 1993-06-22 Natl Starch & Chem Investment Holding Corp ポリエーテルアミン化合物及びエポキシ系接着剤組成物
US5637119A (en) * 1995-12-29 1997-06-10 Chevron Chemical Company Substituted aromatic polyalkyl ethers and fuel compositions containing the same
US5849048A (en) * 1997-09-30 1998-12-15 Chevron Chemical Company Llc Substituted biphenyl poly (oxyalkylene) ethers and fuel compositions containing the same

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6038412B2 (ja) * 1982-09-21 1985-08-31 東洋ゴム工業株式会社 ポリエ−テルポリオ−ル誘導体及びその製造法
DE3622784A1 (de) * 1986-07-07 1988-01-21 Wella Ag Neue 5-alkoxy-2,4-diamino-alkylbenzole sowie haarfaerbemittel mit 5-alkoxy-2,4-diamino-alkyl-benzolen
US4847416A (en) * 1986-10-27 1989-07-11 The Dow Chemical Company Capping of polyols with aromatic amines
DE3713858A1 (de) * 1987-04-25 1988-11-17 Bayer Ag Aromatische polyamine, ein verfahren zu ihrer herstellung und ihre verwendung zur herstellung von polyurethankunststoffen
EP0371248A1 (en) * 1988-11-03 1990-06-06 Miles Inc. Polyurea rim systems

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DE58902962D1 (de) 1993-01-21
BR8905157A (pt) 1990-05-15
DE3834749A1 (de) 1990-04-19
ZA897690B (en) 1990-07-25
AU619903B2 (en) 1992-02-06
ATE83231T1 (de) 1992-12-15
CA1334104C (en) 1995-01-24
ES2053901T3 (es) 1994-08-01
EP0363758A3 (de) 1991-05-02
JPH02169614A (ja) 1990-06-29
EP0363758B1 (de) 1992-12-09
AU4274489A (en) 1990-04-26
EP0363758A2 (de) 1990-04-18
DD288385A5 (de) 1991-03-28

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