KR900006379A - 수용성 또는 수분산성 그래프트 중합체, 이의 제조방법 및 용도 - Google Patents
수용성 또는 수분산성 그래프트 중합체, 이의 제조방법 및 용도 Download PDFInfo
- Publication number
- KR900006379A KR900006379A KR1019890014078A KR890014078A KR900006379A KR 900006379 A KR900006379 A KR 900006379A KR 1019890014078 A KR1019890014078 A KR 1019890014078A KR 890014078 A KR890014078 A KR 890014078A KR 900006379 A KR900006379 A KR 900006379A
- Authority
- KR
- South Korea
- Prior art keywords
- weight
- graft polymer
- mol
- sum
- dye
- Prior art date
Links
- 229920000578 graft copolymer Polymers 0.000 title claims 10
- 238000002360 preparation method Methods 0.000 title 1
- 238000000034 method Methods 0.000 claims 10
- -1 N-vinyl-substituted amides Chemical class 0.000 claims 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 6
- 239000000178 monomer Substances 0.000 claims 6
- 239000000203 mixture Substances 0.000 claims 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims 3
- 125000004432 carbon atom Chemical group C* 0.000 claims 3
- 239000000975 dye Substances 0.000 claims 3
- 238000010438 heat treatment Methods 0.000 claims 3
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 2
- 150000003926 acrylamides Chemical class 0.000 claims 2
- 125000002947 alkylene group Chemical group 0.000 claims 2
- PNLUGRYDUHRLOF-UHFFFAOYSA-N n-ethenyl-n-methylacetamide Chemical compound C=CN(C)C(C)=O PNLUGRYDUHRLOF-UHFFFAOYSA-N 0.000 claims 2
- 239000000985 reactive dye Substances 0.000 claims 2
- 239000012266 salt solution Substances 0.000 claims 2
- 229920001567 vinyl ester resin Polymers 0.000 claims 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 2
- 229920003043 Cellulose fiber Polymers 0.000 claims 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims 1
- 239000000654 additive Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 claims 1
- 239000001913 cellulose Substances 0.000 claims 1
- 229920002678 cellulose Polymers 0.000 claims 1
- 239000000982 direct dye Substances 0.000 claims 1
- 238000004043 dyeing Methods 0.000 claims 1
- 239000002657 fibrous material Substances 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- GORGQKRVQGXVEB-UHFFFAOYSA-N n-ethenyl-n-ethylacetamide Chemical compound CCN(C=C)C(C)=O GORGQKRVQGXVEB-UHFFFAOYSA-N 0.000 claims 1
- RQAKESSLMFZVMC-UHFFFAOYSA-N n-ethenylacetamide Chemical compound CC(=O)NC=C RQAKESSLMFZVMC-UHFFFAOYSA-N 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- 239000000080 wetting agent Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/20—Physical treatments affecting dyeing, e.g. ultrasonic or electric
- D06P5/2011—Application of vibrations, pulses or waves for non-thermic purposes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6131—Addition products of hydroxyl groups-containing compounds with oxiranes
- D06P1/6133—Addition products of hydroxyl groups-containing compounds with oxiranes from araliphatic or aliphatic alcohols
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
- Graft Or Block Polymers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (16)
- (A) 탄소수 3내지 10의 적어도 3가인 지방족 알콜과 알킬렌 옥사이드의 부가 생성물 2내지 30중량%와 (B) (1) N-치환된 또는 N-비치환된 아크릴아미드 또는 메타크릴아미드 20 내지 50중량%와 (2) 각각 포화 지방족 모노카르복실산으로부터 유도된 N-비닐-치환된 아미드 또는 비닐 에스테르 50 내지 80중량%의 그래프트된 단량체 혼합물 70 내지 98중량%[여기서, (A)와 (B)의 합과 (1)과 (2)의 합은 각각의 경우에 100%이다]를 포함하는 그래프트 중합체.
- 제1항에 있어서, 그래프트 기재(A)가 프로필렌 옥사이드 4 내지 100mol과 탄소수 3 내지 6의 3가 내지 6가 알칸올의 부가 생성물인 그래프트 중합체.
- 제1항에 있어서, 그래프트 기재(A)가 프로필렌 옥사이드 40 내지 80mol과 글리세롤 1mol의 부가 생성물인 그래프트 중합체.
- 제1항에 있어서, 단량체(1)이 아크릴아미드 또는 메타크릴아미드인 그래프트 중합체.
- 제1항에 있어서, 단량체(2)가 N-비닐아세트아미드, N-메틸-N-비닐아세트아미드 또는 N-에틸-N-비닐아세트아미드인 그래프트 중합체.
- 제1항에 있어서, 부가 생성물(A) 4 내지 15중량%와 그래프트된 단량체 혼합물(B) 85 내지 96중량%를 함유하는 그래프트 중합체.
- 제1항에 있어서, 단량체 혼합물(B)가 아크릴아미드 화합물(1) 25 내지 48중량%와 비닐 화합물(2) 52 내지 75중량%를 포함하는 그래프트 중합체.
- 제1항에 있어서, 프로필렌 옥사이드 40 내지 80mol과 글리세롤 1mol의 부가 생성물 3 내지 10중량%, 아크릴아미드 35 내지 48중량% 및 N-메틸-N-비닐아세트아미드 42 내지 60중량%를 함유하며, 반응한 성분들의 합이 100%인 그래프트 중합체.
- 염료 이외에 (A) 탄소수 3내지 10의 적어도 3가인 지방족 알콜과 알킬렌 옥사이드의 부가 생성물 2내지 30중량%와 (B) (1) N-치환된 또는 N-비치환된 아크릴아미드 또는 메타크릴아미드 20 내지 50중량%와 (2) 각각 포화 지방족 모노카복실산으로부터 유도된 N-비닐-치환된 아미드 또는 비닐 에스테르 50 내지 80중량%의 그래프트된 단량체 혼합물 70 내지 98중량%[여기서, (A)와 (B)의 합과 (1)과 (2)의 합은 각각의 경우에 100%이다]로부터 수득한 그래프트 중합체를 함유하는 수성 염액으로 셀룰로오즈 재료를 합침시킨 다음, 염료를 가열처리 또는 냉 패드-패치법으로 고착시킴을 포함하여, 전적으로 또는 부분적으로 셀룰로오즈 섬유로 이루어진 섬유재료를 직접 염료 또는 반응성 염료로 염색하는 방법.
- 제9항에 있어서, 염액이 내알칼리성 습윤제를 추가로 함유하는 방법.
- 제9항에 있어서, 염액이 1ℓ당 2내지 40g의 양으로 3내지 10% 수용액 형태의 그래프트 중합체를 함유하는 방법.
- 제9항에 있어서, 반응성 염료를 사용하는 방법.
- 제9항에 있어서, 마이크로파를 사용하여 가열 처리를 수행하는 방법.
- 제9항에 있어서, 더모솔링으로 가열처리를 수행하는 방법.
- 제9항에 있어서, 증기처리로 가열처리를 수행하는 방법.
- 제9항에 있어서, 냉 패드-배치법으로 염료를 고착을 수행하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH3665/88-7 | 1988-10-03 | ||
CH366588 | 1988-10-03 |
Publications (1)
Publication Number | Publication Date |
---|---|
KR900006379A true KR900006379A (ko) | 1990-05-08 |
Family
ID=4260874
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019890014078A KR900006379A (ko) | 1988-10-03 | 1989-09-30 | 수용성 또는 수분산성 그래프트 중합체, 이의 제조방법 및 용도 |
Country Status (12)
Country | Link |
---|---|
US (2) | US4975524A (ko) |
EP (1) | EP0363319B1 (ko) |
JP (1) | JPH0660225B2 (ko) |
KR (1) | KR900006379A (ko) |
AT (1) | ATE87634T1 (ko) |
AU (1) | AU602117B2 (ko) |
CA (1) | CA1318054C (ko) |
DE (1) | DE58903949D1 (ko) |
ES (1) | ES2039936T3 (ko) |
GR (1) | GR3007908T3 (ko) |
IL (1) | IL91840A0 (ko) |
ZA (2) | ZA897464B (ko) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4304313A1 (de) * | 1993-02-12 | 1994-08-18 | Hoechst Ag | Verwendung von Copolymeren auf Basis von Vinylmonomeren und Carbonsäureamiden als Waschmittelzusatz |
TW267198B (ko) * | 1993-03-02 | 1996-01-01 | Ciba Geigy | |
DE69426371T2 (de) * | 1993-05-07 | 2001-05-17 | Nippon Paint Co Ltd | Wässrige Polyoxyalkylene Oberflachenbehandlungslösungen |
AT406782B (de) * | 1995-03-16 | 2000-09-25 | Gawomi Textil Gesmbh | Verfahren zum bedrucken von textilien warenbahnen |
DE19515943A1 (de) * | 1995-05-02 | 1996-11-07 | Basf Ag | Pfropfpolymerisate aus Alkylenoxideinheiten enthaltenden Polymerisaten und ethylenisch ungesättigten Verbindungen, Verfahren zu ihrer Herstellung und ihre Verwendung |
DE19526626A1 (de) * | 1995-07-21 | 1997-01-23 | Basf Ag | Pfropfpolymerisate aus Vinylester- und/oder Vinylalkohol-Einheiten enthaltenden Polymerisaten und ethylenisch ungesättigten Verbindungen, Verfahren zu ihrer Herstellung und ihre Verwendung |
EP0784117B1 (de) * | 1996-01-11 | 2003-12-10 | Ciba SC Holding AG | Verwendung von acrylamid-homo- oder copolymeren als antisettingmittel |
DE19606899C2 (de) * | 1996-02-13 | 2002-11-21 | Fraunhofer Ges Forschung | Verfahren zur Herstellung von Dispersionen wasserlöslicher Vinylpolymere und Stabilisator zur Durchführung des Verfahrens |
JP3863038B2 (ja) * | 2002-03-08 | 2006-12-27 | 株式会社スーパーツール | フレア成形工具 |
US20080063806A1 (en) * | 2006-09-08 | 2008-03-13 | Kimberly-Clark Worldwide, Inc. | Processes for curing a polymeric coating composition using microwave irradiation |
US7674300B2 (en) * | 2006-12-28 | 2010-03-09 | Kimberly-Clark Worldwide, Inc. | Process for dyeing a textile web |
US7568251B2 (en) | 2006-12-28 | 2009-08-04 | Kimberly-Clark Worldwide, Inc. | Process for dyeing a textile web |
US7740666B2 (en) * | 2006-12-28 | 2010-06-22 | Kimberly-Clark Worldwide, Inc. | Process for dyeing a textile web |
US20080156428A1 (en) * | 2006-12-28 | 2008-07-03 | Kimberly-Clark Worldwide, Inc. | Process For Bonding Substrates With Improved Microwave Absorbing Compositions |
US20080156427A1 (en) * | 2006-12-28 | 2008-07-03 | Kimberly-Clark Worldwide, Inc. | Process For Bonding Substrates With Improved Microwave Absorbing Compositions |
US8182552B2 (en) * | 2006-12-28 | 2012-05-22 | Kimberly-Clark Worldwide, Inc. | Process for dyeing a textile web |
US8632613B2 (en) * | 2007-12-27 | 2014-01-21 | Kimberly-Clark Worldwide, Inc. | Process for applying one or more treatment agents to a textile web |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE598847A (ko) * | 1960-01-05 | |||
BE631142A (ko) * | 1962-04-20 | |||
DE1251532B (ko) * | 1963-09-25 | |||
US3627839A (en) * | 1968-11-26 | 1971-12-14 | Hercules Inc | Graft polymer of ethylenically unsaturated monomer onto a halo-substituted branched polyether polymer, and process for making it |
US3776983A (en) * | 1971-06-10 | 1973-12-04 | Nat Starch Chem Corp | Block polymers derived from vinyl quaternary nitrogen monomers and polyalkylene oxide condensates |
US3763277A (en) * | 1971-07-01 | 1973-10-02 | Union Carbide Corp | Process for the preparation of inter-polymers of poly(ethylene oxide) |
DE2918607A1 (de) * | 1979-05-09 | 1980-11-13 | Hoechst Ag | Verfahren zum klotzfaerben von bahnfoermigen textilien aus cellulosefasern |
US4563499A (en) * | 1980-01-21 | 1986-01-07 | The Celotex Corporation | Extraction of polyoxyalkylene surfactants for phenolic foam stabilization |
US4494956A (en) * | 1982-12-14 | 1985-01-22 | Ciba-Geigy Corporation | Process for pad dyeing cellulosic textile materials |
US4604099A (en) * | 1984-01-30 | 1986-08-05 | Ciba-Geigy Corporation | Process for printing cellulose-containing textile material with foam-containing reactive dyes and addition of (meth) acrylamide polymers |
US4612016A (en) * | 1984-03-08 | 1986-09-16 | Ciba-Geigy Corporation | Process for dyeing cellulosic textile materials |
DE3563547D1 (en) * | 1984-05-18 | 1988-08-04 | Ciba Geigy Ag | Process for dyeing or printing fabrics containing cellulose with vat dyes |
US4705525A (en) * | 1985-06-28 | 1987-11-10 | Ciba-Geigy Corporation | Water-soluble or water-dispersible graft polymers, process for their preparation and the use thereof |
US4731092A (en) * | 1986-04-30 | 1988-03-15 | Ciba-Geigy Corporation | Process for printing or dyeing cellulose-containing textile material with reactive dyes in aqueous foam preparation containing acrylic graft co-polymer |
EP0295205A1 (fr) * | 1987-06-05 | 1988-12-14 | Ciba-Geigy Ag | Procédé de teinture ou apprêt par foulardage avec fixation à la continue de matières textiles |
-
1989
- 1989-09-25 CA CA000612806A patent/CA1318054C/en not_active Expired - Fee Related
- 1989-09-26 EP EP89810729A patent/EP0363319B1/de not_active Expired - Lifetime
- 1989-09-26 ES ES198989810729T patent/ES2039936T3/es not_active Expired - Lifetime
- 1989-09-26 DE DE8989810729T patent/DE58903949D1/de not_active Expired - Fee Related
- 1989-09-26 AT AT89810729T patent/ATE87634T1/de not_active IP Right Cessation
- 1989-09-29 US US07/414,996 patent/US4975524A/en not_active Expired - Fee Related
- 1989-09-29 AU AU42439/89A patent/AU602117B2/en not_active Ceased
- 1989-09-29 IL IL91840A patent/IL91840A0/xx not_active IP Right Cessation
- 1989-09-30 KR KR1019890014078A patent/KR900006379A/ko not_active Application Discontinuation
- 1989-10-02 ZA ZA897464A patent/ZA897464B/xx unknown
- 1989-10-02 ZA ZA897465A patent/ZA897465B/xx unknown
- 1989-10-03 JP JP1258624A patent/JPH0660225B2/ja not_active Expired - Lifetime
-
1990
- 1990-09-25 US US07/587,386 patent/US5028237A/en not_active Expired - Fee Related
-
1993
- 1993-05-19 GR GR920403071T patent/GR3007908T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
ES2039936T3 (es) | 1993-10-01 |
JPH0660225B2 (ja) | 1994-08-10 |
IL91840A0 (en) | 1990-06-10 |
US5028237A (en) | 1991-07-02 |
AU4243989A (en) | 1990-04-05 |
CA1318054C (en) | 1993-05-18 |
GR3007908T3 (ko) | 1993-08-31 |
ZA897464B (en) | 1990-06-27 |
EP0363319A1 (de) | 1990-04-11 |
ZA897465B (en) | 1990-06-27 |
EP0363319B1 (de) | 1993-03-31 |
ATE87634T1 (de) | 1993-04-15 |
US4975524A (en) | 1990-12-04 |
AU602117B2 (en) | 1990-09-27 |
DE58903949D1 (de) | 1993-05-06 |
JPH02135207A (ja) | 1990-05-24 |
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