KR900003475A - 저점도 폴리우레탄/우레아 형성 성분들로 함침된 섬유상 보강 물질 - Google Patents

저점도 폴리우레탄/우레아 형성 성분들로 함침된 섬유상 보강 물질 Download PDF

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KR900003475A
KR900003475A KR1019890011549A KR890011549A KR900003475A KR 900003475 A KR900003475 A KR 900003475A KR 1019890011549 A KR1019890011549 A KR 1019890011549A KR 890011549 A KR890011549 A KR 890011549A KR 900003475 A KR900003475 A KR 900003475A
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South Korea
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compound
imino
viscosity
centipoise
less
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KR1019890011549A
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English (en)
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허버트 러셀 길리스
아이.사이오운 린
Original Assignee
임페리얼 케미칼 인더스트리스 피엘시
아이씨아이 아메리카스 인크.
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Publication of KR900003475A publication Critical patent/KR900003475A/ko

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C67/00Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
    • B29C67/24Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 characterised by the choice of material
    • B29C67/246Moulding high reactive monomers or prepolymers, e.g. by reaction injection moulding [RIM], liquid injection moulding [LIM]
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805Compounds having only one group containing active hydrogen
    • C08G18/285Nitrogen containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/32Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225Polyamines
    • C08G18/3253Polyamines being in latent form
    • C08G18/3256Reaction products of polyamines with aldehydes or ketones
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666Compounds of group C08G18/48 or C08G18/52
    • C08G18/667Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6681Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
    • C08G18/6685Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3225 or polyamines of C08G18/38
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2120/00Compositions for reaction injection moulding processes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31551Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Textile Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Reinforced Plastic Materials (AREA)
  • Moulding By Coating Moulds (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)

Abstract

내용 없음

Description

저점도 폴리우레탄/우레아 형성 성분들로 함침된 섬유상 보강 물질
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. (a) 100센티포이즈 미만의 점도를 갖는 폴리이소시아네이트 성분, 및 (b) 100센티포이즈 미만의 점도를 갖고, 분자량이 43이상이고 점도가 50센티포이즈 미만인 이미노 관능성 화합물 또는 엔아민기 함유 화합물을 함유하는 이소시아네이트 반응성 성분으로 이루어진 중합체 형성 반응 혼합물로 섬유상 보강 물질을 함침시키는 것을 특징으로 하는 복합 재료 제조 방법. 여기서 상기한 모든 점도값은 25℃ 또는 25℃에서 고체인 경우에는 그 물질의 융점에서 측정한 값임.
  2. 제1항에 있어서, 이미노-관능성 화합물이 하기 식의 화합물인 것을 특징으로 하는 방법.
    상기 식중, X, Y 및 Z는 집합적으로 상기 화합물의 잔여부를 형성하는 화학적인 성분(chemical moiety)으로서, 각각 독립적으로 수소 및 N, C, O, S, Si 또는 P를 거쳐 상기 화합물의 이미노 단위(C=N-)에 결합되는 유기기로 구성되는 군 중에서 선택되며, 상기 이미노 단위의 중심 탄소원자는 3개의 원자에 결합된다.
  3. 제2항에 있어서, 상기이미노 관능성 화합물이 1 내지 4개의 이미노 단위를 함유하는 것을 특징으로 하는 방법.
  4. 제1항에 있어서, 상기 엔아민기 함유 화합물이 하기 식의 화합물인 것을 특징으로 하는 방법.
    상기 식중, A, B, E, G, J 및 L은 각각 독립적으로 수소 또는 임의로 치환된 탄화수소기로서, A, B, E, G, J 및 (또는) L은 임의로 서로 결합하여 하나 이상의 카르보시클릭 또는 헤테로시클릭 고리를 형성하며, D는 수소 또는 임의로 치환된 탄화수소기이다.
  5. 제1항에 있어서, 상기 이미노 관능성 화합물 또는 엔아민기 함유 화합물의 25℃ 또는 25℃에서 고체인 경우 그 화합물의 융점에서의 점도가 25센티포이즈 미만인 것을 특징으로 하는 방법.
  6. 제1항에 있어서, 상기 반응 혼합물이 중합가능한 불포화 화합물 또는 에폭시 모노머를 함유하는 것을 특징으로 하는 방법.
  7. 제1항에 있어서, 상기 폴리이소시아네이트 및 이소시아네이트 반응성 화합물을 반응 사출 성형 기술을 사용하여 지방산의 염 및 실리콘 중에서 선택된 내부 이형제와 혼합시켜 서로 반응시키는 것을 특징으로 하는 방법.
  8. 제7항에 있어서, 상기 보강 섬유를 반응 사출 성형중에 두는 것을 특징으로 하는 방법.
  9. 제1항에 의해 제조된 경화 보강 복합체.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890011549A 1988-08-12 1989-08-11 저점도 폴리우레탄/우레아 형성 성분들로 함침된 섬유상 보강 물질 KR900003475A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8819297.6 1988-08-12
GB8819297A GB8819297D0 (en) 1988-08-12 1988-08-12 Composite materials

Publications (1)

Publication Number Publication Date
KR900003475A true KR900003475A (ko) 1990-03-26

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Country Status (9)

Country Link
US (1) US5002830A (ko)
EP (1) EP0354712A3 (ko)
JP (1) JPH0288646A (ko)
KR (1) KR900003475A (ko)
AU (1) AU3927089A (ko)
CA (1) CA1322699C (ko)
GB (2) GB8819297D0 (ko)
NZ (1) NZ230100A (ko)
ZA (1) ZA895624B (ko)

Families Citing this family (16)

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NZ230314A (en) * 1988-09-09 1991-02-26 Ici Plc Polyisocyanate composition obtained from the reaction product of uretonimine and/or carbodiimide-modified polyisocyanate with a carboxylic acid
JPH02299811A (ja) * 1989-05-16 1990-12-12 Sakae Riken Kogyo Kk プラスチック成形体およびその成形方法
US5225457A (en) * 1990-06-05 1993-07-06 The Goodyear Tire & Rubber Company Reinforced polymer matrix and product containing micro and macro reinforcement
GB9021051D0 (en) * 1990-09-27 1990-11-07 Ici Plc Catalyst composition
JP2581360B2 (ja) * 1991-10-18 1997-02-12 池田物産株式会社 羽毛弾性体の製造方法
US5643989A (en) * 1993-10-29 1997-07-01 Azdel, Inc. Fiber reinforced functionalized polyolefin composites
ATE173279T1 (de) * 1993-12-21 1998-11-15 Bayer Ag Überzugszusammensetzungen auf der basis von aldiminen und allophanatgruppen enthaltenden polyisocyanaten
US5688590A (en) * 1995-08-21 1997-11-18 Bayer Corporation High heat resistant molded parts produced by structural reaction injection molding
USRE44893E1 (en) 2004-03-26 2014-05-13 Hanwha Azdel, Inc. Fiber reinforced thermoplastic sheets with surface coverings
DE102008001855A1 (de) * 2008-05-19 2009-11-26 Evonik Degussa Gmbh Zweikomponenten-Zusammensetzung zur Herstellung von flexiblen Polyurethan-Gelcoats
US9580598B2 (en) * 2011-03-25 2017-02-28 Covestro Llc Polyurethane composites produced by a vacuum infusion process
US9957345B2 (en) 2014-08-18 2018-05-01 International Business Machines Corporation 3D printing with PHT based materials
US10023735B2 (en) * 2014-08-18 2018-07-17 International Business Machines Corporation 3D printing with PHT/PHA based materials and polymerizable monomers
US9758620B2 (en) 2015-09-03 2017-09-12 International Business Machines Corporation Tailorable viscoelastic properties of PEG-hemiaminal organogel networks
US9873766B2 (en) 2015-11-24 2018-01-23 International Business Machines Corporation Systems chemistry approach to polyhexahydrotriazine polymeric structures
JP6580774B1 (ja) * 2018-05-16 2019-09-25 第一工業製薬株式会社 熱可塑性マトリックス樹脂形成用二液硬化型組成物、繊維強化複合材料用マトリックス樹脂、及び繊維強化複合材料

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1064842A (en) * 1963-02-04 1967-04-12 Ici Ltd New aldimines and ketimines
DE3308418A1 (de) * 1983-03-09 1984-09-13 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von kombinationen aus organischen polyisocyanaten und zumindest teilweise blockierten polyaminen, die nach dem verfahren erhaeltlichen kombinationen und ihre verwendung zur herstellung von lacken, beschichtungs- oder dichtungsmassen
US4513133A (en) * 1984-02-13 1985-04-23 Texaco Inc. Reaction injection molded elastomers containing low molecular weight organic acids
US4582879A (en) * 1984-03-22 1986-04-15 Frisch Kurt C Reaction injection molding process and reaction injection molded products
GB8705801D0 (en) * 1987-03-11 1987-04-15 Ici Plc Injection moulding compositions

Also Published As

Publication number Publication date
GB8819297D0 (en) 1988-09-14
AU3927089A (en) 1990-04-12
ZA895624B (en) 1990-07-25
GB8917933D0 (en) 1989-09-20
EP0354712A3 (en) 1990-09-19
CA1322699C (en) 1993-10-05
EP0354712A2 (en) 1990-02-14
US5002830A (en) 1991-03-26
NZ230100A (en) 1990-12-21
JPH0288646A (ja) 1990-03-28

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