KR900003306A - 수분제거에 의해 엘라스토머로 가교결합할 수 있는 실리콘 수지기제 수성 분산액 - Google Patents

수분제거에 의해 엘라스토머로 가교결합할 수 있는 실리콘 수지기제 수성 분산액 Download PDF

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KR900003306A
KR900003306A KR1019890012552A KR890012552A KR900003306A KR 900003306 A KR900003306 A KR 900003306A KR 1019890012552 A KR1019890012552 A KR 1019890012552A KR 890012552 A KR890012552 A KR 890012552A KR 900003306 A KR900003306 A KR 900003306A
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emulsion
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페데 미셀
윌리쉬 쟝
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쟝-루이 쉐네
롱 쁠랑 쉬미
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/49Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
    • C04B41/4905Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
    • C04B41/495Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon applied to the substrate as oligomers or polymers
    • C04B41/4961Polyorganosiloxanes, i.e. polymers with a Si-O-Si-O-chain; "silicones"
    • C04B41/4966Polyorganosiloxanes, i.e. polymers with a Si-O-Si-O-chain; "silicones" containing silicon bound to hydroxy groups, i.e. OH-blocked polysiloxanes
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/60After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
    • C04B41/61Coating or impregnation
    • C04B41/62Coating or impregnation with organic materials
    • C04B41/64Compounds having one or more carbon-to-metal of carbon-to-silicon linkages
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/02Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/14Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/16Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/20Polysiloxanes containing silicon bound to unsaturated aliphatic groups
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/22Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/24Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen halogen-containing groups
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/70Siloxanes defined by use of the MDTQ nomenclature
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08J2383/00Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2383/04Polysiloxanes

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  • Chemical & Material Sciences (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
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  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Ceramic Products (AREA)
  • Silicon Polymers (AREA)
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Abstract

내용 없음

Description

수분제거에 의해 엘라스토머로 가교결합할 수 있는 실리콘 수지기제 수성 분산액
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 중량기준으로, (A) 음이온 및 양이온 계면활성제 및 이들의 혼합물중에서 선택되는 적어도 하나의 계면활성제로 안정화된 α,ω-(디히드록시)폴리디오루가노실옥산의 수-중-유타입 유탁액 100중량부, (B) 분자당, 하기식의 단위들중에서 적어도 둘의 상이한 단위들을 함유하는 히드록실화 실리콘 수지 1~100중량: R3SiO0.5, R2SiO, RSiO1.5및 SiO2(라디칼 R은 동일하거나 상이하며, 비닐, 페닐 및 3,3,3-트리플루오로프로필 라디칼 및 탄소원자수 1 내지 6의 직쇄 또는 분지쇄 알킬라디칼임)(상기 수지의 히드록실기중량 함량은 0.1~10%임). (C) 비규산질무기충전제 0~250중량부, (D) 금속경화촉매화합물 0.01~3중량부 : 를 포함하며 고형물함량이 적어도 40%인 것을 특징으로 하는, 주위조건에서 수분제거로써 엘라수토머로 가교결합하는 수성 실리콘 분산액.
  2. 제1항에 있어서, 수지 (B)가 MQ, MDQ, TD 및 MDT 수지중에서 선택됨을 특징으로 하는 수성분산액.
  3. 제1항 또는 제2항에 있어서, 수지 (B)가 평균분자량이 25,000 이하인 톨루엔-가용성액체 또는 고체 수지임을 특징으로 하는 수성분산액.
  4. 제1항 내지 제3항중 어느 한 항에 있어서, 금속화합물 (D)가 수성유탁액 형태인 유기주석염(D)인 것을 특징으로 하는 수성분산액.
  5. 제1항 내지 제4항중 어느 한 항에 있어서, 유탁액 (A)의 고형물함량이 적어도 45중량%인 것을 특징으로 하는 수성실리콘 분산액.
  6. 제1항 내지 제5항중 어느 한 항에 있어서, 수화알루미나, 알루미나, 탄산칼슘, 팽창페어미클라이트, 비팽창베어미클라이트, 카본블랙, 산화아연, 이산화티탄, 운모, 활석, 산화철, 황산바륨 및 소석회 중에서 선택되는 충전제 (C) 5~200중량부를 포함하는 것을 특징으로 하는 수성 실리콘 분산액.
  7. 제6항에서 있어서, 탄산칼슘의 평균입경이 0.1μm 이하인 것을 특징으로 하는 수성실리콘 분산액.
  8. 제1항 내지 제7항중 어느 한 항에 있어서, (A) 25℃에서 점도가 50,000~1,500,000Pas이고 방향족 탄화수소 술폰산의 알칼리금속염과 폴리옥시에틸렌화 알킬페놀중에서 선택되는 계면활성제로 안정화된 a,s-(디히드록시)폴리디오루가노실옥산의 수-중-유타입 유탁액 100부, (B) 히드록실화 실리콘 수지 2~20부, (C) 무기충전제, 50~200부, (D) 디오루가노틴 디카르복실레이트 0.05~2부 : 를 포함하며 고형물함량이 적어도 60%인 것을 특징으로 하는 수성실리콘 분산액.
  9. 제1항 내지 제8항중 어느 한 항에 있어서, 유탁액 (A) 100부당 규산나트륨 (0.3~30부) 및 보강 또는 반보강 규산질 충전제(1~150부)를 부가적으로 포함하며, 단 (C)+(E)의 부의 합은 (A) 100부당 300부 이하인 것을 특징으로 하는 수성실리콘 분산액.
  10. 제1항 내지 제9항중 어느 한 항에 있어서, 오루가노트리알콕시실란, 알킬실리케이트 및 알킬폴리실리케이트 중에서 선택되는 부착촉진제 (F) 0.01~20중량부를 부가적으로 포함하는 것을 특징으로 하는 수성 분산액.
  11. 제1항 내지 제10항중 어느 한 항에 있어서, 유탁액 (A) 100부당 0.1~5부의 산소화 붕소유도체를 부가적으로 포함하는 것을 특징으로 하는 수성분산액.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890012552A 1988-08-31 1989-08-31 수분제거에 의해 엘라스토머로 가교결합할 수 있는 실리콘 수지기재 수성 분산액 KR930003699B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR8811609A FR2638166B1 (fr) 1988-08-31 1988-08-31 Dispersion aqueuse a base de resine silicone pouvant reticuler en un elastomere par elimination de l'eau
FR88-11609 1988-08-31
FR11609 1988-08-31

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KR900003306A true KR900003306A (ko) 1990-03-26
KR930003699B1 KR930003699B1 (ko) 1993-05-08

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EP (1) EP0359676B1 (ko)
JP (1) JPH0645756B2 (ko)
KR (1) KR930003699B1 (ko)
CN (1) CN1030460C (ko)
AT (1) ATE96824T1 (ko)
AU (1) AU627217B2 (ko)
BR (1) BR8904277A (ko)
CA (1) CA1326097C (ko)
DE (1) DE68910449T2 (ko)
DK (1) DK175833B1 (ko)
ES (1) ES2047700T3 (ko)
FI (1) FI894073A (ko)
FR (1) FR2638166B1 (ko)
HU (1) HUT53140A (ko)
IE (1) IE63399B1 (ko)
NO (1) NO893437L (ko)
NZ (1) NZ230469A (ko)
PT (1) PT91587A (ko)
ZA (1) ZA896630B (ko)

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FR2637606B1 (fr) * 1988-10-11 1990-12-14 Rhone Poulenc Chimie Dispersion aqueuse de silicone a base d'alcenyloxysilane reticulant en un elastomere par elimination de l'eau
DE4026029A1 (de) * 1989-09-07 1992-02-20 Sandoz Ag Waessrige aminopolysiloxanmikroemulsionen, deren herstellung und verwendung
DE4217561A1 (de) * 1992-05-27 1993-12-02 Wacker Chemie Gmbh Wäßrige Dispersionen von Organopolysiloxanen
US5449712A (en) * 1993-01-13 1995-09-12 Thoro System Products, Inc. Organosilicon emulsions for rendering porous substrates water repellent
US5895794A (en) * 1993-08-30 1999-04-20 Dow Corning Corporation Shelf stable cross-linked emulsions with optimum consistency and handling without the use of thickeners
FR2746052B1 (fr) * 1996-03-15 1998-07-03 Procede de moulage et d'hydrofugation d'elements moules en beton, mortier, ciment, par une resine silicone
DE19934438B4 (de) * 1999-07-22 2008-01-17 Wacker Chemie Ag Verfahren zur Herstellung einer wässrigen 1-Komponenten Siliconzusammensetzung
US20070116969A1 (en) * 2003-10-08 2007-05-24 Yihan Liu Silicone mq resin reinforced silicone elastomeric emulsions
JP4678402B2 (ja) * 2007-11-02 2011-04-27 信越化学工業株式会社 皮膜形成性オルガノポリシロキサンエマルジョン組成物及び繊維用風合い改良剤
DE102007060919A1 (de) 2007-12-14 2009-06-18 Henkel Ag & Co. Kgaa Härtbare Zusammensetzungen enthaltend wässrige Dispersionen von Organopolysiloxanen
DE102008003155A1 (de) 2008-01-03 2009-07-09 Henkel Ag & Co. Kgaa Härtbare Zusammensetzungen enthaltend wässrige Dispersionen von Organopolysiloxanen
WO2009077389A1 (de) 2007-12-14 2009-06-25 Henkel Ag & Co. Kgaa Härtbare zusammensetzungen enthaltend wässrige dispersionen von organopolysiloxanen
JP4678411B2 (ja) * 2008-02-22 2011-04-27 信越化学工業株式会社 皮膜形成性オルガノポリシロキサンエマルジョン組成物
JP5608909B2 (ja) * 2010-01-08 2014-10-22 モメンティブ・パフォーマンス・マテリアルズ・ジャパン合同会社 室温硬化性ポリオルガノシロキサン組成物
JP2016027069A (ja) * 2014-06-26 2016-02-18 日東電工株式会社 難燃材料およびその用途

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US3070560A (en) * 1959-01-19 1962-12-25 Dow Corning Composition comprising a polysiloxane resin, silica filler, a hydroxylated siloxane, and a boron compound
US4257932A (en) * 1978-06-27 1981-03-24 General Electric Company Curable compositions and process
DE3323909A1 (de) * 1983-07-02 1985-01-10 Bayer Ag, 5090 Leverkusen Stabile siliconemulsionen
FR2565593B1 (fr) * 1984-06-12 1986-12-12 Rhone Poulenc Spec Chim Compositions d'emulsions aqueuses pour le traitement antiadherent et hydrofuge de materiaux cellulosiques
JPH0639568B2 (ja) * 1985-04-24 1994-05-25 東レ・ダウコーニング・シリコーン株式会社 シリコ−ン水性エマルジヨン組成物の製造方法
DE3637836A1 (de) * 1986-11-06 1988-05-19 Wacker Chemie Gmbh Waessrige silicondispersionen
DE3727180A1 (de) * 1987-08-14 1989-02-23 Wacker Chemie Gmbh Waessrige silicondispersionen
GB8806145D0 (en) * 1988-03-15 1988-04-13 Unilever Plc Electrical sensor & method

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AU627217B2 (en) 1992-08-20
PT91587A (pt) 1990-03-30
AU4086889A (en) 1990-03-08
JPH02105859A (ja) 1990-04-18
JPH0645756B2 (ja) 1994-06-15
EP0359676A1 (fr) 1990-03-21
HUT53140A (en) 1990-09-28
IE892793L (en) 1990-02-28
DK175833B1 (da) 2005-03-21
DE68910449T2 (de) 1994-05-11
CN1030460C (zh) 1995-12-06
EP0359676B1 (fr) 1993-11-03
CN1040997A (zh) 1990-04-04
NO893437L (no) 1990-03-01
DK426689D0 (da) 1989-08-30
FR2638166B1 (fr) 1991-01-11
ZA896630B (en) 1990-05-30
FI894073A (fi) 1990-03-01
BR8904277A (pt) 1990-04-17
FR2638166A1 (fr) 1990-04-27
DK426689A (da) 1990-03-01
ES2047700T3 (es) 1994-03-01
CA1326097C (fr) 1994-01-11
NZ230469A (en) 1991-09-25
DE68910449D1 (de) 1993-12-09
IE63399B1 (en) 1995-04-19
FI894073A0 (fi) 1989-08-30
KR930003699B1 (ko) 1993-05-08
NO893437D0 (no) 1989-08-28
ATE96824T1 (de) 1993-11-15

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