KR900002926B1 - A process for the preparation of a industrial creanlike detergent - Google Patents
A process for the preparation of a industrial creanlike detergent Download PDFInfo
- Publication number
- KR900002926B1 KR900002926B1 KR1019870015257A KR870015257A KR900002926B1 KR 900002926 B1 KR900002926 B1 KR 900002926B1 KR 1019870015257 A KR1019870015257 A KR 1019870015257A KR 870015257 A KR870015257 A KR 870015257A KR 900002926 B1 KR900002926 B1 KR 900002926B1
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- South Korea
- Prior art keywords
- parts
- added
- ethylene oxide
- kaolin
- detergent
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
본 발명은 카오린에 생분해성이 양호한 에탄올아민류의 용제와 에틸렌옥사이드가 부가된 야자유를 흡착시켜 공업용색소 유류 등으로 오염된 피부 및 섬유를 세척 및 마찰(문지름) 등에 의해 제거할 수 있도록 한 약알카리성 공업용 크림세제의 제조방법에 관한 것이다.The present invention provides a weak alkaline industrial adsorbent for adsorbing solvents of ethanolamines with good biodegradability and palm oil added with ethylene oxide to kaolin to remove skin and fibers contaminated with industrial pigment oils by washing and rubbing. It relates to a method for producing a cream detergent.
일반적으로 나염공장에서 피부 또는 섬유에 색소가 오염되었을 경우 소디움 하이드로 설파이드, 요소 및 가성소다를 물에 녹여 이를 솔에 묻혀서 닦아내고 있는데, 이경우 상기한 용액이 강알카리성 임으로해서 피부에 탈지현상을 일으키거나 건조파열을 유발시키게되어 작업자에게 불이익을 가져오게할 염려가 있으며, 또한 기존하는 세탁용 합성세제는 세척시 다량의 거품이 생겨 헹굼에 곤란을 느끼게할뿐만이 아니라 세탁시 다량의 인산염이 방출되기때문에 이로인한 수질의 오염으로 공해문제의 원인이되기도 하였던 것이 현실정이다.In general, when dyes are contaminated with skin or textiles in a printing factory, sodium hydrosulfide, urea and caustic soda are dissolved in water and wiped off with a brush.In this case, the solution is strongly alkaline and causes degreasing or drying on the skin. This may cause a rupture, which may cause disadvantages to the worker. In addition, conventional synthetic detergents may cause a large amount of foam during washing, which may cause difficulty in rinsing, and also cause large amounts of phosphate to be released during washing. It is a fact that water pollution has also caused pollution problems.
본 발명은 이러한 종래의 제결함을 해소시키기위해 생분해성이 양호한 에탄올아민류 및 에틸렌옥사이드가 부가된 야자유를 카오린에 흡착시킴과 동시에 약알카리성 환원제를 사용하여 산화 환원반응을 유발시켜 표백작용을 하게함으로서 공업용 색소 및 유류 등으로 오염된 피부 및 섬유를 세정시키는 세제를 얻고자 하는데 그 목적을 둔것으로서 이를 아래의 제조공정에 의해 상세히 설명하면 다음과 같다.The present invention is to absorb bleaching action by using a weakly alkaline reducing agent to adsorb the palm oil added to the biodegradable ethanolamines and ethylene oxide to the kaolin to solve the conventional defects, and to industrialize the bleaching action The purpose of the present invention is to obtain a detergent for cleaning skin and fibers contaminated with pigments and oils, which are described in detail by the following manufacturing process.
제 1 공정: 에탄올 아민유도체 30-40부, 에틸렌옥사이드 수용액 10-0부, 에틸렌옥사이드가 부가된 야자유 10-0부를 40-90℃에서 가열 숙성농축시킨후 다시 여기에 카오린 30-10부를 첨가하여 RPM 50으로 3시간정도 서서히 교반흡착시켜 이를 상온으로 냉각시킨다.First step: 30-40 parts of ethanol amine derivative, 10-0 parts of ethylene oxide aqueous solution, 10-0 parts of palm oil to which ethylene oxide was added were heated and concentrated at 40-90 ° C., and then 30-10 parts of kaolin was added thereto. Stir and adsorb slowly with RPM 50 for 3 hours to cool it to room temperature.
제 2 공정: 요소(Urea) 10-30부, 환원성표백제 10-20부와 첨가제(재오염방지제, 피부보호제, 안정제, 향)를 0.02부 첨가한후 상기한 제 1 공정에서 얻은 내용물과 함께 RPM 50으로 1시간정도 서서히 교반하여 크림상의 세제를 얻는다.Second process: 10-30 parts of urea, 10-20 parts of reducing bleach and 0.02 parts of additives (anti-contamination agent, skin protectant, stabilizer, fragrance) are added and the RPM together with the contents obtained in the first process described above. Slowly stir at 50 for 1 hour to obtain a creamy detergent.
상기한 공정으로 얻어지는 본 발명은 생분해성이 양호함과 동시에 약알칼리성의 소포성 임으로서 세척시 거품이 생기지 않아 헹굼이 양호하고, 또한 생분해성이 양호하여 세척시 물과 기름 등의 물질이 서로 별개의 군으로 분리형성되는 부유층이 생성되지 않음으로해서 세척후 세척용기 내주면에 상기한 부유층이 달라붙는 현상을 방지하게 되는 것이며, 휘발성이 없어 화재의 위험에서 벗어나게될 뿐만 아니라, 인산염이 전혀 함유되어 있지 않고 피부보호제가 함유되어 종래처럼 세제를 사용할시 초래되었된 피부의 탈지현상이나 건조파열 등의 현상을 미연에 방지하면서도 세척시 장갑을 사용치 않아도 피부가 손상될 염려없는 것이다.The present invention obtained by the above process has good biodegradability and weak alkaline antifoaming, so that foam does not form during washing, so rinsing is good, and the biodegradability is good, so that water and oil and the like are separated from each other. Since no floating layer is formed in the group, the floating layer is prevented from sticking to the inner circumferential surface of the washing container after washing, and it is free from volatile and does not contain any phosphate. It contains a skin protection agent and prevents skin degreasing or dry rupture caused by using a detergent as in the prior art, but there is no fear of damaging the skin even without using gloves when washing.
또한 본 발명에서는 생분해성이 양호한 에탄올 아민류 및 에틸렌옥사이드가 부가된 야자유를 카오린에 흡착시킴으로해서 물과 반응하여 산화, 환원반응에 의해 표백 및 세척의 효과를 일층 높여줌과 동시에 그 사용이 간편하여 일상생활에 큰 도움을 주게되는 공해방지의 신규유용의 발명인 것이다.In the present invention, by adsorbing palm oil added ethanol amines and ethylene oxide having good biodegradability to kaolin, it reacts with water to enhance the effect of bleaching and washing by oxidation and reduction reactions, and at the same time, its use is simple. It is a new useful invention of pollution prevention that is greatly helped.
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1019870015257A KR900002926B1 (en) | 1987-12-29 | 1987-12-29 | A process for the preparation of a industrial creanlike detergent |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1019870015257A KR900002926B1 (en) | 1987-12-29 | 1987-12-29 | A process for the preparation of a industrial creanlike detergent |
Publications (2)
Publication Number | Publication Date |
---|---|
KR890010177A KR890010177A (en) | 1989-08-07 |
KR900002926B1 true KR900002926B1 (en) | 1990-05-03 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019870015257A KR900002926B1 (en) | 1987-12-29 | 1987-12-29 | A process for the preparation of a industrial creanlike detergent |
Country Status (1)
Country | Link |
---|---|
KR (1) | KR900002926B1 (en) |
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1987
- 1987-12-29 KR KR1019870015257A patent/KR900002926B1/en not_active IP Right Cessation
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Publication number | Publication date |
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KR890010177A (en) | 1989-08-07 |
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