KR900002927B1 - A process for the preparation of creanlike detergent for removing oil - Google Patents

A process for the preparation of creanlike detergent for removing oil Download PDF

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Publication number
KR900002927B1
KR900002927B1 KR1019870015258A KR870015258A KR900002927B1 KR 900002927 B1 KR900002927 B1 KR 900002927B1 KR 1019870015258 A KR1019870015258 A KR 1019870015258A KR 870015258 A KR870015258 A KR 870015258A KR 900002927 B1 KR900002927 B1 KR 900002927B1
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South Korea
Prior art keywords
parts
detergent
kaolin
urea
removing oil
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KR1019870015258A
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Korean (ko)
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KR890010178A (en
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이상영
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권충세
이상영
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Priority to KR1019870015258A priority Critical patent/KR900002927B1/en
Publication of KR890010178A publication Critical patent/KR890010178A/en
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Publication of KR900002927B1 publication Critical patent/KR900002927B1/en

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

A process for prepg. creamlike detergent for removing oil comprises (a) heat-concentrating the mixt. of ethanolamines of 30-40 wt.%, ethyleneoxide aq. soln. of 0-10 wt.% and coconut oil of 0-10 wt.% added with ethyleneoxide for 3hr at 40-90 deg.C; (b) mixing kaoline of 20-30 wt.%, urea of 20-30 wt.% and additive (stabilizer, skin protector, perfume); and (c) adding the (b)-soln. to the (a)-soln. in a stirrer (at 50 rpm for 3hr) at 40-90 deg.C, and cooling at room temp.

Description

유류제거용 크림세제의 제조방법Manufacturing method of cream detergent for oil removal

본 발명은 피부에 오염된 공업용 유류 또는 유지의 제거는 물론, 각종 공구류나 금속표면에 이물질과 함께 고착된 기계유등을 세척 또는 마찰(문지름)에 의해서 손쉽게 제거할 수 있도록하기 위하여 카오린(Kaoline)에 아민류를 흡착시킨 약 알카리성 크림세제의 제조방법에 관한 것이다.The present invention is not only to remove industrial oils or fats contaminated with skin, but also to remove various kinds of tools and metal oils with foreign matter on the surface of Kaolin to easily remove them by washing or rubbing. It relates to a method for producing a weak alkaline cream detergent obtained by adsorbing amines.

일반적으로 가정용이나 공업용으로 사용되고 있는 합성세제는 알킬벤젠 설포네이트(A.B.S)가 주원료로 되어있어 생분해도가 낮고, 인산염의 다량방출로서 수질오염에 따른 공해문제를 야기시키고 있는 것이 현실정이다. A.B.S계의 세제를 사용할 경우 피부독성으로 인하여 피부의 탈지 및 접촉성 피부염을 유발시키는 것으로 알려져 있어서 보호장갑의 착용을 필요로 하였으며, 상기와 같은 종래의 합성세제는 세탁시에는 다량의 거품을 발생시킴으로서 헹굼에 곤란을 느낄 뿐만 아니라 헹굼에 소요되는 과량의 물과 시간으로서 그 경제성마저 결여되고 있는 것이다.Generally, synthetic detergents used for household and industrial use are mainly composed of alkyl benzene sulfonate (A.B.S), which is low in biodegradation, and causes large amounts of phosphate to cause pollution due to water pollution. The use of ABS-based detergents is known to cause skin degreasing and contact dermatitis due to skin toxicity, which requires the wearing of protective gloves. Such conventional synthetic detergents generate a large amount of foam during washing. Not only is it difficult to rinse, but it is also lacking in economy as an excessive amount of water and time required for rinsing.

본 발명은 상기와 같은 종래의 합성세제에 있어서의 제결함을 해소하고자 보다 양호한 세정력, 침투력을 갖고 세탁시의 헹굼성을 향상시키기 위해 소포성으로 생분해성이 좋은 약 알카리성 크림세제를 제공하는데 그 목적을 둔 것으로서 이를 아래의 제조공정에 의해 상세히 설명하면 다음과 같다.The present invention is to provide a weak alkaline deodorizing cream detergent having a good detergency, biodegradability to improve the rinsability during washing in order to eliminate the defects in the conventional synthetic detergent as described above. If it is described in detail by the following manufacturing process as follows.

제 1 공정: 에타놀아민류 40-30부, 에틸렌 옥사이드수용액 10-0부, 에틸렌옥사이드가 부가된 야자유 0-10부를 40-90℃에서 3시간 가열 농축시킨 후 상온에서 냉각시킨다.First step: 40-30 parts of ethanolamines, 10-0 parts of aqueous ethylene oxide solution, and 0-10 parts of palm oil to which ethylene oxide was added are concentrated by heating at 40-90 ° C. for 3 hours, and then cooled at room temperature.

제 2 공정: 카오린(Kaoline) 20-30부, 요소(Urea) 30-20부를 제 1 공정에서 얻어진 내용물에 혼합하되, 첨가제(안정제, 피부보호제, 향)를 0.1부 부가 혼합하고, 이때 40-90℃에서 3시간정도 RPM 50으로 서서히 혼합한 후 상온에서 냉각시켜 크림상의 세제를 생성시킨다.Second step: 20-30 parts of kaoline and 30-20 parts of urea are mixed with the contents obtained in the first step, but 0.1 part of an additive (stabilizer, skin protectant, fragrance) is mixed, wherein 40- After slowly mixing at 50 ° C. for 3 hours at 90 ° C., the mixture is cooled to room temperature to form a creamy detergent.

상기한 공정으로 얻어지는 본 발명의 크림상 세제는 인산염을 전혀 사용치 않았고 피부보호제가 함유되어 피부의 탈지나 접촉성 피부염을 발생시키지 않을 뿐만 아니라 휘발성이 희박하여 화재의 염려가 없고 또한 본 발명은 생분해성이 양호한 약 알칼리성의 소포성이어서 세탁헹굼이 거품의 발생이 적음으로해서 종래처럼 세탁물의 헹굼시 과량의 물과 시간을 낭비할 염려가 없어 경제성이 풍부하게 되는 한편 세탁시 물과 기름이 별개의 군으로 형성되어 부유층이 발생하지 않음으로서 세탁후에도 세탁용기에 오물이 달라붙는 폐단 역시 지양한 것으로서 종래의 합성세제에 비하여 공해의 염려가 없어 그 실사용가치를 일층 고양시키는 신규의 발명인 것이다.The creamy detergent of the present invention obtained by the above-mentioned process does not use phosphate at all and contains a skin protective agent, which does not cause skin degreasing or contact dermatitis, but also has a low volatility, so there is no fear of fire, and the present invention is biodegradable Because of its weak alkaline defoaming properties, washing rinsing is less likely to generate bubbles, so there is no fear of wasting excess water and time when rinsing laundry. It is a novel invention to increase the actual value of use as there is no fear of pollution compared to the conventional synthetic detergents because it is also formed as a group does not generate a floating layer to cling to the washing container even after washing.

Claims (4)

에타놀아민류 40-30부, 에틸렌옥사이드수용액 10-0부 에틸렌 옥사이드가 부가된 야자유 0-10부를 40-90℃에서 3시간 가열농축하여 이를 상온에서 냉각시키는 제 1공정과 카오린 20-30부, 요소(Urea) 30-20부를 제1공정에서 얻은 내용물과 혼합하되 첨가제(안정제, 피부보호제, 향)를 0.1부 부가시켜 40-90℃에서 3시간정도 RPM50으로 서서히 혼합한 후 상온에서 냉각시키는 제2공정으로 이루워지는 것을 특징으로 하는 유류제거용 크림세제의 제조방법.40-30 parts of ethanolamine, 10-0 parts of ethylene oxide aqueous solution 0-10 parts of palm oil to which ethylene oxide was added and heated and concentrated at 40-90 ° C. for 3 hours and 20-30 parts of kaolin and urea (Urea) Mix 30-20 parts with the contents obtained in the first step, but add 0.1 parts of additives (stabilizer, skin protector, fragrance), and slowly mix with RPM50 for about 3 hours at 40-90 ° C., and then cool at room temperature. Process for producing an oil removal cream detergent, characterized in that made in the process. 제 1항에 있어서, 카오린에 아민류를 흡착시키는 것.The amine adsorbed on kaolin according to claim 1. 제 2항에 있어서, 카오린에 아민류를 흡착시키는 온도를 40℃로 하는 것.The temperature at which amines are adsorbed to kaolin is 40 ° C. 제 1항에 있어서의 첨가를 펙틴으로 하고, 그 첨가비율을 0.05부로 하는 것.The addition of Claim 1 is made into pectin, and the addition rate shall be 0.05 part.
KR1019870015258A 1987-12-29 1987-12-29 A process for the preparation of creanlike detergent for removing oil KR900002927B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019870015258A KR900002927B1 (en) 1987-12-29 1987-12-29 A process for the preparation of creanlike detergent for removing oil

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Application Number Priority Date Filing Date Title
KR1019870015258A KR900002927B1 (en) 1987-12-29 1987-12-29 A process for the preparation of creanlike detergent for removing oil

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KR890010178A KR890010178A (en) 1989-08-07
KR900002927B1 true KR900002927B1 (en) 1990-05-03

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