KR900002925B1 - A process for the preparation of creanlike detergent for removing oil - Google Patents
A process for the preparation of creanlike detergent for removing oil Download PDFInfo
- Publication number
- KR900002925B1 KR900002925B1 KR1019870015256A KR870015256A KR900002925B1 KR 900002925 B1 KR900002925 B1 KR 900002925B1 KR 1019870015256 A KR1019870015256 A KR 1019870015256A KR 870015256 A KR870015256 A KR 870015256A KR 900002925 B1 KR900002925 B1 KR 900002925B1
- Authority
- KR
- South Korea
- Prior art keywords
- parts
- ethylene oxide
- oil
- added
- detergent
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
- C11D11/0094—Process for making liquid detergent compositions, e.g. slurries, pastes or gels
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
Abstract
Description
본 발명은 피부에 오염된 공업용 유류의 제거는 물론 각종공구류나 금속표면에 이물질과 함께 고착된 기계유 등을 세척 및 마찰(문지름) 등에 의해서 제거할 수 있도록 하기 위하여 에틸렌 옥사이드가 부가된 야자유를 주원료로한 세제로서 그 구조식은 다음과 같다.The present invention is to remove the industrial oil contaminated with the skin as well as palm oil added with ethylene oxide as a main raw material in order to be able to remove various kinds of tools and machine oils fixed with foreign matter on the metal surface by washing and rubbing. As a detergent, the structural formula is as follows.
여기서 R=C7H15, n=5-20이다.Wherein R = C 7 H 15 , n = 5-20.
일반적으로 각종기계유 및 공업용 폐유 등으로 손등과 피부가 오염되었을 경우에 있어서는 휘발유, 신나, 벤졸같은 인화성물질을 사용하여 이를 용해시킨후 다시 알카리성유지(세제)로 세척하는 것이 통상적인 사용례인데, 이경우 상기한 인화성물질을 사용함으로서, 발화의 위험성과 피부막의 건조파열을 조장함에 따른 부작용을 초래하고 있을뿐만이 아니라, 세척력이 완전하지 못하고, 또한, 설령 세척이 되었다하더라도 물과 기름이 별개의 군으로 분리되어 부유층을 생성시키게 되고, 또한 이부유층은 타물체에 강력한 부착현상을 일으킴으로해서 세척용기에 주변이 항상 상기한 부유층의 부착현상을 가져오게됨으로해서 세척후 또다시 세척한 용기까지도 세척하여야하는 등의 제결함을 야기시켰던 것이며, 또한 기존에 있어서 가정용이나 공업용으로 사용하고 있는 합성세제의 경우를 살펴보면, 알킬벤젠 설포네이트(A.B.S)가 주원료로서 그 생분해도가 낮고, 인산염의 다량반출로해서 부유층의 생성은 물론 수질오염에 따른 공해의 원인을 초래함과 동시에 사용시 피부 독성으로 인하여 피부의 탈지와 접촉성 피부염들을 유발시키는 것이 현실정이었다.In general, when the back of the hand and skin are contaminated with various machine oils and industrial waste oils, it is common practice to dissolve them using flammable substances such as gasoline, thinner and benzol, and then wash them with alkaline oils (detergents). The use of a flammable substance not only causes the risk of ignition and the side effects of promoting dry rupture of the skin membrane, but also the inability to clean, and even if washed, water and oil are separated into separate groups. In addition, the floating layer generates strong adhesion to other objects, so that the surroundings always bring the above-mentioned floating layer to the cleaning container, and thus the container that has been washed again after washing should be cleaned. Caused defects, and in the past In the case of the synthetic detergent used in the present invention, alkylbenzene sulfonate (ABS) is the main raw material, its biodegradability is low, and the large amount of phosphate is released, causing not only the formation of the floating layer but also the cause of pollution due to water pollution. It has been a reality to induce skin degreasing and contact dermatitis due to skin toxicity during use.
본 발명은 이와같은 상기의 제결함을 감안하여 생분해도가 양호한 고급 알콜계의 천연 계면 활성제를 주원료로 하여 부유층의 생성이 없이 오염된 유류를 손쉽게 세척할 수 있음은 물론 화재의 위험성이 없고 피부 보호제를 함유한 중성세제임으로 오히려 피부의 탈지나 접촉성피부염을 미연에 방지하여 주게되는 것이다.In view of the above deficiencies, the present invention uses a high biodegradable natural alcohol-based surfactant as a main raw material, so that contaminated oils can be easily washed without generating a floating layer, and there is no risk of fire, and a skin protectant. It is a neutral detergent that contains rather it will prevent skin degreasing or contact dermatitis in advance.
또한 세척후에도 종래처럼 물과 유류가 별도군으로 분리되는 부유층현상이 없어서 세척한 후에도 세척용기 내주면이 항시 청결한 상태를 유지케하는 것으로서 그 제조방법을 다음의 공정에 의거 상세히 설명하면 다음과 같다.In addition, there is no floating layer phenomenon in which water and oil are separated into separate groups even after washing, so that the inner circumferential surface of the washing container is always kept clean even after washing. The manufacturing method will be described in detail based on the following process.
제 1공정 : 에틸렌옥사이드가 5내지 20몰의 부가된 야자유 10내지 20부, 상화에틸렌 수용액 0내지 5부, 파라핀 오일 20내지 30부 및 지방족 유기용매 40내지 30부를 혼합하여 이를 40-90℃에서 3시간 정도 가열 농축하여 이를 숙성시킨후 40℃로 유지한다.First step: 10 to 20 parts of added palm oil with 5 to 20 moles of ethylene oxide, 0 to 5 parts of aqueous ethylene solution, 20 to 30 parts of paraffin oil, and 40 to 30 parts of aliphatic organic solvent are mixed at 40-90 ° C. The mixture was heated and concentrated for 3 hours to mature and then maintained at 40 ° C.
제 1 공정에서 야자유에 에틸렌옥사이드등의 몰수 5내지 20범위에서 부가 몰수가 큰것과 작은 것과의 차이는 작은 것이 공업유에 대한 세정력 침투력이 우수하여 에틸렌옥사이드산화물은 물과 반응하여 에틸렌그리콜을 생성시킴으로해서 공업유에 대해 보다 양호한 침투력을 가지게 하여 주는 것임으로 본 발명에서는 야자수에 부가되는 에틸렌옥사이드의 몰수를 적은쪽으로 선택하는 것이 바람직하다.In the first process, the difference between the large number of moles of ethylene oxide and the like and the small number of added moles in the oil process is small and small in the range of 5 to 20. Since the ethylene oxide oxide reacts with water to produce ethylene glycol, Therefore, in order to have better penetrating power with respect to industrial oil, in this invention, it is preferable to select the number-of-moles of ethylene oxide added to a palm tree to a smaller one.
제 2 공정 : 몰 30내지 15부에 첨가제(재오염방지제, 피부보호제, 안전제, 향) 0.2부를 첨가하여 녹인후 40℃로 유지케한다.Second step: Add 0.2 parts of additive (anti-contamination agent, skin protector, safety agent, fragrance) to 30 to 15 moles of molten material and keep it at 40 ℃.
제 3 공정 : 제 1 공정에서 얻은 내용물과 제 2 공정에서 얻은 내용물을 40℃에서 혼합하여 이를 RPM 50으로 60분정도 교반시킨후 상온으로 급냉하여 크림상의 중성세제를 얻는다.3rd process: The content obtained in the 1st process and the content obtained in the 2nd process are mixed at 40 degreeC, this is stirred for 60 minutes by RPM50, it is quenched to room temperature, and a creamy neutral detergent is obtained.
상기한 공정에서 얻은 본발명은 인산염의 사용을 배제하고 친수성에틸렌옥사이드가 부가된 야자유를 주원료로한 비이온 계면활성제를 사용함으로서 침투력이 월등하고, 생분해성이 양호하여 수질오염에 따른 공해 발생이 전혀 없는 중성세제로서 화재의 위험성이 없을뿐만아니라 세척후 피부의 탈지현상이나 접촉성 피부염의 발생을 미연에 방지케함은 물론 종래처럼 세척시 물과 유류가 별개의 군으로 형성되는 부유층의 생성으로 인하여 세척용기 내주연에 상기한 부유층의 결착되기 때문에 세척후 그 세척용기까지 다시 세척시켜야하는 폐단에 비하여 본발명은 세척시 물과 유류가 별도의 군으로 형성되는 부유층의 생성을 억제시킴으로해서 세척물의 세척후에도 그 세척용기가 항시 청결한 상태를 이루는 점역시 새로운 효과가 아닐 수 없다 할 것이며, 본 발명을 실사용할경우의 예를 살펴보면, 우선, 공장내에서 기계류를 취급하다가 갑작스럽게 더렵혀진 손을 씻고자할때는 본 발명의 크림소량을 손바닥에 놓고 양손으로 일반적으로 크림을 바르듯이 바른후 서너번 계속적으로 손과 손을 서로 마찰시켜주게되면 유류로 더럽혀진 손 피부가 완전히 세척되는데 이때 물이 있으면 별도의 비누 등을 사용하지 않고 그냥 헹구워주게되면 더욱 좋은 것이나, 물이 없을 경우에는 휴지 등으로 닦아내어도 무방하며 오히려 피부에 좋은 결과를 가져오게되는 발명은 그 용도 역시 다양하여 세탁용으로 할시에는 본 발명은 소포성임으로 거품의 발생이 없이 그 헹굼성이 풍부하다하겠으며, 그밖에 일반적으로 사용하는 비누의 대용으로 사용하여 월등한 효과를 얻을 수 있는 신규유용의 획기적인 발명이라 하겠다.The present invention obtained in the above process is a non-ionic surfactant whose main ingredient is palm oil to which hydrophilic ethylene oxide is added, excluding the use of phosphate, so that the penetration is excellent and biodegradability is good, so there is no pollution caused by water pollution. It is not a neutral detergent and there is no risk of fire, and it prevents the degreasing of the skin and the occurrence of contact dermatitis after washing, as well as cleaning due to the formation of a floating layer in which water and oil are formed in separate groups when washing. Compared to the closed end where the above-mentioned floating layer binds to the inner circumference of the container and needs to be washed again after the washing, the present invention suppresses the formation of the floating layer in which water and oil are formed in separate groups during washing. When the washing container is always clean, it is a new effect. If you look at an example of the practical use of the present invention, first of all, when handling the machinery in the factory to wash the hands dirty suddenly, put a small amount of the cream of the present invention on the palm of the hand and apply the cream in general with both hands If you rub your hands three or four times in a row, the oiled soil of your hand is completely washed. If there is water, it is better to rinse it without using a separate soap, etc. Invention that can be wiped off, but rather good results on the skin has a variety of uses also when used for washing the present invention is a defoaming because it is rich in rinsability without the generation of bubbles, and other commonly used soap Innovative invention of new utility that can be used as a substitute for I will.
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019870015256A KR900002925B1 (en) | 1987-12-29 | 1987-12-29 | A process for the preparation of creanlike detergent for removing oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019870015256A KR900002925B1 (en) | 1987-12-29 | 1987-12-29 | A process for the preparation of creanlike detergent for removing oil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR890010176A KR890010176A (en) | 1989-08-07 |
| KR900002925B1 true KR900002925B1 (en) | 1990-05-03 |
Family
ID=19267573
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019870015256A KR900002925B1 (en) | 1987-12-29 | 1987-12-29 | A process for the preparation of creanlike detergent for removing oil |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR900002925B1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11180716B2 (en) * | 2017-07-28 | 2021-11-23 | Croda, Inc. | Cleaning formulation comprising a solvent additive |
-
1987
- 1987-12-29 KR KR1019870015256A patent/KR900002925B1/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| KR890010176A (en) | 1989-08-07 |
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