KR900001783A - 저점도 에폭시수지 조성물 - Google Patents

저점도 에폭시수지 조성물 Download PDF

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Publication number
KR900001783A
KR900001783A KR1019890010696A KR890010696A KR900001783A KR 900001783 A KR900001783 A KR 900001783A KR 1019890010696 A KR1019890010696 A KR 1019890010696A KR 890010696 A KR890010696 A KR 890010696A KR 900001783 A KR900001783 A KR 900001783A
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South Korea
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weight
parts
resin composition
methylimidazole
thermosetting resin
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KR1019890010696A
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English (en)
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KR0143782B1 (ko
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마코비쯔 마이크(엔엠엔)
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제이 엘.채스킨
제네랄 일렉트릭 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C08G59/686—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C08G59/72—Complexes of boron halides

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Epoxy Resins (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Insulating Materials (AREA)

Abstract

내용 없음

Description

저점도 에폭시수지 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 분자당 적어도 두개의 에폭사이드 그룹을 갖는 1,2에폭시수지 약 50 내지 약 95중량%, 방향족 비닐 단량체를 함유하는 반응성 희석제 약 3 내지 33중량%, 및 에폭시수지 및 반응성 희석제 100중량부당 이미다졸 화합물, 붕소 트리플루오라이드-아민 및 붕소 트리클로라이드-아민, 및 이들의 화합물로 이루어진 그룹중에서 선택된 유기 촉매 경화제를 함유하는 질소 약 1 내지 10중량부를 함유함을 특징으로 하는, 우수한 열안정성을 갖는 열경화성 수지 조성물.
  2. 제1항에 있어서, 이미다졸 화합물 촉매 경화제가 이미다졸, 1-메틸이미다졸, 2-메틸이미다졸, 1,2-디메틸이미다졸, 2-에틸이미다졸, 1-시아노에틸-2-에틸-4-메틸이미다졸, 2-페닐이미다졸, 2,4-디메틸이미다졸, 2-에틸-4-메틸이미다졸, 2-운데실이미다졸, 2-헵타데실이미다졸, 및 1-벤질-2-메틸-이미다졸, 및 이들의 화합물로 이루어진 그룹중에서 선택되는 열경화성 수지 조성물.
  3. 제1항에 있어서, 에폭시 수지를 약 50 내지 약 95중량% 함유하고 방향족 비닐 단량체 반응성 희석제를 약 3 내지 약 33중량% 함유하며, 유기촉매 경화제를 함유하는 질소가 에폭시수지 밑 반응성 희석제 100중량부당 약 2 내지 약 6중량부의 양으로 언급된 수지 및 희석제와 혼합된 열경화성 수지 조성물.
  4. 제1항에 있어서, 반응성 희석제가 비닐 톨루엔인 열경화인 수지 조성물.
  5. 분자당 적어도 두개의 에폭사이드 그룹을 갖는 1,2-에폭시수지 약 50 내지 약 95중량%, 방향족 비닐 단량체를 함유하는 반응성 희석제 약 3 내지 약 33중량%, 및 에폭시수지 및 반응성 희석제 100중량부당 이미다졸 화합물 촉매 경화제 약 1 내지 약 10중량부를 함유함을 특징으로 하는, 우수한 열안정성을 갖는 열경화성 수지 조성물.
  6. 제5항에 있어서, 이미다졸 화합물 촉매 경화제가 에폭시수지 및 반응성 희석제 100중량부당 약 2 내지 약 6중량부인 열경화성 수지 조성물.
  7. 제5항에 있어서, 이미다졸 화합물 촉매 경화제가 이미다졸, 1-메틸이미다졸, 2-메틸이미다졸, 1,2-디메틸이미다졸, 2-에틸이미다졸, 1-시아노에틸-2-에틸-4-메틸이미다졸, 2-페닐이미다졸, 2,4-디메틸이미다졸, 2-에틸-4-메틸이미다졸, 2-운데실이미다졸, 2-헵트데실이미다졸, 및 1-벤질-2-메틸이미다졸, 및 이들의 화합물로 이루어진 그룹중에서 선택되는 열경화성 수지 조성물.
  8. 제5항에 있어서, 반응성 희석제가 비닐 톨루엔인 열경화성 수지 조성물.
  9. 제5항에 있어서, 촉매 경화제가 2-에틸-4-메틸이미다졸을 함유하는 열경화성 수지 조성물.
  10. 분자당 적어도 두개의 에폭사이드 그룹을 갖는 1,2에폭시수지 약 50 내지 약 95중량%, 방향족 비닐 단량체를 함유하는 반응성 희석제 약 3 내지 33중량%, 및 에폭시수지 및 반응성 희석제 100중량부당 붕소 트리플루오라이드-아민 및 붕소 트리클로라이드-아민, 및 이들의 혼합물로 이루어진 그룹중에서 선택된 아민 촉매 경화제 약 1 내지 10중량부를 함유함을 특징으로 하는, 우수한 열안정성을 갖는 열경화성 수지 조성물.
  11. 제10항에 있어서, 아민 촉매 결화제가 에폭시수지 및 반응성 희석제 100중량부당 약 2 내지 약 6중량부인 열경화성 수지 조성물.
  12. 제10항에 있어서, 반응성 희석제가 비닐 톨루엔인 열경화성 수지 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890010696A 1988-07-29 1989-07-28 열안정성이 우수한 열경화성 수지 조성물 KR0143782B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US226,114 1988-07-29
US07/226,114 US4906711A (en) 1988-07-29 1988-07-29 Low viscosity epoxy resin compositions
US226114 1999-01-07

Publications (2)

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KR900001783A true KR900001783A (ko) 1990-02-27
KR0143782B1 KR0143782B1 (ko) 1998-07-15

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KR1019890010696A KR0143782B1 (ko) 1988-07-29 1989-07-28 열안정성이 우수한 열경화성 수지 조성물

Country Status (5)

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US (1) US4906711A (ko)
EP (1) EP0353103A3 (ko)
JP (1) JPH0286616A (ko)
KR (1) KR0143782B1 (ko)
CA (1) CA1333837C (ko)

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JPH04296316A (ja) * 1990-12-18 1992-10-20 General Electric Co <Ge> 耐熱性樹脂組成物、製品及び方法
DE19520854A1 (de) * 1995-06-08 1996-12-12 Hoechst Ag Selbstemulgierende wäßrige Epoxidharzdispersionen
ATE203553T1 (de) * 1996-03-22 2001-08-15 Vantico Ag Einkomponentenepoxidharz verarbeitungsmaterial
GB0212977D0 (en) 2002-06-06 2002-07-17 Vantico Ag Actinic radiation curable compositions and their use
US7013965B2 (en) * 2003-04-29 2006-03-21 General Electric Company Organic matrices containing nanomaterials to enhance bulk thermal conductivity
US8647548B1 (en) * 2012-08-31 2014-02-11 The Boeing Company Method and system to reduce porosity in composite structures
ITMI20121808A1 (it) 2012-10-24 2014-04-25 Versalis Spa Composizioni polimeriche concentrate di polimeri e/o copolimeri vinilaromatici
JP6131062B2 (ja) * 2013-02-05 2017-05-17 株式会社日本触媒 硬化性樹脂組成物、その硬化物及び光学材料
WO2015062660A1 (en) * 2013-10-31 2015-05-07 Abb Research Ltd. Composite high voltage insulation materials and methods for preparing the same
DE102015204885A1 (de) * 2015-03-18 2016-09-22 Siemens Aktiengesellschaft Isolationssystem, Verwendungen dazu, sowie elektrische Maschine

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US2939859A (en) * 1954-03-31 1960-06-07 Shell Oil Co Process for preparing resinified product from polyepoxy polyether and aromatic-substituted-alkene-1 and composition for production of said product
US3293322A (en) * 1963-04-09 1966-12-20 Koppers Co Inc Homogeneous copolymer of epoxy resin and vinyl aryl monomer, cured with a bf3-amine complex
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JPS57180623A (en) * 1981-04-30 1982-11-06 Japan Atom Energy Res Inst Self-curing modified epoxy resin composition and aqueous dispersion thereof
US4379908A (en) * 1982-03-05 1983-04-12 Shell Oil Company Rapid curing epoxy-unsaturated monomer compositions
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US4603182A (en) * 1984-10-05 1986-07-29 General Electric Company Low viscosity epoxy resin compositions

Also Published As

Publication number Publication date
CA1333837C (en) 1995-01-03
JPH0286616A (ja) 1990-03-27
EP0353103A2 (en) 1990-01-31
EP0353103A3 (en) 1990-10-03
US4906711A (en) 1990-03-06
KR0143782B1 (ko) 1998-07-15

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