KR950018260A - 에폭시 수지를 기제로 하는 조성물 - Google Patents

에폭시 수지를 기제로 하는 조성물 Download PDF

Info

Publication number
KR950018260A
KR950018260A KR1019940035805A KR19940035805A KR950018260A KR 950018260 A KR950018260 A KR 950018260A KR 1019940035805 A KR1019940035805 A KR 1019940035805A KR 19940035805 A KR19940035805 A KR 19940035805A KR 950018260 A KR950018260 A KR 950018260A
Authority
KR
South Korea
Prior art keywords
suspension
epoxy resin
cycloaliphatic
methane
bis
Prior art date
Application number
KR1019940035805A
Other languages
English (en)
Other versions
KR100360164B1 (ko
Inventor
제티아브디 프란스
Original Assignee
베르너 발테크
시바-가이기 아게
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 베르너 발테크, 시바-가이기 아게 filed Critical 베르너 발테크
Publication of KR950018260A publication Critical patent/KR950018260A/ko
Application granted granted Critical
Publication of KR100360164B1 publication Critical patent/KR100360164B1/ko

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • C08G59/5026Amines cycloaliphatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • C08G59/56Amines together with other curing agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02Polyalkylene oxides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L79/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
    • C08L79/02Polyamines
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Epoxy Resins (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

본 발명은 A) 에폭시 수지 및 여기에 현탁된, 에폭시 수지계와 반응하는 어떤 기도 함유하지 않는 강화제로 구성된 저장 안정성 현탁액, B) B1) 디시안디아미드, B2) 시클로지방족 폴리아민, 및 B3) 폴리옥시알킬렌 아민으로 구성된 경화제 혼합물 및, 임의성분으로서 C) 경화 촉진제, 표준 충전재, 강화제 또는 변성제를 포함하는 에폭시 수지 조성물에 관한 것이다. 이들 조성물은 캐스팅 수지, 라미네이팅 수지, 프리프레그 또는 접착제로서 특히 적합하다.

Description

에폭시 수지를 기제로 하는 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. A) 에폭시 수지 및 여기에 현탁된, 에폭시 수지계와 반응하는 어떤 기도 함유하지 않는 강화제로 구성된 저장 안정성 현탁액, B) B1) 디시안디아미드, B2) 시클로지방족 폴리아민, 및 B3) 폴리옥시알킬렌 아민으로 구성된 경화제 혼합물 및, 임의성분으로서 C) 경화 촉진제, 표준 충전재, 강화제 또는 변성제를 포함하는 에폭시 수지 조성물이 현탁액.
  2. 제1항에 있어서, 성분 A)의 에폭시 수지가 액체 또는 고체 폴리글리시딜 에테르 또는 폴리글리시딜 에스테르, 또는 시클로지방족 에폭시 수지인 현탁액.
  3. 제2항에 있어서, 폴리글리시딜 에테르가 비스페놀의 액체 또는 고체 디글리시딜에테르이거나 또는 폴리글리시딜 에스테르가 시클로지방족 또는 방향족 디카르복시산의 디글리시딜 에스테르인 현탁액.
  4. 제1항에 있어서, 성분 A)가 고체 강화제를 포함하는 현탁액.
  5. 제4항에 있어서, 고체 강화제가 코아/쉘 중합체인 현탁액.
  6. 제1항에 있어서, 성분 B2)로서 1,2-디아미노시클로헥산, 비스(4-아미노시클로헥실)메탄, 비스(4-아미노-3-메틸시클로헥실)메탄, 4-아미노시클로헥실-4'-아미노페닐메탄.
    으로 이루어진 군으로부터 선정된 시클로지방족 폴리아민 1이상을 포함하는 현탁액.
  7. 제6항에 있어서, 비스(4-아미노시클로헥실)메탄, 비스(4-아미노-3-메틸시클로헥실)-메탄 및으로 구성된 군으로부터 선정되는 시클로지방족 폴리아민 1이상을 포함하는 현탁액.
  8. 제1항에 있어서, 성분 B3)로서 폴리옥시프로필렌 아민 또는 폴리옥시에틸렌 아민, 또는 이 두가지 모두의 혼합물을 포함하는 현탁액.
  9. 제8항에 있어서, 하기식의 폴리옥시프로필렌 아민을 포함하는 현탁액 :
    상기식에서, n은 2내지 40의 정수이다.
  10. 캐스팅 수지, 라미네이팅 수지, 프리프레그 또는 접착제로서의 제1항에 정의된 현탁액의 용도.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940035805A 1993-12-21 1994-12-20 에폭시수지를기제로하는조성물 KR100360164B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH327893 1993-12-21
CH94-3/278 1993-12-21

Publications (2)

Publication Number Publication Date
KR950018260A true KR950018260A (ko) 1995-07-22
KR100360164B1 KR100360164B1 (ko) 2003-03-12

Family

ID=4252526

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019940035805A KR100360164B1 (ko) 1993-12-21 1994-12-20 에폭시수지를기제로하는조성물

Country Status (4)

Country Link
EP (1) EP0659833B1 (ko)
KR (1) KR100360164B1 (ko)
AT (1) ATE195544T1 (ko)
PL (1) PL178737B1 (ko)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5508373A (en) * 1994-08-04 1996-04-16 Henkel Corporation Curing agents for epoxy resins based on 1,2-diaminocyclohexane
EP0723982B1 (de) * 1995-01-26 1999-06-16 Ciba SC Holding AG Härtbares Epoxidharzgemisch
DE19605098A1 (de) * 1996-02-12 1997-08-14 Siemens Ag Temperaturhärtbare schwundarme Reaktionsharzsysteme mit Low-Streß-Verhalten
JP4568940B2 (ja) * 1999-04-13 2010-10-27 日立化成工業株式会社 封止用エポキシ樹脂組成物及び電子部品装置
ATE450575T1 (de) * 2005-07-15 2009-12-15 Huntsman Adv Mat Switzerland Gehärtete zusammensetzung
US8741426B2 (en) 2008-07-22 2014-06-03 Basf Se Blends comprising epoxy resins and mixtures of amines with guanidine derivatives
EP2307360B1 (de) 2008-07-22 2011-12-21 Basf Se Verfahren zur herstellung von formkörpern mit hilfe von mischungen von aminen mit guanidin-derivaten
EP2307358B1 (de) 2008-07-22 2011-12-21 Basf Se Mischungen von aminen mit guanidin-derivaten
US20110319564A1 (en) * 2010-06-24 2011-12-29 Larry Steven Corley Epoxy systems for composites
US20120328811A1 (en) * 2011-06-24 2012-12-27 Air Products And Chemicals, Inc. Epoxy Resin Compositions
CN102924871A (zh) * 2011-08-10 2013-02-13 上海立汰新模具材料有限公司 环氧树脂组合物
JP2016501928A (ja) * 2012-11-12 2016-01-21 ジーカ テクノロジー アクチェンゲゼルシャフト 耐衝突性2剤エポキシ接着剤用のアミン組成物
US9862798B2 (en) * 2013-09-30 2018-01-09 Evonik Degussa Gmbh Epoxy liquid curing agent compositions

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH481963A (de) * 1967-06-08 1969-11-30 Ciba Geigy Neue härtbare Mischungen aus Diepoxydverbindungen, disekundären Aminen sowie mindestens 3 Aminwasserstoffatome enthaltenden Polyaminen
CA1249691A (en) * 1984-07-18 1989-01-31 Janis Robins Fast curing epoxy resin compositions
KR100204325B1 (ko) * 1991-05-17 1999-06-15 월터클라웨인 한스-피터워트린 잠재적 경화제, 아민 및 디티올을 포함하는 경화성 에폭시 수지 조성물
AU3941593A (en) * 1992-04-15 1993-11-18 B.F. Goodrich Company, The Multilayer core-shell polymer compositions as toughener for thermosets and thermoplastics
ES2148213T3 (es) * 1992-07-09 2000-10-16 Vantico Ag Suspensiones endurecibles a base de resinas epoxi.

Also Published As

Publication number Publication date
EP0659833A1 (de) 1995-06-28
EP0659833B1 (de) 2000-08-16
PL306275A1 (en) 1995-06-26
PL178737B1 (pl) 2000-06-30
KR100360164B1 (ko) 2003-03-12
ATE195544T1 (de) 2000-09-15

Similar Documents

Publication Publication Date Title
KR900007950A (ko) 폴리옥시알킬렌디디올과 폴리아민을 함유하는 에폭시드 수지 재료의 경화성 혼합물
KR950018260A (ko) 에폭시 수지를 기제로 하는 조성물
US4593056A (en) Epoxy/aromatic amine resin systems containing aromatic trihydroxy compounds as cure accelerators
KR930021718A (ko) 불포화 폴리에스테르-에폭시 수지 망상 구조 조성물
KR910016853A (ko) 개질된 에폭시 수지
KR940002314A (ko) 에폭시 수지의 경화성 현탁액
US5302666A (en) Bisphenol A and novolak epoxy resins with nitrile rubber
US8859694B2 (en) Cure accelerators
KR960007637A (ko) 에폭시 수지 시스템
GB1567047A (en) Epoxy resin compositions
CA2223917A1 (en) Amine curable epoxy coating compositions having an improved adhesion to substrates
FI110112B (fi) Epoksidihartsikovetinaineiden varastointistabiilit suspensiot
JPH0195176A (ja) エポキシ接着剤
KR970705595A (ko) 프리프레그 및 복합 재료용 에폭시수지 혼합물(epoxy resin mixtures for prepregs and composites)
JPS5927916A (ja) エポキシ樹脂組成物およびエポキシ樹脂の加工性改善方法
KR920018181A (ko) 코팅 조성물
US4110313A (en) Epoxy curing agent
KR970042721A (ko) 만니히 염기 경화제
KR890011949A (ko) 에폭시 수지 조성물 및 이를 사용하는 복합재료용 프리프레그(prepreg)
JPS63186726A (ja) 常温速硬化型エポキシ樹脂組成物
EP0057325A1 (en) Epoxy-coating composition containing a hardener and an accelerator
JPH0912683A (ja) エポキシ樹脂組成物およびそのための硬化剤
EP0501916A2 (en) Creosote resistant epoxy adhesive system
ES2007540A6 (es) Procedimiento para la preparacion de productos reticulados de mezclas de productos endurecibles de resinas epoxi, conteniendo un tetraglicidileter de un compuesto tetrametilol.
EP0132853B1 (en) Preimpregnated reinforcements and high strength composites therefrom

Legal Events

Date Code Title Description
N231 Notification of change of applicant
A201 Request for examination
N231 Notification of change of applicant
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20110929

Year of fee payment: 10

LAPS Lapse due to unpaid annual fee