KR890700145A - 폴리우레탄(메타)아크릴레이트 혼합물, 수지조성물 및 피복제 - Google Patents

폴리우레탄(메타)아크릴레이트 혼합물, 수지조성물 및 피복제

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Publication number
KR890700145A
KR890700145A KR1019880700866A KR880700866A KR890700145A KR 890700145 A KR890700145 A KR 890700145A KR 1019880700866 A KR1019880700866 A KR 1019880700866A KR 880700866 A KR880700866 A KR 880700866A KR 890700145 A KR890700145 A KR 890700145A
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KR
South Korea
Prior art keywords
meth
acrylate
diisocyanate
resin composition
compound
Prior art date
Application number
KR1019880700866A
Other languages
English (en)
Inventor
가즈노리 사사하라
미노루 요꼬시마
Original Assignee
사까노 쓰네까즈
니뽕 가야꾸 가부시끼가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 사까노 쓰네까즈, 니뽕 가야꾸 가부시끼가이샤 filed Critical 사까노 쓰네까즈
Publication of KR890700145A publication Critical patent/KR890700145A/ko

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/06—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4266—Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from hydroxycarboxylic acids and/or lactones
    • C08G18/4269—Lactones
    • C08G18/4275—Valcrolactone and/or substituted valcrolactone
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/81—Unsaturated isocyanates or isothiocyanates
    • C08G18/8141—Unsaturated isocyanates or isothiocyanates masked
    • C08G18/815—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen
    • C08G18/8158—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen
    • C08G18/8175—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen with esters of acrylic or alkylacrylic acid having only one group containing active hydrogen

Abstract

내용 없음

Description

폴리우레탄(메타)아크릴레이트 혼합물, 수지조성물 및 피복제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (15)

  1. 폴리(β-메틸-δ-발레로락톤)디올, 유기 폴리이소시아네이트와 히드록시(메타)아크릴레이트 화합물의 반응 생성물인 폴리우레탄(메타)아크릴레이트 혼합물.
  2. 제1항에 있어서, 유기 폴리이소시아네이트가 이소포론디이소시아네이트, 헥사메틸렌디이소시아네이트, 2,2,4-트리메틸헥사메틸렌디이소시아네이트, 2,4,4-트리메틸헥사메틸렌디이소시아네이트, 톨일렌 디이소시아네이트, 크실렌디이소시아네이트, 디폐닐메탄-4,4'-디이소시아네이트, 리신 디이소시아네이트 또는 이합체산 디이소시아네이트로부터 선택되는 화합물인 것을 특징으로 하는 폴리우레탄(메타)아크릴레이트 혼합물.
  3. 제1항에 있어서, 히드록시(메타)아크릴레이트 화합물이 히드록시메틸(메타)아크릴레이트, 히드록시프로필(메타) 아크릴레이트 또는 ε-카프로락톤-β-히드록시에틸(메타)아크릴레이트 부가물로부터 선택되는 화합물인 것을 특징으로 하는 폴리우레탄(메타)아크릴레이트 혼합물.
  4. 제1항 제2항 또는 제3항에 있어서, 폴리(β-메틸-δ-발레로락톤)디올의 평균 분자량이 500 내지 5,000인 것을 특징으로 하는 폴리우레탄(메타)아크릴레이트 혼합물.
  5. 폴리(β-메틸-δ-발레로락톤)디올 (평균분자량 500 내지 5000), 유기 폴리이소시아네이트와 히드록시(메타)아크릴레이트 화합물의 반응 생성물인 폴리우레탄(메타)아크릴레이트 혼합물을 포함하는 것을 특징으로 하는 수지 조성물.
  6. 폴리(β-메틸-δ-발레로락톤)디올 (평균분자량 500 내지 5000), 유기폴리이소시아네이트와 히드록시(메타) 아크릴레이트 화합물의 반응 생성물인 폴리우레탄(메타)아크릴레이트 혼합물(A), (A)이외의 에틸렌성 불포화 화합물(B) 및 임의성분으로서 광중합 개시제(C)를 포함하는 것을 특징으로 하는 수지 조성물.
  7. 제6항에 있어서, 유기 폴리이소시아네이트가 이소포론디이소시아네이트, 헥사메틸렌디이소시아네이트, 2,2,4-트리메틸헥사메틸렌디이소시아네이트, 2,4,4-트리메틸헥사메틸렌디이소시아네이트, 톨일렌디이소시아네이트, 크실일렌디이소시아네산이트, 디페닐메탄, -4,4'-디이소시아네이트, 리신디이소시아네이트 또는 이합체산의 디이소시아네이트로부터 선택되는 화합물인 것을 특징으로 하는 수지 조성물.
  8. 제6항에 있어서, 히드록시(메타)아크릴레이트 화합물이 히드록시에틸(메타)아크릴레이트, 히드록시프로필(메타) 아크릴레이트 또는 ε-카프로락톤-β-히드록시 에틸(메타)아크릴레이트 부가물로부터 선택되는 화합물인 수지 조성물.
  9. 제6항에 있어서, (A)이외의 에틸렌성 불포화 화합물(B)이 에폭시(메타)아크릴레이트, 폴리카보네이트(메타) 아크릴레이트 페닐옥시(또는 알킬 페닐옥시) 폴리에톡시(메타)아크릴레이트, 페닐옥시(또는 알킬페닐옥시)폴리프로폭시(메타)아크릴레이트, 노닐페닐옥시폴리에톡시(메타)아크릴레이트, 페닐옥시(또는 알킬페닐옥시)에톡시(메타)아크릴레이트, 페닐옥시(또는 페닐옥시)프로폭시(메타) 아크릴레이트, 테트라히드로푸르푸릴알코올의 ε-카프로락톤 부가물의(메타) 아크릴레이트, ε-카프로락톤-β-히드록시에틸(메타)아크릴레이트 부가물, 및 노닐페놀의 폴리에톡시화합물 또는 폴리프로폭시화합물의 ε-카프로락톤 부가물의(메타) 아크릴레이트 혼합물(A)의 비율이 20 내지 80중량%이고 광중합개시제(C)의 비율이 0.1 내지 10중량%인 수지 조성물.
  10. 제6항, 제7항 제8 또는 제9항에 있어서, 수지 조성물중의 폴리우레탄(메타)아크릴레이트 혼합물(A)의 비율이 20 내지 80중량%이고, (A)이외의 에틸렌성 불포화합물(B)의 비율이 20 내지 80중량%이고, 광중합개시제(C)의 비율이 0.1 내지 10중량%인 수지 조성물.
  11. 제5항에 있어서, 광학 유리섬유 피복용의 수지 조성물.
  12. 제6항 또는 제7항에 있어서, 광학 유리섬유 피복용의 수지조성물.
  13. 제8항에 있어서, 광학 유리섬유 피복용의 수지 조성물.
  14. 제9항에 있어서, 광학 유리 섬유 피복용의 수지 조성물.
  15. 제10항에 있어서, 광학 유리섬유 피복용의 수지 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880700866A 1986-11-21 1987-11-20 폴리우레탄(메타)아크릴레이트 혼합물, 수지조성물 및 피복제 KR890700145A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US276445/86 1986-11-21
JP61276445A JPS63130611A (ja) 1986-11-21 1986-11-21 ポリウレタン（メタ）アクリレ−ト混合物，樹脂組成物及びコ−テイング剤
PCT/JP1987/000903 WO1988003934A1 (en) 1986-11-21 1987-11-20 Polyurethane (meth)acrylate mixture, resin composition, and coating agent

Publications (1)

Publication Number Publication Date
KR890700145A true KR890700145A (ko) 1989-03-10

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ID=17569526

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Application Number Title Priority Date Filing Date
KR1019880700866A KR890700145A (ko) 1986-11-21 1987-11-20 폴리우레탄(메타)아크릴레이트 혼합물, 수지조성물 및 피복제

Country Status (5)

Country Link
EP (1) EP0290623A4 (ko)
JP (1) JPS63130611A (ko)
KR (1) KR890700145A (ko)
AU (1) AU600783B2 (ko)
WO (1) WO1988003934A1 (ko)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4027971A1 (de) * 1990-09-04 1992-03-05 Bayer Ag Acryloylgruppen enthaltende, aliphatische polyurethane, ein verfahren zu ihrer herstellung und ihre verwendung
EP0579503B1 (en) * 1992-07-17 1997-11-05 Ethicon Inc. Radiation-curable, urethane-acrylate prepolymers and crosslinked polymers
DE4302327A1 (de) * 1993-01-28 1994-08-04 Basf Lacke & Farben Strahlenhärtbare Oligomere sowie flüssige, strahlenhärtbare Überzugsmasse für die Beschichtung von Glasoberflächen
WO1996015179A2 (en) * 1994-11-04 1996-05-23 The Kerr Corporation Radiation curable molding compositions
CA2189836C (en) * 1995-12-04 2004-05-25 Angela S. Rosenberry Coating composition and floor covering including the composition

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3426875C2 (de) * 1983-07-21 1993-12-16 Kuraray Co Verfahren zur Herstellung von Polyurethanen mit überragender Hydrolysebeständigkeit
US4618632A (en) * 1985-02-07 1986-10-21 Westinghouse Electric Corp. UV curable high tensile strength resin composition

Also Published As

Publication number Publication date
WO1988003934A1 (en) 1988-06-02
AU8327287A (en) 1988-06-16
EP0290623A1 (en) 1988-11-17
JPS63130611A (ja) 1988-06-02
EP0290623A4 (en) 1989-07-11
AU600783B2 (en) 1990-08-23

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