KR890009997A - 함규소 폴리머의 제조방법 - Google Patents

함규소 폴리머의 제조방법 Download PDF

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Publication number
KR890009997A
KR890009997A KR1019880016657A KR880016657A KR890009997A KR 890009997 A KR890009997 A KR 890009997A KR 1019880016657 A KR1019880016657 A KR 1019880016657A KR 880016657 A KR880016657 A KR 880016657A KR 890009997 A KR890009997 A KR 890009997A
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South Korea
Prior art keywords
silicon
containing polymer
producing
compound
group
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KR1019880016657A
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English (en)
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KR920005671B1 (ko
Inventor
마사요시 이도오
가즈오 와끼무라
우찌료 다께
겐지 이와다
미네오 고바야시
다다시 아사누마
가쯔히꼬 야마노또
준꼬 오오나까
요시꼬 도꾸라
Original Assignee
사와무라 하루오
미쯔이도오아쯔 가가꾸 가부시기가이샤
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Priority claimed from JP63042361A external-priority patent/JPH01217018A/ja
Priority claimed from JP63045783A external-priority patent/JPH01221406A/ja
Application filed by 사와무라 하루오, 미쯔이도오아쯔 가가꾸 가부시기가이샤 filed Critical 사와무라 하루오
Publication of KR890009997A publication Critical patent/KR890009997A/ko
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Publication of KR920005671B1 publication Critical patent/KR920005671B1/ko

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F30/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F30/04Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
    • C08F30/08Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F230/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F230/04Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
    • C08F230/08Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/654Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14Monomers containing five or more carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F230/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F230/04Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
    • C08F230/08Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
    • C08F230/085Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon the monomer being a polymerisable silane, e.g. (meth)acryloyloxy trialkoxy silanes or vinyl trialkoxysilanes

Abstract

내용 없음

Description

함규소 폴리머의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 폴리비닐실란의 IR스팩트럼.
제2도는 동 폴리비닐 실란의 XRD 측정결과,
제3도는 폴리알릴실란의 IR스펙트럼.

Claims (3)

  1. 할록겐화 마그네슘을 함유한 조성물을 티탄화합물을 담지시킨것(A), 및 일반식 AlR′nX3-n(단 R1탄소수 1∼12의 알킬기, X는 할로겐원자, n은 1n3을 표시함.)로 표시되는 유기알루미늄 화합물(B)로 이루어진 촉매의 존재하에,
    일반식 CH2=CH-(R2)n-SiHm(R3 3-m)
    또는
    일반식 CH2=CH-(R2)n-SipH2p+1(단, n은 0 또는 1∼12, m은 1∼3, P1∼3, R2는 알킬렌기 또는 페닐렌기, R3은 메틸기, 페닐기, 염소원자를 표시함)로 표시되는 규소화합물을 중합시키는 것을 특징으로 하는 함규소폴리머의 제조방법.
  2. 제1항에 있어서, 기재된 촉매(A) 및 (B)를 사용해서, 제1항에 기재의 규소화합물과α-올레핀을 공중합시키는 것을 특징으로 하는 함규소 폴리머의 제조방법.
  3. 제1항에 있어서, 전자공여성화합물의 공중하에 행사는 함규소폴리머의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880016657A 1987-12-16 1988-12-14 함규소 폴리머의 제조방법 KR920005671B1 (ko)

Applications Claiming Priority (12)

Application Number Priority Date Filing Date Title
JP31602387 1987-12-16
JP316023 1987-12-16
JP22063 1988-02-03
JP2206388 1988-02-03
JP63-22063 1988-02-03
JP42361 1988-02-26
JP63042361A JPH01217018A (ja) 1988-02-26 1988-02-26 含ケイ素α−オレフィンの重合方法
JP63-42361 1988-02-26
JP63-45783 1988-03-01
JP63045783A JPH01221406A (ja) 1988-03-01 1988-03-01 含ケイ素ポリマーの製造方法
JP45783 1988-03-01
JP62-316023 1988-07-11

Publications (2)

Publication Number Publication Date
KR890009997A true KR890009997A (ko) 1989-08-05
KR920005671B1 KR920005671B1 (ko) 1992-07-13

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KR1019880016657A KR920005671B1 (ko) 1987-12-16 1988-12-14 함규소 폴리머의 제조방법

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EP (2) EP0585967B1 (ko)
KR (1) KR920005671B1 (ko)
CA (1) CA1308513C (ko)
DE (2) DE3853199T2 (ko)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5239030A (en) * 1987-05-08 1993-08-24 Aristech Chemical Corporation Amine/propylene copolymers
JP2974404B2 (ja) * 1989-12-28 1999-11-10 三井化学株式会社 新規な重合体およびそれを含むポリプロピレン樹脂組成物
WO1992005226A1 (en) * 1990-09-19 1992-04-02 Minnesota Mining And Manufacturing Company Moisture-curable polyolefin pressure-sensitive adhesives
JP2002503732A (ja) 1998-02-11 2002-02-05 ザ ダウ ケミカル カンパニー 改良されたオレフィン重合方法
US6624254B1 (en) 1999-01-21 2003-09-23 The Dow Chemical Company Silane functionalized olefin interpolymer derivatives
ATE328918T1 (de) * 1999-07-29 2006-06-15 Dow Global Technologies Inc Verbesserte silanefunktionelle olefin- interpolymere derivate
JP2005511799A (ja) * 2001-11-16 2005-04-28 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 改良されたオレフィン重合方法
US6936671B2 (en) * 2003-10-08 2005-08-30 Equistar Chemicals, Lp Process for copolymerizing ethylene with vinylsilanes
JP2023532870A (ja) 2020-06-24 2023-08-01 ダウ グローバル テクノロジーズ エルエルシー オレフィン/シランインターポリマーの硬化及び官能化

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL101938C (ko) * 1957-12-23
GB1415194A (en) * 1972-03-23 1975-11-26 Dow Corning Ltd Preparation of copolymers containing silicon
US3953414A (en) * 1972-09-13 1976-04-27 Montecatini Edison S.P.A., Catalysts for the polymerization of olefins to spherically shaped polymers
JPH0615644B2 (ja) * 1985-02-25 1994-03-02 三菱油化株式会社 シラン架橋性共重合体組成物
CA1278397C (en) * 1985-12-16 1990-12-27 Exxon Research And Engineering Company Olefinic chlorosilane and olefinic halide functional group containing polymers and method of forming the same
JPH0680101B2 (ja) * 1986-09-09 1994-10-12 三井東圧化学株式会社 プロピレンのブロツク共重合体の製造方法
WO1988005779A1 (en) 1987-01-28 1988-08-11 Mitsui Toatsu Chemicals, Inc. Processes for preparing organosilicon compounds and silicon carbide
JP2713585B2 (ja) * 1987-11-17 1998-02-16 三井東圧化学株式会社 新規なポリα−オレフィン樹脂組成物及びその用途

Also Published As

Publication number Publication date
EP0321259A3 (en) 1991-01-23
DE3855259T2 (de) 1996-12-12
DE3853199D1 (de) 1995-04-06
DE3853199T2 (de) 1995-09-28
KR920005671B1 (ko) 1992-07-13
EP0321259A2 (en) 1989-06-21
CA1308513C (en) 1992-10-06
EP0585967B1 (en) 1996-05-01
EP0321259B1 (en) 1995-03-01
EP0585967A1 (en) 1994-03-09
DE3855259D1 (de) 1996-06-05

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