KR890009602A - 층간하이브리즈 적층재 - Google Patents

층간하이브리즈 적층재 Download PDF

Info

Publication number
KR890009602A
KR890009602A KR1019880016114A KR880016114A KR890009602A KR 890009602 A KR890009602 A KR 890009602A KR 1019880016114 A KR1019880016114 A KR 1019880016114A KR 880016114 A KR880016114 A KR 880016114A KR 890009602 A KR890009602 A KR 890009602A
Authority
KR
South Korea
Prior art keywords
fibers
inorganic
interlayer
fiber
hybrid laminate
Prior art date
Application number
KR1019880016114A
Other languages
English (en)
Other versions
KR930009294B1 (ko
Inventor
야마모토 신지
타나카 히데호
사사끼 히로시게
타가 다케후미
미우라 타다시
니시무라 카주오
오쯔카 히토유키
Original Assignee
와수오 시미즈
우배고-상 가부시기 가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP62305593A external-priority patent/JPH01148547A/ja
Priority claimed from JP62305592A external-priority patent/JPH01148546A/ja
Priority claimed from JP62305591A external-priority patent/JPH01148545A/ja
Application filed by 와수오 시미즈, 우배고-상 가부시기 가이샤 filed Critical 와수오 시미즈
Publication of KR890009602A publication Critical patent/KR890009602A/ko
Application granted granted Critical
Publication of KR930009294B1 publication Critical patent/KR930009294B1/ko

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/28—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer impregnated with or embedded in a plastic substance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/08—Impregnating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/02—Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments
    • B32B17/04—Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments bonded with or embedded in a plastic substance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • B32B27/281—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polyimides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/38—Layered products comprising a layer of synthetic resin comprising epoxy resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/42—Layered products comprising a layer of synthetic resin comprising condensation resins of aldehydes, e.g. with phenols, ureas or melamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/022—Non-woven fabric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/024—Woven fabric
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/005—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
    • B32B9/007—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile comprising carbon, e.g. graphite, composite carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/047—Reinforcing macromolecular compounds with loose or coherent fibrous material with mixed fibrous material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/247—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using fibres of at least two types
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02—Composition of the impregnated, bonded or embedded layer
    • B32B2260/021—Fibrous or filamentary layer
    • B32B2260/023—Two or more layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04—Impregnation, embedding, or binder material
    • B32B2260/046—Synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/101—Glass fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/106—Carbon fibres, e.g. graphite fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/54—Yield strength; Tensile strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2398/00—Unspecified macromolecular compounds
    • B32B2398/10—Thermosetting resins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Reinforced Plastic Materials (AREA)
  • Laminated Bodies (AREA)

Abstract

내용 없음

Description

층간하이브리즈 적층재
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (22)

  1. 탄소섬유 및 Si, 또는 Ti 또는 Zr, C 및 0로 구성된 무기섬유에 각각 열경화성수지를 함침시켜 프레프레그를 형성하고 어프리프레그를 적층하므로서 제조되는 층간하이브리즈 적층재에 있어서, 상기 층간하이브리즈 적층재로 상기 탄소섬유의 인장탄성율대(對)상기 무기섬유의 인장탄성율의 비가 0.6-1.4범위인것을 특징으로 하는 층간하이브리즈 적층재(interply-hybridixed laninated material)
  2. 제1항에 있어서, 상기 탄소섬유가 탄소질섬유 또는 흑연질섬유 인것을 특징으로하는 층간하이브리즈 적층재.
  3. 제1항에 있어서, 상기 무기섬유가 일반식
    (단,식중의 R은 수소원자, 저급알킬기 또는 페닐기를 나타냄.) 으로 표시된 주쇄골격을 갖는 수평균분자량 약 200-10,000의 폴리카르보시란과 일반식 MX4(단,M은 Ti 또는 Zr를 나타내고 X는 1-20탄소원자를 갖는 알콕시기 페닐기 또는 아세틸아세톡시기를 나타냄)로 표시되는 유기금속화합물을 반응에 대한 불황성 분위기에서 가열반응시켜 얻는 유기금속화합물을 방사하고 방사된 섬유를 소성하므로서 제조되는 것을 특징으로 하는 층간하이브리즈 적충재.
  4. 제1항에 있어서,무기섬유가 30-60중량%의 Si, 0.5-35중량%의 Ti 또는 Zr, 25-40중량%의 C및 0.01-30%의 0로 이루어진 원소비율을 갖는 것을 특징으로 하는 층간하이브리즈 적층재.
  5. 제1항에 있어서 무기 섬유의 비율이 무기섬유와 탄소섬유의 전체부피에 대하여 1-80vol%인것을 특징으로 하는 층간하이브리즈 적층재.
  6. 제1항에 있어서 무기 섬유및 탄소섬유초부피비율이 적충재 전체부피에 대하여 30-80vol%인것을 특징으로 하는 층간하이브리즈 적층재.
  7. 제1항에 있어서 적충재가 탄소섬유 및 무기섬유에 열경화성 수지를 각각 함침시켜 조제된 프리프레그를 적층한 다음 열경화성성 수지를 경화시킴으로서 제조되는 것을 특징으로하는 층간하이브리즈 적층재.
  8. 탄소섬유 및 Si, Ti 또는 Zr, C및 0로 구성되는 무기섬유에 열경화성수지를 각각 함침시켜 프fl프레그를 조제하고 프리프레그를 적층하므로서 제조되는 증간 하이브리즈 적층재에 있어서, 프리프레그의 적층구성이 적층재의 중앙면에 대하여 대칭인 것을 특징으로 하는 층간하이브리즈 적층재.
  9. 제8항에 있어서, 탄소섬유가 탄소질섬유 또는 흑연질섬유인 것을 특징으로 하는 층간하이브리즈 적층재.
  10. 제8항에 있어서, 상기 무기섬유가 일반식
    (단,식중의 R은 수소원자, 저급알킬기 또는 페닐기를 나타냄.) 으로 표시된 주쇄골격을 갖는 수평균분자량 약 200-10,000의 폴리카르보시란과 일반식 MX4(단,M은 Ti 또는 Zr를 나타내고 X는 1-20탄소원자를 갖는 알콕시기 페닐기 또는 아세틸아세톡시기를 나타냄)로 표시되는 유기금속화합물을 반응에 대한 불황성 분위기에서 가열반응시켜 얻는 유기금속화합물을 방사하고 방사된 섬유를 소성하므로서 제조되는 것을 특징으로 하는 층간하이브리즈 적층재.
  11. 제8항에 있어서, 무기섬유가 Si:30-60중량%, Ti또는 Zr; 0.5-35중량%, C:25-40중량% 및 0 : 0.01-30중량%로 이루어진 원소비율을 갖는 것을 특징으로 하는 층간하이브리즈 적층재.
  12. 제8항에 있어서, 무기섬유의 비율이 무기섬유와 탄소섬유의 총부피에 대하여 1-80vol%인것을 특징으로 하는 층간하이브리즈 적층재.
  13. 제8항에 있어서 무기섬유와 탄소섬유의 총부피비가 적충재의 총부피에 대하여 30-80vol%인것을 특징으로 하는 층간하이브리즈 적층재.
  14. 제8항에 있어서, 적층재가 탄소섬유 및 무기섬유에 각각 열경화성 수지를 함침 시켜 조제된 프리프레그를 적층한 다음, 열경화성 수지를 경화시키는 것을 특징으로하는 층간하이브리즈 적층재.
  15. 제8항에 있어서, 적층된 프리프레그내의 섬유방향이 적층재의 중앙면에 대하여 대칭인 것을 특징으로 하는 층간하이브리즈 적층재.
  16. 탄소섬유와 Si, Ti 또는 Zr, C및 0로 구성되는 무기섬유에 열경화성수지를 각각 함침시켜 프리프레그를 형성하고 이 프리프레그를 적층하므로서 제조되는 층간하이브리즈 적층재에 있어서, 적층재의 최최부층 중의 한층은 탄소섬유 함유 프리프레그로구성되고 적층재의 최외부층중의 다른 층은 무기섬유함유 프리프레그로 구성됨을 특징으로하는 층간하이브리즈 적층재.
  17. 제16항에 있어서. 탄소섬유가 탄소질섬유 또는 흑연질섬유 인것을 특징으로 하는 층간하이브리즈 적층재.
  18. 제16항에 있어서, 무기섬유가 일반식
    (단,식중의 R은 수소원자, 저급알킬기 또는 페닐기를 나타냄.) 으로 표시된 주쇄골격을 갖는 수평균분자량 약 200-10,000의 폴리카르보시란과 일반식 MX4(단,M은 Ti 또는 Zr를 나타내고 X는 1-20탄소원자를 갖는 알콕시기 페닐기 또는 아세틸아세톡시기를 나타냄)로 표시되는 유기금속화합물을 반응에 대한 불황성 분위기에서 가열반응시켜 얻는 유기금속화합물을 방사하고 방사된 섬유를 소성하므로서 제조되는 것을 특징으로 하는 층간하이브리즈 적층재.
  19. 제16항에 있어서, 무기섬유가 Si:30-60중량%, Ti또는 Zr:0.5-35중량%, C:25-40중량%및 0 : 0.1-30중량%로 이루어진 원소비율을 갖는 것을 특징으로 하는 층간하이브리즈 적층재.
  20. 제16항에 있어서, 무기섬유의 비율이 무기섬유와 탄소섬유의 총부피에 대하여 1-80vol%인것을 특징으로 하는 층간하이브리즈 적층재.
  21. 제16항에 있어서, 무기섬유와 탄소섬유의 총부피가 적층재의 총부피에 대하여 30-80vol%인것을 특징으로 하는 층간하이브리즈 적층재.
  22. 제16항에 있어서, 적층재가 탄소섬유 및 무기섬유에 각각 열경화성 수지를 함침 시켜 조제된 프리프레그를 적층한 다음, 열경화성 수지를 경화시키는 것을 특징으로하는 층간하이브리즈 적층재.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880016114A 1987-12-04 1988-12-03 층간 하이브리드 적층재 KR930009294B1 (ko)

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
JP62305593A JPH01148547A (ja) 1987-12-04 1987-12-04 対称ハイブリッド積層材
JP305593/87 1987-12-04
JP305591/87 1987-12-04
JP305591 1987-12-04
JP305593 1987-12-04
JP62305592A JPH01148546A (ja) 1987-12-04 1987-12-04 繊維強化樹脂積層材
JP305592 1987-12-04
JP305592/87 1987-12-04
JP62305591A JPH01148545A (ja) 1987-12-04 1987-12-04 層間ハイブリッド積層材

Publications (2)

Publication Number Publication Date
KR890009602A true KR890009602A (ko) 1989-08-03
KR930009294B1 KR930009294B1 (ko) 1993-09-25

Family

ID=27338770

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019880016114A KR930009294B1 (ko) 1987-12-04 1988-12-03 층간 하이브리드 적층재

Country Status (2)

Country Link
EP (1) EP0319346A3 (ko)
KR (1) KR930009294B1 (ko)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115771313B (zh) * 2022-12-09 2023-06-13 东华大学 一种高阻燃低密度聚醚砜复合材料及其制备方法

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS627737A (ja) * 1985-07-03 1987-01-14 Ube Ind Ltd ハイブリツド繊維強化プラスチツク複合材料

Also Published As

Publication number Publication date
KR930009294B1 (ko) 1993-09-25
EP0319346A3 (en) 1990-05-30
EP0319346A2 (en) 1989-06-07

Similar Documents

Publication Publication Date Title
US8273448B2 (en) Reinforced silicone resin films
US20100136316A1 (en) Laminated composites and methods of making the same
JPH0344570B2 (ko)
EP3643492B1 (en) Laminates of polysilazane and carbon fiber reinforced polymer
KR20160079326A (ko) 유리섬유 강화 플라스틱 및 알루미늄을 포함한 하이브리드 복합재료 제조방법 및 하이브리드 복합재료
JP2503497B2 (ja) 黒鉛・繊維複合材料
Yi et al. Effect of interleaf sequence on impact damage and residual strength in a graphite/epoxy laminate
KR890009602A (ko) 층간하이브리즈 적층재
WO2018057055A1 (en) High heat composite compositions, articles, and uses thereof
JPS61110742A (ja) 無機繊維強化金属複合材料
KR900014475A (ko) 열성형 가능한 열가소성체/유리 편포 복합체의 용융함침 성형법
JP5654936B2 (ja) 透明複合体
JPS5889630A (ja) 繊維強化プラスチツク組成物
CN111344338B (zh) 预浸料、纤维强化复合材料及成形体
JPH0353334B2 (ko)
JPH01223158A (ja) 難燃性フェノール樹脂組成物
JPH07506082A (ja) ブラックガラスの製造方法
JPH0149301B2 (ko)
JPS63159439A (ja) ハイブリツド繊維強化複合体
JPH04187583A (ja) 耐酸化性炭素繊維強化炭素複合材とその製造方法
JPH06263537A (ja) 擬似一方向強化ｃ／ｃ複合材料及びその製造方法
JP6854028B1 (ja) プリプレグ及び不燃材料
GB833800A (en) Asbestos based silicone reinforced structures
JPH04222865A (ja) ガラス強化ポリ（アリーレンスルフィド）組成物
EP0524343A1 (en) Poly(arylene sulfide) resins reinforced with glass fibers

Legal Events

Date Code Title Description
A201 Request for examination
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
NORF Unpaid initial registration fee