KR890008080A - 2,2- 디플루오로시클로 프로필에탄 유도체, 그의 제조 방법 및 살충제로서의 용도 - Google Patents

2,2- 디플루오로시클로 프로필에탄 유도체, 그의 제조 방법 및 살충제로서의 용도 Download PDF

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KR890008080A
KR890008080A KR1019880015623A KR880015623A KR890008080A KR 890008080 A KR890008080 A KR 890008080A KR 1019880015623 A KR1019880015623 A KR 1019880015623A KR 880015623 A KR880015623 A KR 880015623A KR 890008080 A KR890008080 A KR 890008080A
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alkyl
halo
alkoxy
phenyl
cycloalkyl
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KR1019880015623A
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베그너 페터
욥핀 하르트무트
횜버거 귄터
쾬 아르님
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원본미기재
쉐링 악티엔게젤샤프트
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/608—Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a ring other than a six-membered aromatic ring in the acid moiety
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/62—Oxygen or sulfur atoms
    • C07D213/63—One oxygen atom
    • C07D213/64—One oxygen atom attached in position 2 or 6
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/22—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and doubly-bound oxygen atoms bound to the same carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/15—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen containing halogen
    • C07C53/23—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen containing halogen containing rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/38—Acyl halides
    • C07C53/46—Acyl halides containing halogen outside the carbonyl halide group
    • C07C53/50—Acyl halides containing halogen outside the carbonyl halide group of acids containing three or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
    • C07D277/02—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
    • C07D277/20—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D277/22—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D277/24—Radicals substituted by oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/16—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
    • C07D295/18—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms by radicals derived from carboxylic acids, or sulfur or nitrogen analogues thereof
    • C07D295/182—Radicals derived from carboxylic acids
    • C07D295/185—Radicals derived from carboxylic acids from aliphatic carboxylic acids

Abstract

내용 없음

Description

2,2-디플루오로시클로 프로필에탄 유도체, 그의 제조 방법 및 살충제로서의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. 하기 일반식(I)로 표시되는 2,2-디플루오로시클로프로필에탄 유도체.
    상기 식중, C1-4는 서로 동일하거나 또는 상이한 것으로서, 수소, C1-6-알킬 또는 할로겐이고 R7는 수소, 알칼리 금속 또는 2가 금속의 대응하는 등가물 C1-10-알킬, C2-20-알케닐, C2-20-알키닐, 할로-C1-10-알킬, C3-6-시클로알킬, C1-1-알킬-C3-6-시클로알킬, C3-6-시클로알킬-C1-6-알킬, 할로-C3-6-시클로알킬-C1-10-알킬, 데카리닐, 인다닐, 아다만틸, 아다만틸메닐, 디르루오로시클로프로필에틸카르로닐옥시-C1-10-알킬, 디플루오로시클로프로필에틸카를보닐옥시데킬린닐, 디플루오로시클로프로필카르보닐옥시-C1-3-알콕시-C1-3-알킬, 페닐-C1-6-알킬, 페닐-C2-6-알케닐, 할로벤질, C1-4-알킬벤질, C1-4-알콕시페닐-C1-6-알킬, 페녹시벤질,-시아노페녹시벤질,-C1-3-알킬페녹시벤질, 에톡시-(-트리플루오로메틸)벤질, 할로페닐(클로프로필)-C1-3-알킬, 할로페녹시-C1-6-알킬, 나프틸-C1-6-알킬, 메틸티아졸릴-C1-6-알킬, 트리스(디플루오로시클로프로필 메틸카르보닐옥시메틸)메틸, 트리(C4-9-시크로알킬)스타닐, 아릴(1개이상의 C1-20-알킬, 할로-C1-6-알킬, C1-10-알콕시, 할로-C1-6-알콕시, 페닐-C1-6-알킬, 페닐-C1-6-알콕시, C3-10-시클로알콕시, 할로-C3-10-시클로알콕시, C3-6-시클로알킬말콕시, 할로-C3-6-시클로알킬알콕시, C2-6-일케닐옥시, 할로-C2-6-알케닐옥시, C2-6-알키닐옥시, 할로-C2-6-알키닐옥시, 알킬술포닐옥시, 알킬페닐술포닐옥시, 할로알킬술포닐옥시, 페닐, 할로겐, 아미노, 시아노, 히드록시, 니트로, 아릴옥시, 헤테로아릴옥시, 하로아릴옥시, 아릴아미노, 할로아릴아미노, C1-6-알콕시카르보닐, C1-6-알콕시카르보닐메틸, 할로-C1-6-알콕시카르보닐, C1-2-알킬디옥시, C1-6-알킬티오, 할로-C3-6-시클로알킬알킬아미노, 할로-C3-6-시클로알킬알킬카르보닐옥시, C1-6-알킬아미노 또는 디-C1-6-알킬아미노에 의해 임의로 치환됨), 헤테로아릴(할로겐, C1-3-알킬 또는 할로-C1-3-알킬에 의해 임의로 치환됨), 또는 CONHR8기 (여기서, R8은수소, C1-6-알킬 또는 페닐)1개 이상의 C1-6-알킬, 할로-C1-6-알킬, C1-16-알콕시, 할로-C1-6-알콕시, 페닐-C1-6-알콕시, C3-10-시클로알콕시, 할로-C3-10-시클로알콕시, C3-6-시클로알킬콕시, 할로-C3-6-시클로알킬알콕시, C2-6-알케닐옥시, 할로-C2-6-알케닐옥시, C2-6-알키닐옥시, 할로-C2-6-알키닐옥시, 알킬술포닐옥시, 할로알킬술포닐옥시, 페닐, 할로겐, 아미노, 시아노, 히드록시, 니트로, 아릴옥시, 할로아릴옥시, 이릴아미노,할로아릴아미노, C1-6-알콕시카르보닐, 할로-C1-6-알콕시카르보닐, C1-2-알킬닐옥시, C1-6-알킬티오, 할로-C3-6-시클로알킬알킬아미노, C1-6-알킬아미노 또는 디-C1-6-알킬아미노에 의해 임의로 치환됨)임}이고, A는 카르보닐, 티오카르보닐, 또는 메틸렌이고, B는 산소, 황 또는 NR6[여기서, R6는 수소, C1-6-알킬 또는 C3-12-시클로알킬, 페닐 또는 CORw{여기서, R7은 C1-6-알킬, 할로-C1-6-알킬, 페닐)1개 이상의 C1-6-알킬, 할로 -C1-6-알킬, C1-16-알콕시, 할로-C1-6-알콕시, 페닐-C1-6-알콕시, C3-10-시클로알콕시, 할로-C3-10-시클로알킬알콕시, C3-6-시클로알킬콕시, 할로-C3-6-시클로알킬알콕시, C2-6-알케닐옥시, 할로-C2-6-알케닐옥시, C2-6-알키닐옥시, 할로-C2-6-알키닐옥시, 알킬술포닐옥시, 하로알킬술포닐옥시, 페닐, 할로겐, 아미노, 시아노, 히드록시, 니트로, 아릴옥시, 할로아릴옥시, 아릴아미노, 할로아릴아마노, C1-6-알콕시카르보닐, 할로-C1-6-알콕시크르보닐, C1-2-알킬디옥시, C1-6-알킬티오, 할로-C3-6-시클로알킬알킬아미노, C1-6-알킬아미노 또는 디-C1-6-알킬아미노에 의해 임의로 치환됨), C3-6-시크로알킬, C1-6-알킬아미노 또는 C3-6-알콕시임]}이다
  2. 제 1 항에 있어서, A가 카르보닐이고, B가 산소 또는 NH이고, R1-4가 수소이며 R5가 수소 또는 C1-20-알킬, C1-20-알케닐, C1-20-알키닐, m-페녹시벤질 또는 나프틸메틸인 2-2,2-디플루루오로시크로프로필에탄 유도체
  3. 일반식(I)의 화합물의 제조에 있어서 중간체로서 하기 일반식(II)로 표시되는 화합물
    상기 식중 R1-4는 제 1 항에서 정의한 바와 같고, X는 OH,CI 또는 Br이다
  4. 제 1 항 또는 2항의 화합물과 농학적으로 허용되는 희석제 또는 담체와의 혼합물로 되는 살충 및 진드기 구충 조성물
  5. 제 1 항 또는 2항의 화합물의 유효량을 곤충, 또는 진드기 또는 그의 소재지에 투여하는 것으로 되는 곤충 및 진드기 박멸 방법
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880015623A 1987-11-27 1988-11-26 2,2- 디플루오로시클로 프로필에탄 유도체, 그의 제조 방법 및 살충제로서의 용도 KR890008080A (ko)

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DEP3740840.2 1987-11-27
DE19873740840 DE3740840A1 (de) 1987-11-27 1987-11-27 2,2-difluorcyclopropylethanderivate, verfahren zu ihrer herstellung und ihre verwendung als schaedlingsbekaempfungsmittel

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KR890008080A true KR890008080A (ko) 1989-07-08

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PH26571A (en) 1992-08-19
FI90529B (fi) 1993-11-15
DK660788A (da) 1989-05-28
CN1033271A (zh) 1989-06-07
HU204398B (en) 1992-01-28
US4983630A (en) 1991-01-08
JPH02218A (ja) 1990-01-05
DE3869342D1 (de) 1992-04-23
AR247547A1 (es) 1995-01-31
FI885488A0 (fi) 1988-11-25
FI885488A (fi) 1989-05-28
DD283552A5 (de) 1990-10-17
IL88503A (en) 1994-01-25
ATE73758T1 (de) 1992-04-15
AU619509B2 (en) 1992-01-30
CA1316182C (en) 1993-04-13
BR8806217A (pt) 1989-08-15
FI90529C (fi) 1994-02-25
GR3004537T3 (ko) 1993-04-28
ZA888862B (en) 1989-08-30
US5089662A (en) 1992-02-18
HUT49450A (en) 1989-10-30
EP0318425A1 (de) 1989-05-31
DK660788D0 (da) 1988-11-25
ES2038337T3 (es) 1993-07-16
RU1833139C (ru) 1993-08-07
IL88503A0 (en) 1989-06-30
CN1021011C (zh) 1993-06-02
EP0318425B1 (de) 1992-03-18
JPH0468295B2 (ko) 1992-11-02
DE3740840A1 (de) 1989-06-08
AU2597688A (en) 1989-06-29

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