KR890003714A - 아릴렌디아미노 치환 트리아진 - Google Patents

아릴렌디아미노 치환 트리아진 Download PDF

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Publication number
KR890003714A
KR890003714A KR1019880010906A KR880010906A KR890003714A KR 890003714 A KR890003714 A KR 890003714A KR 1019880010906 A KR1019880010906 A KR 1019880010906A KR 880010906 A KR880010906 A KR 880010906A KR 890003714 A KR890003714 A KR 890003714A
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KR
South Korea
Prior art keywords
alkyl
triazine
rubber
phenylenediamino
trihydrohalide
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KR1019880010906A
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English (en)
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KR960009423B1 (en
Inventor
록우드 휠러 에드워드
허버트 바로우스 프랭클린
죤 프랭코 로버트
바토레위츠 와딤
앤게로 마제오 러셀
승 더블유. 홍
죠셉 코넬 로버트
Original Assignee
아이. 제이. 크라코워
유니로열 케미칼 컴페니 인코퍼레이티드
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Priority claimed from US07/090,298 external-priority patent/US4794135A/en
Priority claimed from US07/163,921 external-priority patent/US4946881A/en
Priority claimed from US07/163,924 external-priority patent/US4794134A/en
Application filed by 아이. 제이. 크라코워, 유니로열 케미칼 컴페니 인코퍼레이티드 filed Critical 아이. 제이. 크라코워
Publication of KR890003714A publication Critical patent/KR890003714A/ko
Application granted granted Critical
Publication of KR960009423B1 publication Critical patent/KR960009423B1/ko

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
    • C07D251/40—Nitrogen atoms
    • C07D251/54—Three nitrogen atoms
    • C07D251/70—Other substituted melamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C08K5/34922—Melamine; Derivatives thereof

Abstract

내용 없음

Description

아릴렌디아미노 치환 트리아진
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 하기 일반식의 화합물:
    (Ⅰ)
    여기서, R1, R2및 R3는 C3-C18 가지쇄 또는 직쇄 알킬, 또는 C3-C12시클로알킬 또는 하나 이상의 C1-C12알킬 그룹으로 치환된 C3-C12시클로알킬로부터 독립적으로 선택된다.
  2. 제1항에 있어서, R1, R2및 R3가 C3-C18가지쇄 알킬 라디칼로부터 선택된 동일 라디칼인 화합물.
  3. 제1항에 있어서, 알킬이 1,4-디메틸펜틸; 이소프로필; 시클로헥실, sec-부틸; 1,3-디메틸부틸; 1-메틸헥실; 2,4-디-t-부탈시클로헥실; 2-sec-부틸 시클로헥실; 및 1-메틸데실로 구성되어 있는 군으로 부터 선택된 화합물.
  4. N-알킬-p-페닐렌디아민을 용매내에서 트리-할로트리아진과 반응시켜, 2,4,6-트리스(N-알킬-p-페닐렌디아미노)-1,3,5-트리아진 트리히드로할라이드를 포함하는 반응혼합물을 형성하는 단계 및 상기 2,4,6-트리스(N-알킬-p-페닐렌디아미노)-1,3,5-트리아진 트리히드로할라이드를 염기로 중화하여 2,4,6-트리(N-알킬-p-페닐렌디아미노)-1,3,5-트리아진을 중화하는 단계로 구성되는, 제1항의 화합물의 제조방법.
  5. 제4항에 있어서, 하기 단계를 더 포함하는 제조방법.
    상기 반응혼합물로부터 상기 트리히드로할라이드를 여과하는 단계; 수성염기로의 상기 중화단계 이전에,수혼화성 용매내에서 상기 트리히드로할라이드를 슬러리화 하는 단계.
  6. 제4항에 있어서, 중화단계 후에, 상기 용매로부터 상기 트리아진을 결정화하는 단계를 더 포함하는 제조방법.
  7. 하기 (a) 및 (b)로 구성되는 내붕괴성 조성물. (a) 불포화 중합체; 및 (b) 0.1-10중량부의 하기구조식(Ⅰ) 화합물의 중합체:
    여기서, R1, R2및 R3는 C3-C18가지쇄 또는 직쇄 알킬, 또는 C3-C12시클로알킬 또는 하나 이상의 C1-C12알킬 그룹으로 치환된 C3-C12시클로알킬로부터 독립적으로 선택된다.
  8. 제7항에 있어서, 하기(C)를 더 포함하는 조성물. (C) 오존 붕궤에 대하여 상기 중합체를 보호하기에 충분한 양으로 상기 중합체에 첨합된 피라페닐렌디아민 오존균열방지제.
  9. 부분적으로 제7항의 내붕궤 조성물로 구성된 엘라스토머 본체의 내오존성 고무제품.
  10. 제9항에 있어서, 상기 제품이 타이어이고, 상기 엘라스토머 본체가, 천연고무, 폴리이소프렌, 폴리부타디엔, 스티렌, 부타디엔 고무, 에틸렌-프로필렌-디엔3원 공중합체, 부틸고무, 폴리클로로프렌, 아크릴로니트릴 부타디엔 고무 및 폴리부텐으로 구성되어 있는 군으로부터 선택된 하나 이상의 엘라스토머를 함유하는 고무제품.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR88010906A 1987-08-28 1988-08-27 Arylenediamine substituted triazines KR960009423B1 (en)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US090,298 1987-08-28
US07/090,298 US4794135A (en) 1987-08-28 1987-08-28 Arylenediamine substituted triazines
US07/163,921 US4946881A (en) 1987-08-28 1988-03-04 Tire sidewall
US163,924 1988-03-04
US163,921 1988-03-04
US07/163,924 US4794134A (en) 1987-08-28 1988-03-04 Ozone resistant elastomeric articles

Publications (2)

Publication Number Publication Date
KR890003714A true KR890003714A (ko) 1989-04-17
KR960009423B1 KR960009423B1 (en) 1996-07-19

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Application Number Title Priority Date Filing Date
KR88010906A KR960009423B1 (en) 1987-08-28 1988-08-27 Arylenediamine substituted triazines

Country Status (13)

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EP (1) EP0305190B1 (ko)
JP (1) JPH07116323B2 (ko)
KR (1) KR960009423B1 (ko)
CN (1) CN1036274C (ko)
AR (1) AR244214A1 (ko)
AU (1) AU613946B2 (ko)
BR (1) BR8804367A (ko)
CA (1) CA1340206C (ko)
DE (1) DE3888760T2 (ko)
DK (1) DK171765B1 (ko)
ES (1) ES2052734T3 (ko)
IL (1) IL87542A (ko)
MY (1) MY103550A (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5304475A (en) * 1991-09-12 1994-04-19 Miwon Co., Ltd. Method for production of L-phenylalanine by recombinant E. coli

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US4839188A (en) * 1988-05-27 1989-06-13 Uniroyal Chemical Company, Inc. Stabilized fat compositions
US4972010A (en) * 1988-09-21 1990-11-20 Uniroyal Chemical Company, Inc. Substituted triazines
US5723523A (en) * 1996-05-22 1998-03-03 Hankook Tire Mfg., Co., Ltd. Rubber composition for a radial tire having improved processability and adhesive strength
EP0818450B1 (de) * 1996-07-08 2003-01-15 Ciba SC Holding AG Triazinderivate als UV-Filter in Sonnenschutzmitteln
US6160043A (en) * 1997-06-05 2000-12-12 Lord Corporation Curable compositions having high amount of antiozonant and an article made therefrom
KR100875362B1 (ko) * 2002-02-05 2008-12-22 아스텔라스세이야쿠 가부시키가이샤 2,4,6-트리아미노-1,3,5-트리아진 유도체
WO2006060896A1 (en) * 2004-12-08 2006-06-15 Lanxess Inc. Peroxide vulcanizable butyl compositions useful for rubber articles
DE102007057133A1 (de) 2007-11-28 2009-06-04 Robert Bosch Gmbh Wischgummi für Scheibenwischer
JP5524949B2 (ja) * 2008-03-31 2014-06-18 コンパニー ゼネラール デ エタブリッスマン ミシュラン 耐オゾン性が増強されたタイヤ
US20100010122A1 (en) * 2008-07-10 2010-01-14 Steiber Joseph F Substituted triazine compositions and methods for producing same
KR101404387B1 (ko) * 2012-07-26 2014-06-11 주식회사 한화 보강 충진제를 포함하는 내열재용 고무 조성물
US20160160079A1 (en) * 2013-07-31 2016-06-09 Nissan Chemical Industries, Ltd. Carbon material dispersed film formation composition
CN106032418A (zh) * 2015-02-25 2016-10-19 赛轮金宇集团股份有限公司 一种非污染橡胶
CN108203414A (zh) * 2016-12-20 2018-06-26 圣奥化学科技有限公司 三嗪衍生物的制备方法
CN112759557B (zh) * 2019-11-04 2023-12-29 圣奥化学科技有限公司 具有抗老化和耐变色功效的化合物及其制备方法
CN114105895A (zh) * 2020-08-28 2022-03-01 圣奥化学科技有限公司 新型对苯二胺类化合物、其制备方法及应用
CN112300440B (zh) * 2020-11-17 2021-11-02 圣奥化学科技有限公司 防老剂组合物、防老剂母胶及橡胶组合物
CN113683578B (zh) * 2021-09-03 2022-12-09 山东阳谷华泰化工股份有限公司 2,4,6-三（n-1,4-二甲基戊基对苯二胺基）-1,3,5-三嗪的制备方法

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BE793389A (fr) * 1971-12-27 1973-06-27 Degussa Composes de phenylenediamine-s-triazine et leur utilisation
DE3206398A1 (de) * 1982-02-23 1983-09-01 Basf Ag, 6700 Ludwigshafen S-triazinderivate und ihre verwendung als lichtschutzmittel
JPS60186549A (ja) * 1984-03-06 1985-09-24 Kawaguchi Kagaku Kogyo Kk ゴム用老化防止剤及びその製造法
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US4839188A (en) * 1988-05-27 1989-06-13 Uniroyal Chemical Company, Inc. Stabilized fat compositions
US4972010A (en) * 1988-09-21 1990-11-20 Uniroyal Chemical Company, Inc. Substituted triazines

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5304475A (en) * 1991-09-12 1994-04-19 Miwon Co., Ltd. Method for production of L-phenylalanine by recombinant E. coli

Also Published As

Publication number Publication date
BR8804367A (pt) 1989-03-21
IL87542A (en) 1993-01-31
CN1036274C (zh) 1997-10-29
DE3888760T2 (de) 1994-07-28
EP0305190A3 (en) 1991-01-09
AU2156088A (en) 1989-03-02
AR244214A1 (es) 1993-10-29
CA1340206C (en) 1998-12-15
DK477588D0 (da) 1988-08-26
AU613946B2 (en) 1991-08-15
DE3888760D1 (de) 1994-05-05
JPH01104058A (ja) 1989-04-21
DK477588A (da) 1989-03-01
DK171765B1 (da) 1997-05-12
ES2052734T3 (es) 1994-07-16
CN1050871A (zh) 1991-04-24
EP0305190B1 (en) 1994-03-30
MY103550A (en) 1993-07-31
EP0305190A2 (en) 1989-03-01
IL87542A0 (en) 1989-01-31
KR960009423B1 (en) 1996-07-19
JPH07116323B2 (ja) 1995-12-13

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