KR890003612B1 - Process for making cigarettes - Google Patents

Process for making cigarettes Download PDF

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KR890003612B1
KR890003612B1 KR1019880002068A KR880002068A KR890003612B1 KR 890003612 B1 KR890003612 B1 KR 890003612B1 KR 1019880002068 A KR1019880002068 A KR 1019880002068A KR 880002068 A KR880002068 A KR 880002068A KR 890003612 B1 KR890003612 B1 KR 890003612B1
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South Korea
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tobacco
herbal medicine
extract
citrus
leaf
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KR1019880002068A
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Korean (ko)
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KR890012577A (en
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유광근
박은수
최영현
이규서
김정렬
김시동
안기영
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한국전매공사
홍두표
한국인삼연초 연구소
이종화
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    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/002Cigars; Cigarettes with additives, e.g. for flavouring
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/18Selection of materials, other than tobacco, suitable for smoking

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  • Medicines Containing Plant Substances (AREA)
  • Manufacture Of Tobacco Products (AREA)
  • Medicinal Preparation (AREA)
  • Paper (AREA)

Abstract

The cigarette having a antitussive and expetorant effects is produced in 2 steps by blending one or more of herbicidal medicine to Maryland tobacco crude leaf. (a) 30 Kg Scopoliae Rhizoma contg. 0.253% atropine and 70kg stem of tobacco are shredded, extracted in hot water and vacuum-concentrated to give extracts (I). (I), binder and moisture absorbing agent are added to a paper made of cellulose residue of (I) to give herbicidal-medicine-contg. paper (II). (b) 85kg shredded Maryland tobacco is blended with 15kg shredded paper (II) followed by adding 1.5kg glycerine and 1.5kg propylene glycol to give the cigarette.

Description

권련 제조방법Citrus Making Method

본 발명은 황색종 잎담배에 진해 거담 효과가 있는 한방 생약재를 일종 또는 2종 아상 배합하여서된 건강, 약용 권련 담배 및 그 제조방법에 관한 것이다.The present invention relates to a health, medicinal tobacco cigarettes, and a method for producing the same, comprising two or two kinds of herbal medicines having an antitussive expectorant effect on yellow leaf tobacco.

쑥과 같은 한방 생약재를 첨가한 담배는 종래부터 연구되어 왔으나, 안전성, 약리효과, 경제성, 담배맛과의 친화성등의 문제성이 있어서, 완전한 개발이 이루어지지 않았었다.Tobacco added with herbal herbs such as mugwort has been studied conventionally, but there are problems such as safety, pharmacological effects, economics, and affinity with tobacco taste, so that no complete development has been made.

본 발명은 한방 생약재를 담배에 첨가하였을때 나타나는 약리 효과와 향끽미의 변화등을 연구한 결과 한방생약재인 낭탕, 다투라, 창포, 마황, 철명정, 원지, 길경, 오미자등의 한방 생약재는 적당량 담배에 혼합하면 담배의 향끽미를 저하시키지 않으면서도 전기한 생약재 특유의 약리 효과인 진해 거담 효과를 얻을 수 있음을 알게되어 본 발명을 완성하게 된 것이다.The present invention is a study of the pharmacological effects and flavor changes that occur when adding herbal medicines to tobacco, herbal medicines such as Nantang, tatura, irises, ephedra, Cheolmyeongjeong, Jiji, Gilgyeong, Schisandra chinensis, etc. The present invention has been accomplished by mixing the tobacco with an antitussive expectorant effect, which is a pharmacological effect peculiar to the herbal medicine described above, without lowering the taste of tobacco.

동의보감, 중약 대사전등의 한의학 약전에 의하면 진해 거담 효과가 있는 생약재가 수십종이 있는바, 이들생약재 중에서 전술한 생약재를 선택한 것은 수집의 용이성, 담배맛과의 친화성등을 고려할때 전술한 생약재들이 담배의 첨가물로서 가장 적당한 것으로 판단되어 선택하게 된 것이다.According to the herbal medicine pharmacy, such as consent agreement and Chinese medicine metabolism, there are dozens of herbal medicines with antitussive expectorant effect. Among these herbal medicines, the above-mentioned herbal medicines were selected by considering the ease of collection and affinity with tobacco taste. It was decided that it is the most suitable as an additive of and selected.

본 발명에 의한 담배는 생약재의 엑기스를 추출하여 잎담배 원료에 직접 배합하거나 또는 판상엽에 첨가하고 절각하여 잎담배 원료에 배합하는 방법으로 제조하든가 또는 생약재가 잎인 경우에 세편으로 절단하여 이를 잎담배 원료에 배합하는 방법등으로 제조할 수 있다.Tobacco according to the present invention is prepared by extracting the extract of the herbal medicine directly to the leaf tobacco raw material or by adding to the leaf leaf and blended to the leaf tobacco raw material or cut into three pieces when the herbal medicine is a leaf and mix it into the leaf tobacco raw material It can manufacture by the method.

생약재를 추출하여 그 엑기스를 이용하는 경우에는 온수나 증기로 추출하는 것이 좋다. 판상엽 제조방법은 공지의 판상엽 제조방법인 제지식과 압연식을 이용하는바, 일종 이상의 생약재를 사용하는 경우에는 각개 생약재를 별도로 추출하여 엑기스를 얻고 이를 판상엽 제조공정중의 적당한 단계에서 판상엽에 첨가할 수도 있고 사용할 2종 이상의 생약재를 함께 추출하여 혼합 엑기스를 판상엽에 첨가할 수도 있다.If you use the extract to extract the herbal medicine is good to extract with hot water or steam. The platelet manufacturing method uses papermaking and rolling formulas, which are known methods for producing platelets, and when using one or more types of herbal medicines, extract each herbal medicine separately to obtain an extract, and then at the appropriate stage in the platelet manufacturing process. The mixed extract may be added to the leaflets by extracting two or more kinds of herbal medicines to be used together.

또한, 필요에 따라서는 각개 생약재의 엑기스를 추출하고 각개 생약재 엑기스가 함유된 판상엽을 만든다음 이를 절각하여 적당한 비율로 잎담배 원료와 배함하므로서 2종 이상의 생약재 엑기스를 함유하는 담배를 만들수도 있다.In addition, if necessary extract the extract of each herbal medicine and make a leaflet containing each herbal medicine extract and then cut it and fermented with leaf tobacco raw materials in an appropriate ratio, it is possible to make a cigarette containing two or more herbal medicine extracts.

제지식 판상엽 제조방법의 일예를 설명하면 생약재를 추출하고 추출액을 감압 농축하여 엑기스를 얻고 별도로 담배 부산물인 중골, 니분등을 추출하여 엑기스를 얻은 다음 생약재 추출 잔류물과 담배 추출 잔류물로부터 연소 장애를 일으키는 단단한 물질을 제거하고 섬유물질을 고해한후 공지의 제지방법을 이용하여 종이형태로 만든다음 건조시키고 생약재 추출 엑기스와 담배 추출 엑기스를 보습제, 점착제, 가향제등 판상엽 첨가제와 함께 건조된 종이 상태의 제품에 첨가하여 건조시킨다.An example of the manufacturing method of the papermaking leaflets is to extract the herbal medicine, concentrate the extract under reduced pressure to obtain an extract, and extract the extract from the bones, nibs, etc., which are by-products of tobacco, and obtain the extract, After removing the hard substance that causes the chemicals and beating the fiber material, make it into a paper form using a known papermaking method, and then dry it. Then, dry the herbal medicine extract extract and tobacco extract extract with dried leaflet additives such as moisturizer, adhesive, and flavoring agent. It is added to the state product and dried.

제지식으로 제조된 판상엽의 물성은 펴형 수분이 12.0-13.0% 비중이 0.5-0.6g/cc, 연소성이 4분-6분(3cm), 부스럼지수(F.I) 3.50-3.70, 부풀성 4.5-5.6cc/g정도로 나타났다.The physical properties of the plate-shaped leaf produced by the paper-making formula are 12.0-13.0% of the flat moisture, 0.5-0.6g / cc specific gravity, 4 minutes-6 minutes (3cm), swell index (FI) 3.50-3.70, swellability 4.5- It was found to be about 5.6cc / g.

압연식 판상엽 제조방법은 판상엽 제조원료인 중골, 니분등을 분쇄하고 별도로 생약재를 분쇄하여 혼합한 다음 점착제, 보습제, 가향제등 판상엽 첨가제를 가하여 혼날하고 로울러 사이를 통과시켜 판상으로 압연한 다음 건조시킨다.Rolled leaf plate manufacturing method is to crush the raw material of bone plate, nibble, etc., and then crush and mix the herbal medicines separately, add flakes additives such as adhesive, moisturizer, flavoring agent, etc. Then dry.

압연식 방법으로 제조된 판산엽은 평형수분 11.0-13.0%, 비중 0.75-0.95g/cc, 연소성 7분-9분,부스럼지수(F.I) 3.30-3.60, 부풀성 3.3-3.7cc/g으로 나타났다.The leaflets produced by the rolling method showed equilibrium moisture 11.0-13.0%, specific gravity 0.75-0.95 g / cc, combustibility 7 minutes-9 minutes, swell index (FI) 3.30-3.60, bulging 3.3-3.7cc / g .

본 발명에 있어서 담배원료에 대한 생약재의 배합량은 생약재의 종류에 따라 아트로핀 함량과 생약재의 향취등을 고려하여 결정하는바, 예를들면 생약재를 전체 담배중량의 30%이하로 하고 담배원료인 각초를 전체 담배중량의 70% 이상으로 되게 하는 것이 좋다. 특히 생약재의 엑기스를 포함하는 판상엽을 제지식으로 제조하여 각초에 배합하는 경우에는 판상엽 원료인 담배 부산물과 생약재를 별도로 추출하여 엑기스를 얻고 이를 추출 잔류물인 섬유소에 첨가하여 판상엽을 제조한바, 판상엽 제조시에은 생약재를 판상엽 원료인 담배부산물과 동량으로 사용하거나 담배 부산물을 생약재보다 다량 사용하는 것이 바람직하다. 또한 압연식으로 판상엽을 제조하는 경우에도 생약재를 담배 부산물과 동량으로 사용하거나 담배 부산물을 생약재보다 다량 사용하는 것이 좋다. 그러나 판상엽 제조시의 생약재와 담배 부산물의 배합비율로 제조된 판상엽을 담배원료인 각초에 배합하는 비율과 사용하는 생약재의 향취 및 제조되는 담배의 향끽미에 의하여 결정되므로 그 배합비율은 변경될 수도 있다.In the present invention, the blending amount of the herbal medicine to the tobacco raw material is determined in consideration of the atropine content and the odor of the herbal medicine according to the type of herbal medicine, for example, the herbal medicine is less than 30% of the total tobacco weight and the tobacco is a tobacco raw material It is good to make it at least 70% of the total cigarette weight. In particular, when the leaflets containing the extract of the herbal medicines are manufactured in papermaking and blended into the herbaceous plants, extracts are obtained by extracting tobacco by-products and herbal medicines, which are the raw materials of the leaflets, and added to the cellulose, which is the residue of the extraction. In the manufacture of platelets, it is preferable to use the same amount of herbal medicines as tobacco by-products, which are raw materials of leaflets, or to use tobacco by-products in large amounts. In addition, in the case of producing a plate-like leaf by rolling, it is better to use the same amount of herbal medicines as tobacco by-products or to use tobacco by-products in large amounts. However, the mixing ratio of the herbal medicine and tobacco by-products in the manufacture of the leaflets is determined by the ratio of blending the leaflets to tobacco, raw tobacco, the flavor of the herbal medicines used, and the flavor of the tobacco produced. have.

본 발명에 사용되는 생약재들은 모두 검담 효과를 나타내는 물질인 아트로핀을 함유하고 있는바, 흡연시 담배에 함유된 아트로핀중 2-3%가 연기와 함께 이행되어 거담 효과를 나타내게 되는 것이다. 더구나 본 발명에 의한 생약 성분 함유 담배는 타르에 의한 돌연변이 유발성을 감소시키는 부수적인 효과도 가져온다. 연한 오미자를 첨가한 본 발명의 담배는 담배특유의 향끽미에 오미자 향취가 가미되고 여기에 의한 자극성이 감소된다.The herbal medicines used in the present invention all contain atropine, which is a substance that exhibits an anti-gum effect. When smoking, 2-3% of the atropine contained in cigarettes is transferred with smoke to have an expectorant effect. Furthermore, the herbal ingredient-containing tobacco according to the present invention also has a side effect of reducing the mutagenicity by tar. Cigarette of the present invention to which the soft schizandra is added has a schizandra flavor to the tobacco-flavored flavor and the irritation caused by this is reduced.

본 발명에 의한 담배를 흡연하면 연기중에 의행된 생약재의 거담성분인 아트로핀에 의하여 만성 기관지염의 치료효과를 얻을 수 있을 뿐 아니라 흡연에 의하여 나타나는 가래, 기침등을 예방할 수 있는 효과를 갖는다.Smoking cigarettes according to the present invention can not only obtain a therapeutic effect of chronic bronchitis by atropine, an expectorant component of the herbal medicine carried out in the smoke, but also have an effect of preventing phlegm, cough, etc., which are caused by smoking.

[실시예 1]Example 1

제지식 판상엽 제조방법Manufacturing Method of Paper Plate

아트로핀 함량 0.253%의 낭탕 30kg을 절단하고 온수로 추출하여 압착 여과한 다음 추출액을 감압 농축한다. 별도로 70kg의 담배 중골과 니분을 절단하고 온수로 추출하여 압착 여과한다음 감압 농축한다. 낭탕과 담배 부산물의 추출 잔류물에서 연소에 지장을 주는 괴상물들을 골라 낸후 나머지 섬유 물질들을 물에 분산시켜 공지의 제지방법으로 판상으로 만들고 낭탕 추출물과 담배 원료 추출물을 점착제, 보습제등의 첨가물을 가하여 판상엽을 만든다.30 kg of Nantang with an atropine content of 0.253% is cut out, extracted with hot water, filtered under reduced pressure, and the extract is concentrated under reduced pressure. Separately, cut 70 kg of tobacco bones and nibs, extract with hot water, filter under pressure, and concentrate under reduced pressure. From the extraction residue of Nantang and tobacco by-products, the masses that interfere with combustion are picked out, and the remaining fiber materials are dispersed in water to form a plate by a known papermaking method. The Nantang extract and tobacco raw material extract are added with adhesives, moisturizers, etc. Make platelets.

제조된 판상엽의 아트로핀 함량은 0.084%였다. 낭탕이 배합된 판상엽의 물성은 표 1에 기재한다.The atropine content of the prepared leaflets was 0.084%. Table 1 shows the physical properties of the leaflets incorporating cysts.

[실시예 2]Example 2

권련제조Manufacture

정선된 황색종 담배의 각초 85kg에 제조된 낭탕근 판상엽 각초 15kg을 배합하고 과포화상태의 증기에 순환시켜 수분 17±1%로 균일하게 유지되도록 조화시킨다음 보습제인 글리세린과 플로피렌 글리콜을 각각 1.5kg가하여 품온 30℃정도로 되도록 유지 조화시키고 수분 19-21%로 조정한 다음 0.9mm의 각초로 절각하고 수분 13-14%가 되도록 냉각한후 필요에 따라 가향제를 가하고 수분 12-13%로 유지하여 권련을 제조한다.Mix 15kg of glutinous foliar leaf vinegar prepared in 85kg of selected yellow tobacco cigarettes and circulate in supersaturated steam to maintain uniformity of 17 ± 1% of moisture. kg to keep the water temperature around 30 ℃, adjust to 19-21% of water, cut into 0.9mm of kerosene, cool to 13-14% of water, add fragrance if necessary, and keep at 12-13% of water To prepare a gin.

[실시예 3-5]Example 3-5

실시예 1의 제지식 방법으로 판상엽을 제조하되 낭탕근 대신 생약재로서 진피, 오미자, 창포를 사용한다. 대조용으로 한약재가 함유되지 아니한 판상엽을 제조하고 제조된 판상엽의 물성을 다음의 표 1에 기재한다To prepare a platelet by the papermaking method of Example 1 but using dermis, Schizandra, irises as a herbal medicine instead of gluttony root. Prepare a leaflet free of herbal medicine as a control and the physical properties of the produced leaflet are listed in Table 1 below.

[표 1]TABLE 1

Figure kpo00001
Figure kpo00001

[실시예 6]Example 6

실시예 2의 방법으로 권련을 제조하되 판상엽과 잎담배의 배합물에 감초 엑기스 분말인 리코리스 300g과 진피유 50g을 분무 첨가하여 권련을 제조한다.To prepare a citrus by the method of Example 2, a liquor is prepared by spraying 300 g of licorice and 50 g of dermis oil into a combination of leaf and leaf tobacco.

제조된 권련의 연기중에는 0.00028%의 아트로핀이 함유되어 있어서 아트로핀의 연중 이행율이 2.83%였다.In the smoke of the manufactured cistern, 0.00028% of atropine was contained, and the yearly transition rate of atropine was 2.83%.

[실시예 7]Example 7

압연식 판상엽의 제조Preparation of Rolled Leaflets

중골, 설엽, 니분등의 연초 부산물 70kg과 마황 30kg을 분쇄하고 혼합한 다음 점착제 3kg, 구연산 2kg, 질산칼륨 50g, 리코리스 200g, 글리세린 200g을 첨가하고 물로 반죽하여 로울러 사이에서 혼날하고 판상으로 압연하여 판상엽을 제조한다. 제조된 판상엽의 물성은 표 2에 기재한다.Grind and mix 70 kg of tobacco by-products such as golgol, snow leaf, and nibun and 30 kg of ephedra, mix, and then add 3 kg of adhesive, 2 kg of citric acid, 50 g of potassium nitrate, 200 g of licorice, 200 g of glycerin, knead with water, roll between plates and roll into plates. Prepare platelets. Physical properties of the prepared leaflets are shown in Table 2.

[실시예 8-12]Example 8-12

실시예 7의 방법으로 판상엽을 제조하되 낭탕대신 생약재로서 낭탕, 진파, 창포, 오미자를 사용한다.To prepare a platelet by the method of Example 7, but instead of using the Nantang, Nantang, Jinpa, Iris, Schizandra chinensis.

제조된 판상엽과 생약재가 함유되지 아니한 대조용 판상엽의 물성을 표 2에 기재한다.The physical properties of the prepared leaflets and the control leaflets not containing the herbal medicine are listed in Table 2.

[표 2]TABLE 2

Figure kpo00002
Figure kpo00002

[실시예 13]Example 13

실시예 6의 방법으로 권련을 제조하되, 실시예 7 내지 12에서 제조된 판상엽을 사용하여 권련을 제조한다.A citrus was prepared by the method of Example 6, but a citrus was prepared using the platelets prepared in Examples 7 to 12.

제조된 권련과 대조용 시판 솔담재의 연기중 화합성분을 표 3에 기재한다.Table 3 lists the chemical compounds in the smokes of the prepared scouring and control soldamjae.

[표 3]TABLE 3

연기중 화학성분Chemical composition in smoke

Figure kpo00003
Figure kpo00003

[실시예 14]Example 14

낭탕근을 온수로 추출하고 추출액을 담배의 각초에 분무 처리하여 권련을 제조한다.The lotus root is extracted with hot water, and the extract is sprayed on the vinegar of tobacco to prepare a citrus.

[실시예 15]Example 15

건조시킨 창포를 세절하여 담배 각초에 1 : 7의 비율로 배합하여 권련을 제조한다.The dried irises are cut into small pieces and mixed with tobacco vinegar in a ratio of 1: 7 to prepare a citrus.

[실시예 16]Example 16

안정성 실험(Ames Test)Ames Test

본 발명에 사용되는 약초의 흡연 안정성을 실험하기 위하여, 길경, 청폐탕, 원지, 오미자의 추출물을 각초에 처리하여 권련을 만들고 또한 오미자, 마황, 낭탕, 창포 판산엽을 만들어서 돌연변이 유발성 실험을 하였다. 안정성 실험은 캠브릿지 필터로 포집한 탈 500㎍에서의 돌연변이 유발성을 살모넬라 티피무리움 TA98균주를 이용하여 측정하였다. 대조용으로 시판 솔담배에 대하여 동일한 실험을 하였다. 시험결과를 표 4에서 기재한다.In order to test the smoking stability of the medicinal herb used in the present invention, the extracts of Gilkyung, Cheonghaetang, Wonji, and Schisandra chinensis were treated with citrus herb to make a citrus, and also a Schizandra chinensis, ephedra, Nantang, iris foliate leaves were mutagenic. . Stability experiments were determined using Salmonella typhimurium TA98 strain at 500 μl of the Tal collected with the Cambridge filter. The same experiment was performed on commercial sol tobacco as a control. The test results are shown in Table 4.

[표 4]TABLE 4

Figure kpo00004
Figure kpo00004

전술한 안정성 실험결과에 의하면 시판 솔 담배보다 약 40%정도 안전한 것으로 나타났다.According to the above stability test results, it was found that about 40% safer than commercial brush cigarettes.

Claims (12)

진해 거담 효과가 있는 생약재를 잎담배, 담배 각초에 배합하여서된 권련.A medicinal herb that contains herbal medicine with an antitussive expectorant effect in leaf tobacco and tobacco vinegar. 청구범위 1항에서, 생약재가 낭탕, 다투라, 창포, 마황, 철명절, 원지, 길경, 오미자 중에서 선택한 일종 또는 2종 이상에서 선택된 것임을 특징으로 하는 권련.In claim 1, the herb is characterized in that the herbal medicine is selected from one or two or more selected from Nantang, tatura, iris, ephedra, iron festival, paper, Gilgyeong, Schisandra chinensis. 청구범위 1항에서, 생약재가 잎을 건조 세절하여 각초에 배합됨을 특징으로 하는 권련.Claim 1, characterized in that the herbal medicine is characterized in that the leaves are dried finely blended in the grass. 청구범위 1항에서, 생약재가 추출액의 형태로 담배 각초에 첨가됨을 특징으로 하는 권련.The citron according to claim 1, wherein the herbal medicine is added to tobacco citrus in the form of extract. 청구범위 1항에서, 생약재가 판상엽의 상태로 담배 각초에 배합됨을 특징으로 하는 권련.The citrus according to claim 1, wherein the herbal medicine is formulated in tobacco citrus in the form of leaflets. 진해 거담 효과가 있는 생약재를 잎담배 각초에 배합하여 권련을 제조하는 권련 제조방법.A method of manufacturing a citrus liquor by mixing herbal medicines having an antitussive expectorant effect to the leaf tobacco vinegar. 청구범위 6항에서, 생약재가 낭탕, 다투라, 창포, 마황, 철명절, 원지, 길경, 오미자 중에서, 선택한 1종 또는 2종 이상임을 특징으로 하는 방법.The method according to claim 6, wherein the herbal medicine is one or two or more selected from among Nantang, tatura, irises, ephedra, iron festival, original paper, Gilkyung, Schisandra chinensis. 청구범위 6항에서, 생약재가 잎이고, 세절하여 담배 각초에 배합함을 특징으로 하는 방법.The method according to claim 6, wherein the herbal medicine is a leaf, which is cut and blended into tobacco sheaths. 청구범위 6항에서, 생약재가 추출액의 상태로 각초에 배합됨을 특징으로 하는 방법.8. The method of claim 6, wherein the herbal medicine is formulated in the herbicide in the form of extract. 청구범위 6항에서, 생약재가 판상엽의 상태로 담배 각초에 배합됨을 특징으로 하는 방법.8. A method according to claim 6, wherein the herbal medicine is formulated in tobacco citrus in the form of leaflets. 청구범위 10항에서, 판상엽이 제지식으로 제조된 것임을 특징으로 하는 방법.The method of claim 10, wherein the leaflet is produced in papermaking. 청구범위 10항에서, 판상엽이 압연식으로 제조된 것임을 특징으로 하는 방법.Method according to claim 10, characterized in that the platelets are produced by rolling.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100890583B1 (en) * 1997-12-24 2009-03-25 비오신테크 Use of polyphenol compounds as scavengers of free radicals in cigarette filters

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100890583B1 (en) * 1997-12-24 2009-03-25 비오신테크 Use of polyphenol compounds as scavengers of free radicals in cigarette filters

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