KR880014050A - 피복 조성물 - Google Patents

피복 조성물 Download PDF

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Publication number
KR880014050A
KR880014050A KR1019880006226A KR880006226A KR880014050A KR 880014050 A KR880014050 A KR 880014050A KR 1019880006226 A KR1019880006226 A KR 1019880006226A KR 880006226 A KR880006226 A KR 880006226A KR 880014050 A KR880014050 A KR 880014050A
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composition
amine
derived
alkyl
formula
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KR1019880006226A
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English (en)
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파울 레드만 리차드
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알란 브라이안 벡
임페리알 케미칼 인더스트리스 피엘씨
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Application filed by 알란 브라이안 벡, 임페리알 케미칼 인더스트리스 피엘씨 filed Critical 알란 브라이안 벡
Publication of KR880014050A publication Critical patent/KR880014050A/ko

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/797—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing carbodiimide and/or uretone-imine groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/64—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
    • C08G18/6415—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63 having nitrogen
    • C08G18/643—Reaction products of epoxy resins with at least equivalent amounts of amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
    • C08G59/4014—Nitrogen containing compounds
    • C08G59/4028—Isocyanates; Thioisocyanates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4419—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
    • C09D5/443—Polyepoxides
    • C09D5/4434—Polyepoxides characterised by the nature of the epoxy binder
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4419—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
    • C09D5/443—Polyepoxides
    • C09D5/4453—Polyepoxides characterised by the nature of the curing agent

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Molecular Biology (AREA)
  • Paints Or Removers (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

내용 없음

Description

피복 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (17)

  1. (i)(a)다음 구조식(1)의 최소한 하나의 2차 아민;
    R1R2NH
    (1)
    식중, R1및 R2는 같거나 다르고 아미노-또는 보호된 아미노-C2-6알킬, 임의 치환 C1-18알킬 또는 C5-8사이클로알킬이거나 R1및 R2에 부착된 질소원자와 함께 임의치환 5원, 6원 또는 7원 복소환식 그룹을 표시하는데, 각 경우에 임의 치환체는 하나 이상의 C1-4알킬 그룹, C1-4알콕시 그룹 또는 하이드록시 그룹임
    (b)임의로 다음 구조식(2)의 1차 아민
    R3NH2
    (2)
    식중, R3는 아미노, 디-C1-4알킬아미노, 모폴리노 또는 피레라지노로 임의 치환된 C5-8사이클로알킬 또는 C1-18알킬
    (c)폴리에폭사이드로부터 유도된 단위;
    (d)폴리에폭사이드에 대한 임의 캠핑 단위;
    (e)폴리옥시알킬렌 폴리아민으로부터 유도된 임의 단위; 및
    (f)모노에폭사이드로부터 유도된 폴리옥시알킬렌 폴리아민 또는 1차 아민에 대한 임의 캡핑 단위로부터 유도된 단위를 갖는 겔화되지 않은 아민-에폭사이드 반응 생성물;
    (ii)디올 및/또는 트리올; 다음 구조식(3)을 갖는 4,4'-디페닐메탄 디이소시아네이트 및 4,4'-디페닐메탄 디이소시아네이트 우레톤이민 유도체의 혼합물.
    (구조식(3)화합물은 4,4'-디페닐메탄 디이소시아네이트 및 우레톤이민 유도체의 혼합물이 상온에서 액체인 양으로 존재) 및 모노알콜이나 카프롤락탐으로부터 유도된 혼합한 생성물인, 아민-에폭사이드 반응 생성물에 대한 가교제; 및 (iii)본 조성물에 대한 수성 담체로 구성되는 피복조성물.
  2. 제 1 항에 있어서, 아민 에폭사이드가 다음 구조식(10)을 갖는 조성물.
    R1R2N-에폭스1-NR1R2
    (10)
    식중, R1및 R2는 구조식(1)에 관해 정의된 바와같고 에폭스1은 폴리에폭사이드로부터 유도된 단위(c)임.
  3. 제 2 항에 있어서, 하나의 잔기 R1R2N-이 나머지 잔기와 다르며 하나의 잔기에서 R1이 C1-6알킬이고 R2가 하이드록시 C1-6알킬이며 나머지 잔기에서 R1및 R2가 같고 둘다 아미노-C2-6알킬인 조성물.
  4. 제 3 항에 있어서, 에폭스1이 다음 구조식(6)의 진보된 에폭사이드인 조성물.
    식중, Ep는 구조식(4)에폭사이드의 잔기 및 유기폴리올의 잔기임
  5. 제 1 항에 있어서, 아민-에폭사이드 반응생성물이 다음 구조식(11)를 갖는 조성물
    식중, 잔기 R1R2N-이 같고 R1및 R2둘다는 하이드록시 C2-6알킬을 표시; 에폭스1은 폴리에폭사이드의 잔기,는 디-C1-6알킬아미노-C2-6알킬 아민의 잔기, 및은 다음 구조식(12)의 캡핑된 C2-6알칸 디아민의 잔기임
    식중, 에폭스3는 모노에폭사이드의 잔기임
  6. 제 1 항에 있어서, 아민-에폭스 반응생성물이 다음 구조식(13)을 갖는 조성물.
    식중, G는 캡팅 그룹, 에폭스1은 폴리에폭사이드, Am은 폴리옥시알킬렌 폴리아미드, m은 0 또는 1, 에폭스2는 모노에폭사이드, 및 R1R2N-은 구조식(1)아민의 잔기임.
  7. 제 6 항에 있어서, G가 노닐페닐인 조성물.
  8. 제 6 항 또는 제 7 항에 있어서, 에폭스1이 구조식(4)의 에폭사이드로부터 유도된 조성물.
  9. 제 6 항 내지 제 8 항의 어느 한 항에 있어서, Am이 폴리옥시알킬렌 트리아민으로부터 유도된 조성물.
  10. 제 6 항 내지 제10항의 어느 한 항에 있어서, 에폭스2가 C9-분지쇄 글리시딜 에스테르로부터 유도된 조성물.
  11. 제 6 항 내지 제 9 항의 어느 한 항에 있어서, R1이 메틸이고 R2가 2-하이드록시에틸인 조성물.
  12. 제 1 항 내지 제11항의 어느 한 항에 있어서, 가교제내의 4,4-디페닐메탄 디이소시아네이트 단위 대 우레톤이민 유도된 단위의 중량비가 90 : 10 내지 10 : 90 범위인 조성물.
  13. 제12항에 있어서, 중량비가 75 : 25 내지 25 : 75 인 조성물.
  14. 제 1 항 내지 제 3 항의 어느 한 항에 있어서, 가교제 대 에폭시아민 부가물의 비가 10 : 90 내지 60 : 40인 조성물.
  15. 제 4 항에 있어서, 가교제 대 아민-에폭사이드 반응생성물의 비가 20 : 80 내지 50 : 50인 조성물.
  16. 제 1 항에 정의된 아민-에폭사이드 반응생성물을 가교제 및 수성 담체와 함께 분산시키는 것으로 구성되는 제 1 항 내지 제 5 항의 어느 한 항의 조성물을 제조하는 방법.
  17. 피복될 기판을 제 1 항 내지 제15항의 어느 한 항의 조성물에 잠기게하고 음극인 기판과 양극인 반대전극 사이에 전류를 통하게 하는 것으로 구성되는, 전도성 기판의 피복방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880006226A 1987-05-28 1988-05-27 피복 조성물 KR880014050A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8712577 1987-05-28
GB878712577A GB8712577D0 (en) 1987-05-28 1987-05-28 Coating compositions

Publications (1)

Publication Number Publication Date
KR880014050A true KR880014050A (ko) 1988-12-22

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ID=10618056

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Application Number Title Priority Date Filing Date
KR1019880006226A KR880014050A (ko) 1987-05-28 1988-05-27 피복 조성물

Country Status (16)

Country Link
US (1) US4892897A (ko)
EP (1) EP0293088B1 (ko)
JP (1) JPH0822995B2 (ko)
KR (1) KR880014050A (ko)
AR (1) AR245767A1 (ko)
AU (1) AU596298B2 (ko)
CA (1) CA1336632C (ko)
DE (1) DE3873987T2 (ko)
ES (1) ES2051842T3 (ko)
GB (2) GB8712577D0 (ko)
IN (1) IN176083B (ko)
MY (1) MY103161A (ko)
NZ (1) NZ224469A (ko)
PT (1) PT87595B (ko)
ZA (1) ZA883147B (ko)
ZW (1) ZW5088A1 (ko)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1990007778A1 (en) * 1988-12-26 1990-07-12 Filial Vsesojuznogo Elektrotekhnicheskogo Instituta Imeni V.I.Lenina Composition for electrically insulating material
GB9011710D0 (en) * 1990-05-25 1990-07-18 Shell Int Research Heat-curable thermosetting resin system for cathodic electrodeposition
DE4018087A1 (de) * 1990-06-06 1991-12-12 Basf Lacke & Farben Verfahren zum beschichten elektrisch leitfaehiger substrate, waessrige lacke und blockierte nco-gruppen enthaltende vernetzungsmittel
DE4020115A1 (de) * 1990-06-23 1992-01-02 Basf Lacke & Farben Verfahren zum beschichten elektrisch leitfaehiger substrate, waessriger lack und blockierte nco-gruppen enthaltendes vernetzungsmittel
US5089100A (en) * 1990-08-06 1992-02-18 E. I. Du Pont De Nemours And Company Method of incorporating polyamine into a cationic resin
GB9111559D0 (en) * 1991-05-29 1991-07-17 Ici Plc Polyisocyanate composition
GB9117070D0 (en) * 1991-08-08 1991-09-25 Ici Plc Polyisocyanate compositions
US6020069A (en) * 1998-06-18 2000-02-01 E. I. Du Pont De Nemours And Company Cathodic electrocoating composition containing an epoxy resin chain extended with a primary amine
AT409631B (de) * 1998-10-28 2002-09-25 Solutia Austria Gmbh Ionisch oder nichtionisch stabilisierte epoxidaddukte als wasserverdünnbare basisharze für 2 k-isocyanat systeme
CA2349139C (en) * 2000-05-31 2007-09-11 Kansai Paint Co., Ltd. Cationic resin composition
EP1655350A1 (en) * 2004-11-09 2006-05-10 Cytec Surface Specialties Austria GmbH Aqueous paint composition and process to reduce or suppress surface defects in paint films

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2819827A1 (de) * 1978-05-05 1979-11-08 Bayer Ag Pulverfoermige ueberzugsmittel
JPS55127472A (en) * 1979-03-26 1980-10-02 Kansai Paint Co Ltd Resin composition for cation electrodeposition coating
GB2113802B (en) * 1982-01-18 1986-04-23 Dixon And Company Limited R G Shaft couplings
DE3232463A1 (de) * 1982-09-01 1984-03-01 Bayer Ag, 5090 Leverkusen Verwendung blockierter polyisocyanate als haerter fuer hydroxylgruppen-haltige bindemittel
US4615779A (en) * 1985-02-07 1986-10-07 Ppg Industries, Inc. Cationic coating compositions for electrodeposition over rough steel
GB8509955D0 (en) * 1985-04-18 1985-05-30 Ici Plc Coating compositions
GB2173802B (en) * 1985-04-18 1989-12-28 Ici Plc Non-gelled amine-epoxide reaction products and coating compositions comprising acid salts thereof
GB8530645D0 (en) * 1985-12-12 1986-01-22 Ici Plc Coating compositions

Also Published As

Publication number Publication date
IN176083B (ko) 1996-01-20
GB8810106D0 (en) 1988-06-02
ZA883147B (en) 1989-10-25
JPH0822995B2 (ja) 1996-03-06
PT87595B (pt) 1992-10-30
GB8712577D0 (en) 1987-07-01
CA1336632C (en) 1995-08-08
JPS63309564A (ja) 1988-12-16
AU596298B2 (en) 1990-04-26
DE3873987D1 (de) 1992-10-01
AR245767A1 (es) 1994-02-28
AU1567488A (en) 1988-12-01
PT87595A (pt) 1988-06-01
NZ224469A (en) 1990-08-28
EP0293088B1 (en) 1992-08-26
DE3873987T2 (de) 1993-03-04
ZW5088A1 (en) 1989-12-06
MY103161A (en) 1993-04-30
ES2051842T3 (es) 1994-07-01
US4892897A (en) 1990-01-09
EP0293088A1 (en) 1988-11-30

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