KR880013859A - 파릴렌 이량체의 개선된 제조방법 - Google Patents

파릴렌 이량체의 개선된 제조방법 Download PDF

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KR880013859A
KR880013859A KR1019880006111A KR880006111A KR880013859A KR 880013859 A KR880013859 A KR 880013859A KR 1019880006111 A KR1019880006111 A KR 1019880006111A KR 880006111 A KR880006111 A KR 880006111A KR 880013859 A KR880013859 A KR 880013859A
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Prior art keywords
hydroxide
ether
paracyclophane
tetraglyme
diglyme
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KR1019880006111A
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KR930000888B1 (ko
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이진수
로빈스 바세트 데이비드
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티모시 엔.비숍
유니온 카바이드 코포레이션
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/72—Spiro hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C07C1/321—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom
    • C07C1/323—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom the hetero-atom being a nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/70—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a condensed ring system consisting of at least two, mutually uncondensed aromatic ring systems, linked by an annular structure formed by carbon chains on non-adjacent positions of the aromatic ring, e.g. cyclophanes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/92—Systems containing at least three condensed rings with a condensed ring system consisting of at least two mutually uncondensed aromatic ring systems, linked by an annular structure formed by carbon chains on non-adjacent positions of the aromatic system, e.g. cyclophanes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Paper (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
  • Polarising Elements (AREA)

Abstract

내용 없음

Description

파릴렌 이량체의 개선된 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 선행기술에 따른 회분식 반응에서의 시간에 따른 2, 2-파라사이클로판의 수율을 나타내는 그래프(여기서, DMSO 대 4급 암모늄염의 몰비는 변한다)이다. 제2도는 디메틸설폭사이드만을 사용하여 수득한 이량체 및 본 발명의 특정한 반응 촉진제와 혼합하여 수득한 이량체의 중량%를 나타내는 그래프이다.

Claims (18)

  1. P-메틸벤질트리메틸암모늄 할라이드의 수용액을 디메틸설폭사이드와 (a) 하기 일반식의 메틸 알킬렌옥시에테르 및 (b) 4개 내지 6개의 산소원자와 12개 내지 18개의 탄소원자를 갖는 크라운 에테르로 구성된 그룹으로 부터 선택된 하나 이상의 반응 촉진제의 존재하에 알칼리 수산화물과 접촉시킨 후, 2, 2-파라사이클로판을 회수함을 특징으로 하여 파릴렌의 제조에 사용하는 2, 2-파라사이클로판 이량체를 제조하는 개선된 방법.
    상기식에서, n은 1 내지 18이고, m은 0 또는 1 내지 4이다.
  2. 제1항에 있어서, 공정이 불활성 수-볼혼화성 유기 용매의 존재하에 수행되는 방법.
  3. 제2항에 있어서, 용매가 벤젠, 톨루엔, 파라-크실렌, 오르토-크실렌, 메타-크실렌, 헥산, 옥탄 및 메틸렌 클로라이드의 그룹으로부터 선택되는 방법.
  4. 제1항에 있어서, 크라운 에테르가 1, 4, 7, 10, 13, 16-헥사옥사사이클로옥타데칸인 방법.
  5. 제1항에 있어서, 메톡시알케닐옥시에테르가 디글림인 방법.
  6. 제5항에 있어서, 디글림이 2-메톡시에틸에테르인 방법.
  7. 제1항에 있어서, 메톡시알콕시에테르가 테트라 글림인 방법.
  8. 제7항에 있어서, 테트라글림이 2-부톡시에틸에테르인 방법.
  9. 제1항에 있어서, 수산화물이 수산화나트륨인 방법.
  10. 제1항에 있어서, 수산화물이 수산화카륨인 방법.
  11. P-메틸벤질트리메틸암모늄 클로라이드의 용액을 불활성, 수-불혼화성 유기용매, 디메틸설폭사이드 및 (a) 하기 일반식의 메틸 메톡시에틸 에트레 및 (b) 1, 4, 7, 0, 13, 16-헥사옥사사이클로옥타데칸으로 구성된 하나 이상의 반응 촉진제의 존재하에 알칼리 수산화물과 접촉시킨 후, 2, 2-파라사이클로판을 회수함을 특징으로 하여 2, 2-파라사이클로판을 제조하는 개선된 방법.
    상기식에서, n은 1 내지 18이고, m은 0 또는 1 내지 4이다.
  12. 제11항에 있어서, 알칼리 수산화물이 수산화 나트륨인 방법.
  13. 제11항에 있어서, 알칼리 수산화물이 수산화 칼륨인 방법.
  14. 제11항에 있어서, 유기용매가 크실렌인 방법.
  15. 제11항에 있어서, 메틸 메톡시에틸 에테르가 디글림인 방법.
  16. 제11항에 있어서, 디글림 2-메톡시에틸 에테르인 방법.
  17. 제11항에 있어서, 메틸 메톡시에틸 에테르가 테트라글림인 방법.
  18. 제11항에 있어서, 테트라글림이 2-부톡시에틸에테르인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880006111A 1987-05-26 1988-05-25 파릴렌 이량체의 개선된 제조방법 KR930000888B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US053,732 1979-07-02
US07/053,732 US4806702A (en) 1987-05-26 1987-05-26 Process for the preparation of the parylene dimer

Publications (2)

Publication Number Publication Date
KR880013859A true KR880013859A (ko) 1988-12-22
KR930000888B1 KR930000888B1 (ko) 1993-02-11

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Country Status (14)

Country Link
US (1) US4806702A (ko)
EP (1) EP0294651B1 (ko)
JP (1) JPH0637407B2 (ko)
KR (1) KR930000888B1 (ko)
AU (1) AU613368B2 (ko)
BR (1) BR8802506A (ko)
CA (1) CA1282434C (ko)
DE (1) DE3861825D1 (ko)
DK (1) DK284988A (ko)
ES (1) ES2021411B3 (ko)
GR (1) GR3001619T3 (ko)
MX (1) MX166115B (ko)
NO (1) NO167565C (ko)
SG (1) SG94591G (ko)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5110903A (en) * 1990-12-20 1992-05-05 Union Carbide Chemicals & Plastics Technology Corporation Process for the preparation of mixed parylene dimers free of alpha-halogens
EP0554675A1 (de) * 1992-01-31 1993-08-11 Hoechst Aktiengesellschaft Verfahren zur Herstellung von Polymeren des para-Xylylens und von diesem abgeleiteten Derivaten
US5302767A (en) * 1993-03-26 1994-04-12 Union Carbide Chemicals & Plastics Technology Corporation [2.2] paracyclophane and derivatives thereof
US9011627B2 (en) 2007-10-05 2015-04-21 Carver Scientific, Inc. Method of manufacturing high permittivity low leakage capacitor and energy storing device
US8633289B2 (en) 2011-08-31 2014-01-21 Carver Scientific, Inc. Formation of [2,2]paracyclophane and related compounds and methods for the formation of polymers from cyclophanes
US8940850B2 (en) 2012-08-30 2015-01-27 Carver Scientific, Inc. Energy storage device
CN101889321A (zh) 2007-10-05 2010-11-17 D·卡弗 高电容率低漏电的电容器和能量存储器件及其形成方法
US9214281B2 (en) 2008-10-03 2015-12-15 Carver Scientific, Inc. Very thin dielectrics for high permittivity and very low leakage capacitors and energy storing devices
US9214280B2 (en) 2008-10-03 2015-12-15 Carver Scientific, Inc. Very thin dielectrics for high permittivity and very low leakage capacitors and energy storing devices
US10227432B2 (en) 2011-08-31 2019-03-12 Carver Scientific, Inc. Formation of xylylene type copolymers, block polymers, and mixed composition materials
CN102516026A (zh) * 2011-11-30 2012-06-27 苏州市贝克生物科技有限公司 一种二氯环二聚对二甲苯的生产工艺
US10199165B2 (en) 2012-08-30 2019-02-05 Carver Scientific, Inc. Energy storage device
US9899846B2 (en) 2012-08-30 2018-02-20 Carver Scientific, Inc. Entropic energy transfer methods and circuits
US9805869B2 (en) 2012-11-07 2017-10-31 Carver Scientific, Inc. High energy density electrostatic capacitor
EP3371811B1 (en) 2015-11-06 2022-11-23 Carver Scientific, Inc. Electroentropic memory device
MX2019006368A (es) 2016-12-02 2019-08-21 Carver Scient Inc Dispositivo de memoria y dispositivo de almacenamiento de energia capacitiva.
CN113307714B (zh) * 2021-06-18 2021-12-03 安徽苏乐医药材料有限公司 一种派瑞林n的制备方法

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DE3240303C1 (de) * 1982-10-30 1984-01-19 Merck Patent Gmbh, 6100 Darmstadt Verfahren zur Herstellung von [2,2]-Paracyclophan
IT1177104B (it) * 1984-11-02 1987-08-26 Montedison Spa Processo per la preparazione di (2,2)-paraciclofano
IT1191632B (it) * 1985-10-30 1988-03-23 Montedison Spa Processo per la preparazione di (2,2)-paraciolofano
IT1190350B (it) * 1986-06-27 1988-02-16 Montedison Spa Processo per la preparazione di (2,2)-paraciclofano e suoi derivati
US4769505A (en) * 1987-07-17 1988-09-06 Union Carbide Corporation Process for the preparation of the parylene dimer

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EP0294651A1 (en) 1988-12-14
ES2021411B3 (es) 1991-11-01
CA1282434C (en) 1991-04-02
US4806702A (en) 1989-02-21
BR8802506A (pt) 1988-12-20
SG94591G (en) 1992-01-17
AU1656488A (en) 1988-12-01
NO882295D0 (no) 1988-05-25
KR930000888B1 (ko) 1993-02-11
AU613368B2 (en) 1991-08-01
NO167565B (no) 1991-08-12
DE3861825D1 (de) 1991-04-04
JPH0637407B2 (ja) 1994-05-18
JPS63307830A (ja) 1988-12-15
DK284988A (da) 1988-11-27
MX166115B (es) 1992-12-21
GR3001619T3 (en) 1992-11-23
EP0294651B1 (en) 1991-02-27
NO882295L (no) 1988-11-28
NO167565C (no) 1991-11-20
DK284988D0 (da) 1988-05-25

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