MX166115B - Procedimiento mejorado para la preparacion de dimero de parileno - Google Patents

Procedimiento mejorado para la preparacion de dimero de parileno

Info

Publication number
MX166115B
MX166115B MX011632A MX1163288A MX166115B MX 166115 B MX166115 B MX 166115B MX 011632 A MX011632 A MX 011632A MX 1163288 A MX1163288 A MX 1163288A MX 166115 B MX166115 B MX 166115B
Authority
MX
Mexico
Prior art keywords
preparation
improved procedure
parylene dimer
parylene
ether
Prior art date
Application number
MX011632A
Other languages
English (en)
Inventor
Chinsoo Lee
David Robinson Bassett
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of MX166115B publication Critical patent/MX166115B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/72—Spiro hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C07C1/321—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom
    • C07C1/323—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a non-metal atom the hetero-atom being a nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/70—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a condensed ring system consisting of at least two, mutually uncondensed aromatic ring systems, linked by an annular structure formed by carbon chains on non-adjacent positions of the aromatic ring, e.g. cyclophanes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/92—Systems containing at least three condensed rings with a condensed ring system consisting of at least two mutually uncondensed aromatic ring systems, linked by an annular structure formed by carbon chains on non-adjacent positions of the aromatic system, e.g. cyclophanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Polarising Elements (AREA)
  • Paper (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)

Abstract

La presente invención se refiere a un procedimiento mejorado para la preparación del dímero de 2,2-paraciclofano utilizado en la preparación de parileno, que comprende poner en contacto la solución acuosa de haluro de p-metilbenciltrimetilamonio con un hidróxido alcalino en presencia de sulfóxido de dimetilo y, cuando menos un promotor de reacción seleccionado a partir del grupo que consiste de: a) un éter de metilalquilenoxi de la fórmula: CH3-(-O-CH2-CH2-)n-O-(CH2-CH2-O)m-CH3 en donde n tiene un valor de 1 a 18, y m es de 0 ó 1 a 4, y b) un éter de corona que tiene de 4 a 6 átomos de oxígeno y de 12 a 18 átomos de carbono; y a continuación, recuperar el 2,2-paraciclofano.
MX011632A 1987-05-26 1988-05-25 Procedimiento mejorado para la preparacion de dimero de parileno MX166115B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/053,732 US4806702A (en) 1987-05-26 1987-05-26 Process for the preparation of the parylene dimer

Publications (1)

Publication Number Publication Date
MX166115B true MX166115B (es) 1992-12-21

Family

ID=21986187

Family Applications (1)

Application Number Title Priority Date Filing Date
MX011632A MX166115B (es) 1987-05-26 1988-05-25 Procedimiento mejorado para la preparacion de dimero de parileno

Country Status (14)

Country Link
US (1) US4806702A (es)
EP (1) EP0294651B1 (es)
JP (1) JPH0637407B2 (es)
KR (1) KR930000888B1 (es)
AU (1) AU613368B2 (es)
BR (1) BR8802506A (es)
CA (1) CA1282434C (es)
DE (1) DE3861825D1 (es)
DK (1) DK284988A (es)
ES (1) ES2021411B3 (es)
GR (1) GR3001619T3 (es)
MX (1) MX166115B (es)
NO (1) NO167565C (es)
SG (1) SG94591G (es)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5110903A (en) * 1990-12-20 1992-05-05 Union Carbide Chemicals & Plastics Technology Corporation Process for the preparation of mixed parylene dimers free of alpha-halogens
EP0554675A1 (de) * 1992-01-31 1993-08-11 Hoechst Aktiengesellschaft Verfahren zur Herstellung von Polymeren des para-Xylylens und von diesem abgeleiteten Derivaten
US5302767A (en) * 1993-03-26 1994-04-12 Union Carbide Chemicals & Plastics Technology Corporation [2.2] paracyclophane and derivatives thereof
US9011627B2 (en) 2007-10-05 2015-04-21 Carver Scientific, Inc. Method of manufacturing high permittivity low leakage capacitor and energy storing device
EP2206130B1 (en) 2007-10-05 2018-05-09 Carver Scientific, Inc. High permittivity low leakage capacitor and energy storing device and method for forming the same
US8940850B2 (en) 2012-08-30 2015-01-27 Carver Scientific, Inc. Energy storage device
US8633289B2 (en) 2011-08-31 2014-01-21 Carver Scientific, Inc. Formation of [2,2]paracyclophane and related compounds and methods for the formation of polymers from cyclophanes
US9214281B2 (en) 2008-10-03 2015-12-15 Carver Scientific, Inc. Very thin dielectrics for high permittivity and very low leakage capacitors and energy storing devices
US9214280B2 (en) 2008-10-03 2015-12-15 Carver Scientific, Inc. Very thin dielectrics for high permittivity and very low leakage capacitors and energy storing devices
US10227432B2 (en) 2011-08-31 2019-03-12 Carver Scientific, Inc. Formation of xylylene type copolymers, block polymers, and mixed composition materials
CN102516026A (zh) * 2011-11-30 2012-06-27 苏州市贝克生物科技有限公司 一种二氯环二聚对二甲苯的生产工艺
US9899846B2 (en) 2012-08-30 2018-02-20 Carver Scientific, Inc. Entropic energy transfer methods and circuits
US10199165B2 (en) 2012-08-30 2019-02-05 Carver Scientific, Inc. Energy storage device
US9805869B2 (en) 2012-11-07 2017-10-31 Carver Scientific, Inc. High energy density electrostatic capacitor
CN108292514B (zh) 2015-11-06 2022-04-29 卡弗科学有限公司 电熵存储器设备
KR102519699B1 (ko) 2016-12-02 2023-04-07 카버 싸이언티픽, 아이엔씨. 메모리 장치 및 용량성 에너지 저장 장치
CN113307714B (zh) * 2021-06-18 2021-12-03 安徽苏乐医药材料有限公司 一种派瑞林n的制备方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3240303C1 (de) * 1982-10-30 1984-01-19 Merck Patent Gmbh, 6100 Darmstadt Verfahren zur Herstellung von [2,2]-Paracyclophan
IT1177104B (it) * 1984-11-02 1987-08-26 Montedison Spa Processo per la preparazione di (2,2)-paraciclofano
IT1191632B (it) * 1985-10-30 1988-03-23 Montedison Spa Processo per la preparazione di (2,2)-paraciolofano
IT1190350B (it) * 1986-06-27 1988-02-16 Montedison Spa Processo per la preparazione di (2,2)-paraciclofano e suoi derivati
US4769505A (en) * 1987-07-17 1988-09-06 Union Carbide Corporation Process for the preparation of the parylene dimer

Also Published As

Publication number Publication date
DE3861825D1 (de) 1991-04-04
AU1656488A (en) 1988-12-01
NO167565B (no) 1991-08-12
BR8802506A (pt) 1988-12-20
US4806702A (en) 1989-02-21
CA1282434C (en) 1991-04-02
AU613368B2 (en) 1991-08-01
DK284988A (da) 1988-11-27
DK284988D0 (da) 1988-05-25
EP0294651B1 (en) 1991-02-27
JPH0637407B2 (ja) 1994-05-18
EP0294651A1 (en) 1988-12-14
SG94591G (en) 1992-01-17
NO882295D0 (no) 1988-05-25
ES2021411B3 (es) 1991-11-01
KR880013859A (ko) 1988-12-22
NO167565C (no) 1991-11-20
JPS63307830A (ja) 1988-12-15
GR3001619T3 (en) 1992-11-23
KR930000888B1 (ko) 1993-02-11
NO882295L (no) 1988-11-28

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