KR880009893A - 살충 화합물의 중간생성물 제조방법 - Google Patents

살충 화합물의 중간생성물 제조방법 Download PDF

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KR880009893A
KR880009893A KR1019880001065A KR880001065A KR880009893A KR 880009893 A KR880009893 A KR 880009893A KR 1019880001065 A KR1019880001065 A KR 1019880001065A KR 880001065 A KR880001065 A KR 880001065A KR 880009893 A KR880009893 A KR 880009893A
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South Korea
Prior art keywords
compound
formula
trifluoro
ene
following structural
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KR1019880001065A
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English (en)
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아써 엘리스 카 로빈
포웰 라인
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알란 브라이안 벡
임페리알 케미칼 인더스트리스 피엘씨
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Publication of KR880009893A publication Critical patent/KR880009893A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/385—Saturated compounds containing a keto group being part of a ring
    • C07C49/403—Saturated compounds containing a keto group being part of a ring of a six-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/257—Ethers having an ether-oxygen atom bound to carbon atoms both belonging to six-membered aromatic rings
    • C07C43/29—Ethers having an ether-oxygen atom bound to carbon atoms both belonging to six-membered aromatic rings containing halogen
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
    • A01N31/14—Ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/263—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions
    • C07C17/2635—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions involving a phosphorus compound, e.g. Wittig synthesis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/14—Unsaturated ethers
    • C07C43/17—Unsaturated ethers containing halogen
    • C07C43/174—Unsaturated ethers containing halogen containing six-membered aromatic rings
    • C07C43/176—Unsaturated ethers containing halogen containing six-membered aromatic rings having unsaturation outside the aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/20—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
    • C07C43/225—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring containing halogen

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pyridine Compounds (AREA)
  • Furan Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

내용 없음.

Description

살충 화합물의 중간생성물 제조 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 강염기의 존재에서 다음 구조식의 케톤과
    다음 구조식의 포스포늄 염 사이의 Hal-(Q)3P+-CH2-Y 식중, Q는 C6까지의 알킬 또는 아릴, Hal-은 할라이드 음이온 위티그(Wittig) 반응으로 구성되는, 다음 구조식 화합물의 제조방법
    식중, W는 할로, C6까지의 알킬, C6까지의 알콕시, C6까지의 할로알킬, C6까지의 할로알콕시 및 총 C6까지의 알콕시알킬로부터 독립적으로 선택된 1,2,3 또는 4개 치환체를 표시하거나 C4까지의 알킬렌 및 C4까지의 알킬렌디옥시로부터 선택된 인접 탄소 원자에 결합하는 이좌배위 그룹을 표시, X는 C2까지의 플루오로알킬 그룹을 표시, Y는 염소, 브롬 및 알콕시로부터 선택.
  2. 다음 구조식 화합물
    식중, W,X 및 Y는 제1항에 주어진 의미의 어느 것임.
  3. 제2항에 있어서, W가 클로로, 브로모, 플루오로, 메톡시, 에톡시, 트리풀루오로메틸, 트리플루오로메톡시 및 디플루오로 메톡시로부터 선택된 1,2 또는 3개 치환체이고 X가 트리플루오로메틸이며 Y가 염소, 브롬, 메톡시 및 에톡시로부터 선택되는 화합물.
  4. 제2항에 있어서, 1,1,1-트리플루오로-2-(4-에토시페닐)-3-메톡시프롭-2-엔, 1,1,1-트리풀루오로-2-(4-에톡시페닐)-3-클로로프롭-2-엔, 1,1,1-트리플루오로-2-(4-에톡시페닐)-3-브로모프롭-2-엔, 1,1,1-트리플루오로-2-(4-트리플루오로메톡시페닐)-3-메톡시프롭-2-엔, 1,1,1-트리플루오로-2-(4-트리풀루오로메톡시페닐)-3-크로로프롭-2-엔, 1,1,1-트리플루오로-2-(4-트리플루오로메톡시페닐)-3-브로모프롭-2-엔, 1,1,1-트리플루오로-2-(4-트리프루오로메톡시페닐)-3-메톡시프롭-2엔, 1,1,1-트리플루오로-2-(4-트리플루오로메톡시페닐)-3-클로로프롭-2-엔, 1,1,1-트리플루오로-2-(4-클로로페닐)-3-메톡시프롭-2-엔, 1,1,1-트리플루오로-2-(4-클로로페닐)-3-메톡시프롭-2-엔으로 구성되는 화합물 그룹으로부터 선택된 화합물.
  5. (i)다음 구조식 화합물의 한 촉매
    〔식중,Y는 C4까지의 알콕시 가수분해로 다음 구조식(Ⅴ)알데하이드를 생성하고
    (ii)구조식(Ⅴ)알데하이드를 환원시켜 다음 구조식(Ⅵ)알콜을 생성하며
    (iii)염기의 존재에서, 임의로 상(phase)전이 촉맥 존재하는 두 개의 상 시스템에서 구조식(Ⅵ)알콜과 다음 구조식 화합물을
    〔식중, Hal은 수소원자 반응시키는 단계로 구성되는, 다음 구조식 화합물의 제조방법.
    식중, W 및 X는 제1항에 주어진 의미의 어느 것이고, R은 수소, 시아노, 에티닐, 메틸 및 트리플루오로메틸로부터 선택되며, Z는 각 치환제가 할로, C6까지의 알킬, 아릴, 알킬 부분의 C6까지의 아랄킬, 아릴옥시 및 아릴아미노로부터 선택되는 치환된 아릴 그룹을 표시.
  6. (i)다음 구조식 화합물을
    식중, Y는 염소 또는 브룸 다음 구조식 화합물과 반응시켜다음 구조식(Ⅶ)화합물을 생성하고
    (ii)구조식(Ⅶ)화합물을 환원시켜 구조식(Ⅳ)화합물을 생성하는 단계로 구성되는, 다음 구조식(Ⅳ)화랍물의 제조방법. 식중, W, X, R 및 Z는 제5항에 주어진 의미의 어느 것임.
    식중, W, X, R 및 Z는 제5항에 주어진 의미의 어느 것임
  7. (i)다음 구조식 화합물을
    식중, Y는 C4까지의 알콕시 초산제이수은의 존재에서 다음 구조식 화합물과 반응시켜다음 구조식(Ⅶ)화합물을 생성하고
    (ii)구조식(Ⅶ)화합물을 환원시켜 구조식(Ⅳ)화합물을 생성하는 단계로 구성되는, 다음 구조식(Ⅳ)화합물의 제조방법.
    식중, W, X, R 및 Z는 제5항에 주어진 의미의 어느 것임.
  8. 1,1,1-트리플루오로-2-(4-트리플루오로메톡시페닐)-3-〔3-(4-클로로페녹시)-4-플루오로벤질옥시〕프로판.
  9. 살충적으로 불활성인 희석재 또는 담체와 결합된 제8항 화합물의 살충적 효과량으로 구성되는 살충 조성물.
  10. 해충의 소재지를 제9항 조성물의 살충적 효과량으로 처리하는 것으로 구성되는, 해충의 퇴치 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880001065A 1987-02-06 1988-02-05 살충 화합물의 중간생성물 제조방법 KR880009893A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB878702717A GB8702717D0 (en) 1987-02-06 1987-02-06 Insecticidal compounds
GB8702717 1987-02-06

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KR880009893A true KR880009893A (ko) 1988-10-05

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Country Status (10)

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US (2) US4891450A (ko)
EP (1) EP0280383A1 (ko)
JP (1) JPS63225325A (ko)
KR (1) KR880009893A (ko)
AU (1) AU606118B2 (ko)
BR (1) BR8800426A (ko)
GB (2) GB8702717D0 (ko)
MY (1) MY102661A (ko)
NZ (1) NZ223153A (ko)
PH (1) PH24387A (ko)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2233650B (en) * 1987-02-06 1991-06-26 Ici Plc Insecticidal ether
GB8822793D0 (en) * 1988-09-28 1988-11-02 Ici Plc Insecticidal compounds
AU2002953128A0 (en) * 2002-12-05 2002-12-19 Osmose (Australia) Pty Ltd Surface treatment for wood and wood products

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2456316A (en) * 1947-06-10 1948-12-14 Thompson Boyce Plant Res Method for producing alpha-ethylpiperonyl ethers
US2475423A (en) * 1948-04-13 1949-07-05 Eastman Kodak Co Alpha-fluoromethyl styrenes and polymers thereof
NL102188C (ko) * 1957-03-23
GB1085645A (en) * 1964-06-09 1967-10-04 Kenya Pyrethrum Board Insecticidal compositions
DE3438483A1 (de) * 1984-10-17 1986-04-17 Schering AG, Berlin und Bergkamen, 1000 Berlin Substituierte benzylether, schaedlingsbekaempfungsmittel enthaltend diese verbindungen sowie verfahren zu ihrer herstellung
GB8520027D0 (en) * 1985-08-09 1985-09-18 Ici Plc Insecticidal ethers
DE3602169A1 (de) * 1986-01-22 1987-07-23 Schering Ag Neue alkan- und alkoxyalkanderivate, verfahren zu ihrer herstellung und diese verbindungen enthaltende insektizide und akarizide mittel
US4840971A (en) * 1986-04-07 1989-06-20 Sumitomo Chemical Company, Limited Novel ether compound, a process for manufacturing the same, a composition containing the same and a use thereof
DE3780291T2 (de) * 1987-01-08 1993-01-07 Ici Plc Insektizide aether.
GB8710939D0 (en) * 1987-05-08 1987-06-10 Ici Plc Insecticidal ethers

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Publication number Publication date
GB2201956A (en) 1988-09-14
GB8800328D0 (en) 1988-02-10
AU606118B2 (en) 1991-01-31
GB2201956B (en) 1991-07-03
GB8702717D0 (en) 1987-03-11
AU1025488A (en) 1988-08-11
JPS63225325A (ja) 1988-09-20
MY102661A (en) 1992-08-17
NZ223153A (en) 1990-03-27
US4988826A (en) 1991-01-29
BR8800426A (pt) 1988-09-20
US4891450A (en) 1990-01-02
EP0280383A1 (en) 1988-08-31
PH24387A (en) 1990-06-13

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