KR880001715A - 신규 폴리에스테르 중합체 - Google Patents
신규 폴리에스테르 중합체 Download PDFInfo
- Publication number
- KR880001715A KR880001715A KR1019870007276A KR870007276A KR880001715A KR 880001715 A KR880001715 A KR 880001715A KR 1019870007276 A KR1019870007276 A KR 1019870007276A KR 870007276 A KR870007276 A KR 870007276A KR 880001715 A KR880001715 A KR 880001715A
- Authority
- KR
- South Korea
- Prior art keywords
- carbon atoms
- alkyl group
- bis
- polyester polymer
- formula
- Prior art date
Links
- 229920000728 polyester Polymers 0.000 title claims 11
- 229920000642 polymer Polymers 0.000 title claims 11
- 125000000217 alkyl group Chemical group 0.000 claims 9
- 125000004432 carbon atom Chemical group C* 0.000 claims 9
- 125000005843 halogen group Chemical group 0.000 claims 6
- 238000000034 method Methods 0.000 claims 6
- 150000002148 esters Chemical class 0.000 claims 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 5
- -1 Polyethylene terephthalate Polymers 0.000 claims 3
- 150000001875 compounds Chemical class 0.000 claims 3
- 229920000139 polyethylene terephthalate Polymers 0.000 claims 3
- 239000005020 polyethylene terephthalate Substances 0.000 claims 3
- BLSXJPXCICBMMK-UHFFFAOYSA-N 2-[4-(5-carboxy-1,3-dioxoisoindol-2-yl)-3-chlorophenyl]-1,3-dioxoisoindole-5-carboxylic acid Chemical compound O=C1C2=CC=C(C(O)=O)C=C2C(=O)N1C(C(Cl)=C1)=CC=C1N1C(=O)C2=CC=C(C(=O)O)C=C2C1=O BLSXJPXCICBMMK-UHFFFAOYSA-N 0.000 claims 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 2
- AKOGNYJNGMLDOA-UHFFFAOYSA-N (4-acetyloxyphenyl) acetate Chemical compound CC(=O)OC1=CC=C(OC(C)=O)C=C1 AKOGNYJNGMLDOA-UHFFFAOYSA-N 0.000 claims 1
- LTMLBTNDIHVVJN-UHFFFAOYSA-N 2-[4-(5-carboxy-1,3-dioxoisoindol-2-yl)-3-methylphenyl]-1,3-dioxoisoindole-5-carboxylic acid Chemical compound O=C1C2=CC=C(C(O)=O)C=C2C(=O)N1C1=CC=C(N2C(C3=CC(=CC=C3C2=O)C(O)=O)=O)C(C)=C1 LTMLBTNDIHVVJN-UHFFFAOYSA-N 0.000 claims 1
- IHTQUKBUJJKNFQ-UHFFFAOYSA-N 4-(4-acetyloxyphenyl)benzoic acid Chemical compound C1=CC(OC(=O)C)=CC=C1C1=CC=C(C(O)=O)C=C1 IHTQUKBUJJKNFQ-UHFFFAOYSA-N 0.000 claims 1
- GDBUZIKSJGRBJP-UHFFFAOYSA-N 4-acetoxy benzoic acid Chemical compound CC(=O)OC1=CC=C(C(O)=O)C=C1 GDBUZIKSJGRBJP-UHFFFAOYSA-N 0.000 claims 1
- WXNZTHHGJRFXKQ-UHFFFAOYSA-N 4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1 WXNZTHHGJRFXKQ-UHFFFAOYSA-N 0.000 claims 1
- CEYHCFWLAASWDU-UHFFFAOYSA-N [4-(4-acetyloxyphenoxy)phenyl] acetate Chemical compound C1=CC(OC(=O)C)=CC=C1OC1=CC=C(OC(C)=O)C=C1 CEYHCFWLAASWDU-UHFFFAOYSA-N 0.000 claims 1
- RQMBBMQDXFZFCC-UHFFFAOYSA-N [4-(4-acetyloxyphenyl)phenyl] acetate Chemical group C1=CC(OC(=O)C)=CC=C1C1=CC=C(OC(C)=O)C=C1 RQMBBMQDXFZFCC-UHFFFAOYSA-N 0.000 claims 1
- FZLFICOUTCHSSD-UHFFFAOYSA-N [4-(4-acetyloxyphenyl)sulfanylphenyl] acetate Chemical compound C1=CC(OC(=O)C)=CC=C1SC1=CC=C(OC(C)=O)C=C1 FZLFICOUTCHSSD-UHFFFAOYSA-N 0.000 claims 1
- LNYKAPKTSVPQDN-UHFFFAOYSA-N [4-[2-(4-acetyloxy-3-methylphenyl)propan-2-yl]-2-methylphenyl] acetate Chemical compound C1=C(C)C(OC(=O)C)=CC=C1C(C)(C)C1=CC=C(OC(C)=O)C(C)=C1 LNYKAPKTSVPQDN-UHFFFAOYSA-N 0.000 claims 1
- NSNHONPMCQYMNT-UHFFFAOYSA-N [4-[2-(4-acetyloxyphenyl)propan-2-yl]phenyl] acetate Chemical compound C1=CC(OC(=O)C)=CC=C1C(C)(C)C1=CC=C(OC(C)=O)C=C1 NSNHONPMCQYMNT-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
- C07D209/44—Iso-indoles; Hydrogenated iso-indoles
- C07D209/48—Iso-indoles; Hydrogenated iso-indoles with oxygen atoms in positions 1 and 3, e.g. phthalimide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/60—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from the reaction of a mixture of hydroxy carboxylic acids, polycarboxylic acids and polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
- C08G63/685—Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/16—Polyester-imides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Polyesters Or Polycarbonates (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (16)
- 하기 일반식(I),(II),(III) 및 (IV)를 가지는 반복 단위로 실질적으로 구성되며, 60℃에서 농도 0.2g/dl로 p-클로로페놀에서 측정된 바의 적어도 0.2dl/g의 환산점도를 가짐을 특징으로 하는 폴리에스테르 중합체.1내지 10의 값을 가지는 수를 각각 표시하며, R4는 각각 탄소수 1내지 5의 알킬기임)이며, R2및 R3는 각각 수소원자, 할로겐원자, 탄소수 1내지 5의 알킬기, 또는 페닐기이며 R2및 R3는 서로 동일하거나 다른기임] 이고, R1은 수소원자, 할로겐 원자 또는 탄소수 1내지 5의 알킬기이다.
- 제1항에 있어서, Ar1이임을 특징으로 하는 폴리에스테르 중합체.
- 제1항에 있어서, Ar2이임을 특징으로 하는 폴리에스테르 중합체.
- 제1항에 있어서,Ar2가 임을 특징으로 하는 폴리에스테르 중합체.
- 제1항에 있어서, 일반식(I)의 반복단위의 몰분율이 5 내지 50%, 일반식(II)의 반복단위의 몰분율이 5내지 70%, 일반식(III)의 반복단위의 몰분율이 5내지 50% 그리고 일반식(IV)의 반복단위의 몰분율이 5내지 50%임을 특징으로 하는 폴리에스테르 중합체.
- 폴리에틸렌테레프탈레이트(A), 하기 일반식(II´)의 아실옥시-방향족 카르복실산(B), 하기 일반식(III´)의 에스테르 및 하기 일반식(IV´)의 디이미드-디카르복실산을 반응시킴을 특징으로 하는 폴리에스테르 중합체의 제조방법.R5-CO-O-Ar1-COOH (Ⅱ-1)RCOO-Ar2-COOR (Ⅲ′)상기식에서, R5는 탄소수 1 내지 3의 알킬기이고, Ar1은 또는이고,R은 각각 탄소수 1 내지 20의 알킬기이고,Ar2는할로겐으로 치환된 이들의 기 또는[여기서, X는 -O-, -S-, -SO2-, -CO-, -O(CH2)nO-,(여기서 n은 1내지 10의 값을 가지는 수를 각각 표시하고, R4는 각각 탄소수 1 내지 5의 알킬기 임)이며, R2는 R3는 각각 수소원자, 할로겐원자, 탄소수 1 내지 5의 알킬기, 또는 페닐기이며 R2및 R3는 서로 동일하거나 다른 기임] 이고, R1은 수소원자, 할로겐원자 또는 탄소수 1 내지 5의 알킬기이다.
- 제6항에 있어서, 폴리에틸렌테레프탈레이트(A)는 60℃에서 농도 0.2g/dl로 p-폴로로페놀에서 측정된 바의 환산점도[ηsp/c]가 0.1내지 1.0dl/g임을 특징으로 하는 폴리에스테르 중합체의 제조방법.
- 제6항에 있어서, 아실옥시-방향족 카르복실산(B)는 하기 일반식으로 표시됨을 특징으로 하는 폴리에스테르 중합체의 제조방법.상기식에서 R5는 상기 정의된 바와 같다.
- 제8항에 있어서, 아실옥시-방향족 카르복실산(B)이 p-아세톡시벤조산 또는 4-(4´아세톡시페닐)벤조산 임을 특징으로 하는 폴리에스테르 중합체의 제조방법.
- 제6항에 있어서, 에스테르(C)가 4,4´-디아세톡시비페닐 또는 p-페닐렌디아세테이트임을 특징으로 하는 폴리에스테르 중합체의 제조방법.
- 제6항에 있어서, 에스테르(C)가 비스(4-아세톡시페닐)에테르, 비스(4-아세톡시페닐)술파이드, 2, 2-비스(4-아시톡시페닐)프로판 또는 2,2-비스(3-메틸-4-아세톡시페닐)프로판 임을 특징으로 하는 폴리에스테르 중합체의 제조방법.
- 제6항에 있어서, 디이미드-디카르복실산(D)이 1,4-비스(4´-카르복시프탈이미도)-2-클로로벤젠또는 1,4-비스(4´-카르복시프탈이미도)-2-메틸벤젠 임을 특징으로 하는 폴리에스테르 중합체의 제조방법.
- 제6항에 있어서, 제1단계로 폴리에틸렌테레프탈레이트(A), 아실옥시-방향족 카르복실산(B),에스테르(C) 및 디이미드-디카르복실산(D)를 1내지 2시간 동안 대기압으로 250℃내지 300℃의 온도에서 반응시킴과, 제2단계에서 연속하여 1 내지 5시간동안 감압하에 250℃ 내지 320℃의 온도에서 반응시킴을 특징으로 하는 폴리에스테르 중합체의 제조방법.
- 하기 일반식(IV´)로 표시됨을 특징으로 하는 디이미드-디카르복실산.상기식에서 R1은 수소원자,할로겐 원자 또는 탄소수 1내지 5의 알킬기이다.
- 1,4-비스(4´-카르복시프탈이미도)-2-클로로벤젠.
- 1,4-비스(4´-카르복시프탈이미도)-2-메틸벤젠.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15796386 | 1986-07-07 | ||
| JP157963 | 1986-07-07 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR880001715A true KR880001715A (ko) | 1988-04-26 |
| KR910000424B1 KR910000424B1 (ko) | 1991-01-25 |
Family
ID=15661273
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019870007276A KR910000424B1 (ko) | 1986-07-07 | 1987-07-07 | 신규 폴리에스테르 중합체 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4749775A (ko) |
| EP (1) | EP0252415B1 (ko) |
| JP (1) | JPS63152625A (ko) |
| KR (1) | KR910000424B1 (ko) |
| DE (1) | DE3789994T2 (ko) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2509259B2 (ja) * | 1987-11-17 | 1996-06-19 | 出光石油化学株式会社 | 芳香族ポリエステルの製造方法 |
| US5003030A (en) * | 1988-05-17 | 1991-03-26 | Idemitsu Petrochemical Co., Ltd. | Thermoplastic wholly aromatic copolyimide ester and process for producing the same |
| US4892912A (en) * | 1988-11-08 | 1990-01-09 | Idemitsu Petrochemical Co., Ltd. | Process for producing aromatic polyester |
| US4944880A (en) * | 1989-10-16 | 1990-07-31 | Exxon Research And Engineering Company | Polyimide/aliphatic polyester copolymers |
| AT397799B (de) * | 1991-08-13 | 1994-06-27 | Chemie Linz Gmbh | Benzophenoniminodiimide und daraus abgeleitete thermostabile polymere |
| US5453515A (en) * | 1991-08-13 | 1995-09-26 | Chemie Linz Gesellschaft M.B.H. | Benzophenone iminodiimides and heat-stable polymers derived therefrom |
| DE4129325A1 (de) * | 1991-09-04 | 1993-03-11 | Chemie Linz Deutschland | Benzophenoniminodiimide und daraus abgeleitete thermostabile polymere |
| AT398977B (de) * | 1992-11-10 | 1995-02-27 | Chemie Linz Gmbh | Thermoplastische polyesterimide aus trimellitsäure, propandiphenol und einem aromatischen diamin mit verbesserten mechanischen eigenschaften, ihre herstellung und verwendung |
| US7238770B2 (en) | 2004-01-29 | 2007-07-03 | Wellman, Inc. | Methods of making imide-modified polyester resins |
| BRPI0507205A (pt) * | 2004-01-29 | 2007-06-12 | Wellman Inc | resinas de poliéster modificadas com imida e métodos para fazer a mesma |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4145351A (en) * | 1961-11-02 | 1979-03-20 | Dr. Beck & Co. Ag | Diimidodicarboxylic acids |
| US4146702A (en) * | 1977-08-08 | 1979-03-27 | Eastman Kodak Company | Liquid crystal copolyesters prepared from an aromatic dicarboxylic acid, a substituted hydroquinone and a m-acyloxybenzoic acid |
| US4265802A (en) * | 1980-01-04 | 1981-05-05 | Celanese Corporation | Polyester of para-hydroxy benzoic acid, 1,4-bis(para-carboxyphenoxy) benzene, aromatic diol and aromatic diacid capable of undergoing melt processing |
| US4362861A (en) * | 1980-12-23 | 1982-12-07 | Schenectady Chemicals, Inc. | Polyesterimide |
| US4412058A (en) * | 1982-06-02 | 1983-10-25 | E. I. Du Pont De Nemours And Company | Aromatic polyesters and high strength filaments thereof |
| JPS6119627A (ja) * | 1984-07-06 | 1986-01-28 | Mitsubishi Chem Ind Ltd | 全芳香族ポリエステル |
| US4556705A (en) * | 1984-10-26 | 1985-12-03 | General Electric Company | Thermoplastic polyetherimide ester elastomers |
-
1986
- 1986-11-13 JP JP61268756A patent/JPS63152625A/ja active Pending
-
1987
- 1987-06-30 EP EP87109410A patent/EP0252415B1/en not_active Expired - Lifetime
- 1987-06-30 DE DE3789994T patent/DE3789994T2/de not_active Expired - Fee Related
- 1987-07-07 US US07/070,553 patent/US4749775A/en not_active Expired - Fee Related
- 1987-07-07 KR KR1019870007276A patent/KR910000424B1/ko not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| JPS63152625A (ja) | 1988-06-25 |
| EP0252415A3 (en) | 1990-08-01 |
| DE3789994D1 (de) | 1994-07-14 |
| EP0252415B1 (en) | 1994-06-08 |
| DE3789994T2 (de) | 1995-01-12 |
| EP0252415A2 (en) | 1988-01-13 |
| KR910000424B1 (ko) | 1991-01-25 |
| US4749775A (en) | 1988-06-07 |
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