KR880000454A - [헥사키스(펜텐니트릴로)니켈 II]비스-μ-(시아노)비스(트리페닐보란))(I)], 이의 제조방법 및 용도 - Google Patents

[헥사키스(펜텐니트릴로)니켈 II]비스-μ-(시아노)비스(트리페닐보란))(I)], 이의 제조방법 및 용도 Download PDF

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Publication number
KR880000454A
KR880000454A KR870005611A KR870005611A KR880000454A KR 880000454 A KR880000454 A KR 880000454A KR 870005611 A KR870005611 A KR 870005611A KR 870005611 A KR870005611 A KR 870005611A KR 880000454 A KR880000454 A KR 880000454A
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KR
South Korea
Prior art keywords
bis
triphenylborane
pentenenitrilo
hexakis
cyano
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KR870005611A
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English (en)
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KR950002865B1 (ko
Inventor
폴 베티 리챠드
죠셉 오스터마이어 죤
Original Assignee
도날드 에이 · 호에스
이 · 아이 · 듀퐁 드 네모어 앤드 캄파니
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Application filed by 도날드 에이 · 호에스, 이 · 아이 · 듀퐁 드 네모어 앤드 캄파니 filed Critical 도날드 에이 · 호에스
Publication of KR880000454A publication Critical patent/KR880000454A/ko
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Publication of KR950002865B1 publication Critical patent/KR950002865B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04—Nickel compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/02—Preparation of carboxylic acid nitriles by reaction of nitrogen oxide with organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/08—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
    • C07C253/10—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds to compounds containing carbon-to-carbon double bonds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

〔헥사키스(펜텐니트릴로)니켈 Ⅱ〕비스-μ-(시아노)비스(트리페닐보란))(Ⅰ)〕, 이의 제조방법 및 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제 1 도는 본 발명 화합물의 적외선 스펙트럼에 관한 도이다.
제 2 도는 단일 결정 X-선 분석에 의한 본 발명의 화합물의 양이온을 나타낸 도이다.
제 3 도는 단일 결정 X-선 분석에 의한 본 발명의 화합물의 음이온을 나타낸 도이다.

Claims (4)

  1. 〔헥사키스(펜텐니트릴로)니켈(Ⅱ)〕비스〔μ-(시아노)비스(트리페닐보란) (Ⅰ).
  2. 펜텐니트릴을 함유하는 혼합물과 Ni(NC(CH2)4(N)(NCBφ3)2및 트리페닐보란으로 이루어진 부류 중 하나를 반응시켜〔헥사키스(펜텐니트릴로)니켈(Ⅱ)〕비스〔μ-(시아노) 비스(트리페닐보란)(Ⅰ)〕을 제조하는 방법.
  3. 제 2 항에 있어서, 상기 부류 중 하나가 트리페닐보란이고 혼합물에 역시 Ni(CH2CH=CHCH2CH)4(NCBφ3)2가 함유된 방법.
  4. 제 2 항에 있어서, 상기 부류 중 하나가 트리페닐보란이고 혼합물에 역시 시안화나트륨 및 니켈디메로로 디메톡시에탄이 함유된 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870005611A 1986-06-04 1987-06-03 [헥사키스(펜텐니트릴로)니켈(II)]비스-[μ-(시아노)비스(트리페닐보란)(I)] 및 이의 제조방법 KR950002865B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/870,739 US4749801A (en) 1986-06-04 1986-06-04 [Hexakis(pentenenitrilo)nickel II]bis-[μ-(cyano) bis(triphenylborane) (I)], its method of preparation and its use
US870739 1986-06-04

Publications (2)

Publication Number Publication Date
KR880000454A true KR880000454A (ko) 1988-03-25
KR950002865B1 KR950002865B1 (ko) 1995-03-27

Family

ID=25355988

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019870005611A KR950002865B1 (ko) 1986-06-04 1987-06-03 [헥사키스(펜텐니트릴로)니켈(II)]비스-[μ-(시아노)비스(트리페닐보란)(I)] 및 이의 제조방법

Country Status (7)

Country Link
US (1) US4749801A (ko)
EP (1) EP0248643B1 (ko)
JP (1) JPH0813832B2 (ko)
KR (1) KR950002865B1 (ko)
CA (1) CA1274245A (ko)
DE (1) DE3784378T2 (ko)
SG (1) SG62693G (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100466683B1 (ko) * 2001-12-12 2005-01-15 한국효소 주식회사 곡물주정용 조 글루코 아미라제의 제조방법

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CA1324613C (en) * 1988-03-31 1993-11-23 Ronald J. Mckinney Promoter synergism in pentenenitrile hydrocyanation
US4990645A (en) * 1990-06-27 1991-02-05 E. I. Du Pont De Nemours And Company Hydrocyanation process
US5382697A (en) * 1994-06-23 1995-01-17 E. I. Du Pont De Nemours And Company Preparation of triarylborane
BR9908336A (pt) * 1998-02-20 2000-10-10 Dow Chemical Co Composto ativador de catalisador compreendendo ânions expandidos, composição de catalisador para polimerização de &-olefina e processo de polimerização.
FR2849027B1 (fr) * 2002-12-23 2005-01-21 Rhodia Polyamide Intermediates Procede de synthese de composes comprenant des fonctions nitriles a partir de composes a insaturations ethyleniques
FR2850966B1 (fr) * 2003-02-10 2005-03-18 Rhodia Polyamide Intermediates Procede de fabrication de composes dinitriles
FR2854891B1 (fr) 2003-05-12 2006-07-07 Rhodia Polyamide Intermediates Procede de preparation de dinitriles
FR2854892B1 (fr) * 2003-05-12 2005-06-24 Rhodia Polyamide Intermediates Procede de fabrication de dinitriles
EP1948591A1 (en) * 2005-10-18 2008-07-30 INVISTA Technologies S.à.r.l. Process of making 3-aminopentanenitrile
US7629484B2 (en) * 2006-03-17 2009-12-08 Invista North America S.A.R.L. Method for the purification of triorganophosphites by treatment with a basic additive
US7709674B2 (en) * 2006-07-14 2010-05-04 Invista North America S.A R.L Hydrocyanation process with reduced yield losses
US7880028B2 (en) * 2006-07-14 2011-02-01 Invista North America S.A R.L. Process for making 3-pentenenitrile by hydrocyanation of butadiene
US7919646B2 (en) 2006-07-14 2011-04-05 Invista North America S.A R.L. Hydrocyanation of 2-pentenenitrile
WO2009075692A2 (en) 2007-05-14 2009-06-18 Invista Technologies S.A.R.L. High efficiency reactor and process
WO2008157218A1 (en) * 2007-06-13 2008-12-24 Invista Technologies S.A.R.L. Process for improving adiponitrile quality
US7977502B2 (en) * 2008-01-15 2011-07-12 Invista North America S.A R.L. Process for making and refining 3-pentenenitrile, and for refining 2-methyl-3-butenenitrile
CN101918356B (zh) * 2008-01-15 2013-09-25 因温斯特技术公司 戊烯腈的氢氰化
JP2011515411A (ja) * 2008-03-19 2011-05-19 インビスタ テクノロジーズ エス エイ アール エル シクロドデカトリエンの製造方法およびラウロラクトンの製造方法
US8247621B2 (en) * 2008-10-14 2012-08-21 Invista North America S.A.R.L. Process for making 2-secondary-alkyl-4,5-di-(normal-alkyl)phenols
KR20120047251A (ko) 2009-08-07 2012-05-11 인비스타 테크놀러지스 에스.에이.알.엘. 디에스테르를 형성하기 위한 수소화 및 에스테르화
US8815186B2 (en) 2009-12-18 2014-08-26 Invista North America S.A.R.L. Nickel compositions for preparing nickel metal and nickel complexes
EP2614070B1 (en) 2010-09-07 2017-07-26 Invista Technologies S.à r.l. Nickel compositions for preparing nickel metal and nickel complexes
KR20140039268A (ko) 2011-06-10 2014-04-01 인비스타 테크놀러지스 에스.에이 알.엘. 유동층 반응기를 포함하는 하소 및 환원 방법
CN103732323B (zh) 2011-06-10 2016-09-14 因温斯特技术公司 用于催化镍-配体配合物的制备的镍形式

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US3538142A (en) * 1969-08-04 1970-11-03 Du Pont Process of isomerizing 3-pentenenitrile to 4-pentenenitrile
US3676475A (en) * 1970-07-06 1972-07-11 Du Pont Hydrides of nickel coordination compounds
US3846461A (en) * 1972-10-25 1974-11-05 Du Pont Process of preparing a zerovalent nickel complex with organic phosphorus compounds
US4082811A (en) * 1977-02-23 1978-04-04 E. I. Du Pont De Nemours And Company Recovery of metal and triarylborane catalyst components from olefin hydrocyanation residue
US4347193A (en) * 1979-04-20 1982-08-31 E. I. Du Pont De Nemours And Company Aryl borane complexes
US4328172A (en) * 1981-02-24 1982-05-04 E. I. Du Pont De Nemours And Company Hydrocyanation of olefins
US4394321A (en) * 1981-11-12 1983-07-19 E. I. Du Pont De Nemours And Company Triarylboraneisocy ano metal compounds
US4416824A (en) * 1981-12-21 1983-11-22 E. I. Du Pont De Nemours & Co. Recovery of triarylboranes by forming boron-containing metal compounds

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100466683B1 (ko) * 2001-12-12 2005-01-15 한국효소 주식회사 곡물주정용 조 글루코 아미라제의 제조방법

Also Published As

Publication number Publication date
EP0248643B1 (en) 1993-03-03
SG62693G (en) 1993-08-06
US4749801A (en) 1988-06-07
KR950002865B1 (ko) 1995-03-27
EP0248643A3 (en) 1990-02-07
EP0248643A2 (en) 1987-12-09
DE3784378D1 (de) 1993-04-08
JPH0813832B2 (ja) 1996-02-14
JPS62294691A (ja) 1987-12-22
DE3784378T2 (de) 1993-09-02
CA1274245A (en) 1990-09-18

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