KR870011320A - 폴리아미드 섬유 재료의 광화학적 안정화 방법 - Google Patents

폴리아미드 섬유 재료의 광화학적 안정화 방법 Download PDF

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KR870011320A
KR870011320A KR870004351A KR870004351A KR870011320A KR 870011320 A KR870011320 A KR 870011320A KR 870004351 A KR870004351 A KR 870004351A KR 870004351 A KR870004351 A KR 870004351A KR 870011320 A KR870011320 A KR 870011320A
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hydrogen
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alkoxy
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라이네르트 게르하르트
부르데스카 쿠르트
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아놀드 자일러, 에른스트 알테르
시바-가이기 에이지
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Abstract

내용 없음

Description

폴리아미드 섬유 재료의 광화학적 안정화 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (19)

  1. A) 유기 구리 착화합물.
    B) 광안정화제 및 경우에 따라
    C) 산화방지제의 혼합물로 섬유 재료를 처리함을 특징으로 하여, 염색되지 않은 폴리아미드섬유 재료 및 염색된 폴리아미드 섬유 재료 또는 다른 섬유 재료와 이들의 혼합물을 광화학적으로 안정화시키는 방법.
  2. 제1항에 있어서, 사용되는 성분 A)가 방향족 알데하이드 또는 케톤의 비스아조메틴, 아실하이드라존, 세미카바존 또는 티오세미카바존, 또는 옥사임의 비-염색 구리 착화물인 방법.
  3. 제1항 또는 제2항에 있어서, 사용되는 성분 A)가 일반식 (1)의 구리 착화물인 방법.
    상기식에서,
    R는 수소 또는 치환되거나 비치환된 알킬 또는 아릴 라디칼이고,
    Q는 치환되거나 비치환된 알킬렌, 사이클로알킬엔 또는 아릴렌 라디칼이며,
    n는 0,1,2 또는 3이고,
    벤젠 환 A 및 B는 서로 독립적으로 치환될 수 있다.
  4. 제1항 내지 제3중 어느 한 항에 있어서, 사용되는 성분 A)가 일반식(2)의 비스아조메틴 화합물인 방법.
    상기식에서,
    R′는 수소 또는 C1-C3-알킬이고,
    R1, R2, R3및 R4는 각각 수소, 할로겐, 하이드록시, 하이드록시알킬, 알킬, 알콕시, 알콕시알콕시, 알콕시알콕시알콕시, 카복시메톡시, 알킬아미노, 디알킬아미노, -SC2NH2, -SC2NHR0또는 -SO2N(RO)2(여기서, R0는 알킬 또는 알콕시알킬이고, 알킬 또는 알콕시는 각각 1 내지 4개의 탄소원자를 갖는 그룹이다)이거나,
    R1및 R2또는 R2및 R3또는 R3및 R4는 이들이 결합되어 있는 탄소원자와 함께 벤젠 라디칼을 형성하고,
    Q1는 C2-C4-알킬렌 라디칼, 산소 또는 질소에 의해 차단된 C2-C|8-알킬렌 라디칼, 페닐렌 라디칼 또는가교(여기서, X 및 Y는 각각 C1-C4-알킬 또는 방향족 라디칼이거나, X 및 Y는 이들이 결합되어 있는 탄소원자와 함께 5 내지 7개의 탄소원자를 갖는 지환족 라디칼을 형성한다)이다.
  5. 제1항 또는 제2항에 있어서, 사용되는 성분 A)가 일반식(3)의 방향족 알데하이드 또는 케톤의 아실하이드라존인 방법.
    상기식에서,
    R1및 R5는 서로 독립적으로 수소 또는 치환되거나 비치환된 알킬 또는 아릴 라디칼이다.
  6. 제1항 또는 제2항에 있어서, 사용되는 성분 A)가 일반식 (3a)의 세미카바존 또는 티오세미카바존인 방법.
    상기식에서,
    R1는 수소 또는 치환되거나 비치환된 알킬 또는 아릴라디칼이고,
    Z2는 산소 또는 황이다.
  7. 제1항 또는 제2항에 있엉서, 사용되는 성분 A)가 일반식(4)의 페놀의 구리 화합물인 방법.
    상기식에서,
    R는 수소, 하이드록시, 알킬 또는 사이클로알킬이고, 환 A는 추가로 치환될 수 있다.
  8. 제4항에 있어서, 사용되는 성분 A)가 일반식(5)의 비스아조메틴 착화합물일 방법.
    상기식에서,
    R6, R7, R8및 R9는 각각 수소, 하이드록시, 염소, 브롬, 메틸, 3급-부틸, 메톡시, 메톡시에톡시, 에톡시에톡시에톡시 또는 디에틸아미노이고, R7은 또한 설포일 수도 있으며,
    X1는 수소, 메틸, 에틸 또는 페닐이고,
    Y1는 수소이거나,
    R6및 R7은 함께 벤젠 라디칼을 형성하거나
    X1및 Y1은 함께 사이클로헥실렌 라디칼을 형성한다.
  9. 제8항에 있어서, 사용되는 성분 A)가 일반식 (6)의 비스아조메틴 착화합물인 방법.
    상기식에서,
    R10, R11및 R13는 각각 수소, 염소, 브롬, 메틸 또는 메톡시이고, R|11는 또한 설포일 수도 있거나,
    R10및 R11은 함께 벤젠 환을 형성하고,
    R12는 수소 또는 하이드록시이며,
    X2는 수소, 메틸, 에틸 또는 페닐이다.
  10. 제1항 내지 제9항중 어느 한 항에 있어서, 사용되는 성분 B)가 일반식 (7)의 2-하이드록시벤조 페논인 방법.
    상기식에서,
    R1는 수소, 하이드록시, C1-C14-알콕시 또는 펜옥시이고,
    R2는 수소, 할로겐, C1-C4-알킬 또는 설포이며,
    R2는 수소, 하이드록시 또는 C1-C4-알콕시이고
    R4는 수소, 하이드록시 또는 카복시이다.
  11. 제1항 내지 제9항중 어느 한 항에 있어서, 사용되는 성분 B)가 일반식(8)의 2-(2′-하이드록시 페닐)-벤조트리아졸 또는 이의 염인 방법.
    상기식에서,
    R1는 수소, C1-C12-알킬, 염소, C5-C6-사이클로알킬, C7-C9-페닐알킬 또는 설포이고,
    R2는 염소, C1-C4-알킬, C1-C4-알콕시, 염소, 하이드록시 또는 설포이며,
    R3는 C1-C12-알킬, C1-C4-알콕시, 페닐, (C1-C8-알킬)-페닐, C5-C6-사이클로알킬,
    C2-C9-알콕시카보닐, 염소, 카복시에틸 또는 C7-C9-페닐알킬 또는 설포이고,
    R4는 수소, 염소, C1-C4-알킬, C1-C4-알콕시, C2-C9-알콕시카보닐, 카복시 또는 설포이며,
    R5는 수소 염소이다.
  12. 제1항 내지 제9항중 어느 한 항에 있어서, 사용되는 성분 B)가 입체 장애 아민 종류의 화합물인 방법.
  13. 제12항에있어서, 사용되는 입체 장애 아민이 분자내에 일반식(9)의 그룹을 하나 이상 함유하는 2,2,6,6,-테트라알킬피페리딘 유도체인 방법.
    상기식에서,
    R는 수소 또는 메틸이다.
  14. 제1항 내지 제9항중 어느 한 항에 있어서, 사용되는 성분 B)가 일반식(12)의 2-(2′-하이드록시페닐)-s-트리아진 또는 이의 염인 방법.
    상기식에서,
    R는 수소, 할로겐, C1-C4-알킬 또는 설포이고,
    R1는 수소, C1-C4-알킬, C1-C4-알콕시 또는 하이드록시이며,
    R2는 수소 또는 설포이고
    R3및 R4는 서로 독립적으로 C1-C4-알킬, C1-C4-알콕시 C5-C6-사이클로알킬, 페닐, 또는 C1-C4-알킬 및 하이드록시에 의해 치환된 페닐이다.
  15. 제1항 내지 제9항중 어느 한 항에 있어서, 사용되는 성분 B)가 일반식(12a)의 s-트리아진 화합물인 방법.
    상기식에서,
    치환체 R1, R2및 R3중 하나 이상이 일반식(12b)의 라디칼
    [여기서,
    M는 나트륨, 칼륨, 칼슘, 마그네슘, 암모늄 도는 테트라-C1-C4-알킬암모늄이고 m는 1 또는 2이다]이고,
    나머지 치환체는 서로 독립적으로 C1-C12-알킬, 페닐이거나, 산소, 황, 이미노 또는 C1-C4-알킬이미노를 통해 트리아지닐 라디칼에 결합된 C1-C12-알킬 또는 페닐이다.
  16. 제1항 내지 제15항중 어느 한 항에 있어서, 사용되는 성분 C)가 일반식(13)의 하이드록시페닐프로피오네이트인 방법.
    상기식에서,
    n는 1 내지 4의 정수이고,
    A는 C1-C24-알콕, 가교성분 -O(CH2)6O-, -O(CH2)|2O(CH2)2O-, -O(CH2)2O(CH2)2O(CH|2)2O-, -NH-(CH2)26-NH- 또는 -O(CH2)2-S-(CH2)2O-이거나 라디칼 -(CH2O)4-C이다.
  17. 제1항 내지 제15항중 어느 한 항에 있어서, 사용되는 성분C)가 일반식(14)의 페닐알킬포스포네이트인 방법.
    상기식에서,
    R는 하이드록시, 페닐, 펜옥시, C1-C18-알킬펜옥시, C1-C24-알킬티오 또는 C1-C24-알콕시이고,
    R1는 펜옥시, C1-C18-알킬펜옥시, C1-C24-알킬티오, C1-C24-알콕시이며,
    R2및 R3는 서로 독립적으로 C1-C18-알킬이고,
    R4는 수소 또는 C2-C4-알킬이며,
    n는 0,1,2, 또는 3이다.
  18. A)는 0.005 내지 0.20 중량%의 유기 구리착화합물.
    B) 0.05 내지 3중량%, 바람직하게는 0.1 내지 1중량%의 광안정화제 및, 경우에 따라,
    C) 0.05 내지 3중량%, 바람직하게는 0.1 내지 1중량%의 산화방지제를 함유하는, 염색되지 않은 폴리아미드 섬유재료 및 염색된 폴리아미드 섬유재료 또는 다른 섬유재료와 이들의 혼합물의 광화학적 안정화용 시약.
  19. 제1항 내지 제16항중 어느 한 항에 따른 방법으로 처리한 폴리아미드 섬유재료, 또는 다른 섬유재료와 이의 혼합물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870004351A 1986-05-05 1987-05-04 폴리아미드 섬유 재료의 광화학적 안정화 방법 KR940011787B1 (ko)

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