KR870004129A - Detergent Ingredients and Manufacturing Method - Google Patents

Detergent Ingredients and Manufacturing Method Download PDF

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Publication number
KR870004129A
KR870004129A KR1019860008663A KR860008663A KR870004129A KR 870004129 A KR870004129 A KR 870004129A KR 1019860008663 A KR1019860008663 A KR 1019860008663A KR 860008663 A KR860008663 A KR 860008663A KR 870004129 A KR870004129 A KR 870004129A
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South Korea
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detergent
soap
fatty acid
mixture
rosin
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KR1019860008663A
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Korean (ko)
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KR900008342B1 (en
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리차드 노만 에이몬드 필립
티모디 하이트 앤드류
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에이취. 반 발렌
유니레버 엔. 브이
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Publication of KR900008342B1 publication Critical patent/KR900008342B1/en

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D15/00Manufacture of resin soap or soaps derived from naphthenic acids; Compositions
    • C11D15/04Compositions containing resin soap or soap derived from naphthenic acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00Compositions of detergents, not provided for by one single preceding group
    • C11D10/04Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/042Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2079Monocarboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/123Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Manufacturing & Machinery (AREA)
  • Detergent Compositions (AREA)

Abstract

내용 없음No content

Description

세제성분 및 그 제조방법Detergent ingredients and preparation method thereof

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (25)

비누 및 음이온성 합성세제 및 또는 로진에서 유도해낸 것으로서 31옹스트롬 이하의 X-선 회절 긴스페이싱 d0를 갖는 세제성분.Detergent component having an X-ray diffraction long spacing d 0 of 31 angstroms or less derived from soap and anionic synthetic detergents and / or rosin. 청구범위 1항에 있어서, 비누 대음이온성 합성세제 및 또는 로진의 함유비는 1:2이상인 것을 특징으로 하는 세제성분.The detergent component according to claim 1, wherein the content of the soap large anionic synthetic detergent and / or rosin is 1: 2 or more. 청구범위 1항 또는 2항에 있어서 비누 대음이온성세제 및 또는 로진의 함유비는 8:1이하인 것을 특징으로 하는 세제성분.The detergent component according to claim 1 or 2, wherein the content of the soap anionic detergent and / or rosin is 8: 1 or less. 청구범위 3항에 있어서, 비누 대음이온성세제 및 또는 로진의 함유비는 5:1이하인 것을 특징으로 하는 세제성분.The detergent component according to claim 3, wherein the content of the soap anionic detergent and / or rosin is 5: 1 or less. 이상의 청구범위 중 어느 하나에 있어서 비누 대음이온성세제 및 또는 로진의 함유비는 약 2:1인 것을 특징으로 하는 세제조성물.The detergent composition according to any one of the preceding claims, wherein the content of soap anionic detergent and / or rosin is about 2: 1. 이상의 청구범위 중 어느 하나에 있어서, 비누 내의 지방산 함량부분은 최소한 16개의 탄소원자를 가진 포화지방산 최소한 20중량%인 것을 특징으로 하는 세제조성물.The detergent composition according to any of the preceding claims, wherein the fatty acid content portion of the soap is at least 20% by weight of saturated fatty acids having at least 16 carbon atoms. 청구범위 6항에 있어서, 상기 비누는 최소한 16개의 탄소원자를 가진 포화지방산부분 최소한 30중량%를 함유하는 것을 특징으로 하는 세제조성물.7. The detergent composition according to claim 6, wherein the soap contains at least 30% by weight of saturated fatty acid moieties having at least 16 carbon atoms. 이상의 청구범위 중 어느 하나에 있어서, 상기 비누는 탤로우, 종려기름, 수소화반응시킨 트리글리세라이드기름, 수소화반응시킨 지방산, 분별화 트리글리세라이드 기름, 분별화 지방산 및 그 혼합물들로 부터 유도해낸 것임을 특징으로 하는 세제조성물.The method according to any one of the preceding claims, wherein the soap is derived from tallow, palm oil, hydrogenated triglyceride oil, hydrogenated fatty acid, fractionated triglyceride oil, fractionated fatty acid and mixtures thereof. Detergent composition. 청구범위 1항 내지 8항 중 어느 하나에 있어서, 비누 및 로진에서 유도해 냈으며, 약 27.5옹스트롬의 X선 회절긴 스페이싱 d0를 갖는 세제조성물.The detergent composition according to claim 1, which is derived from soap and rosin and has an X-ray diffraction long spacing d 0 of about 27.5 angstroms. 최소한 한가지의 산을 함유하는 혼합물을 중화시키고, (Ⅰ) 지방산 및 또는 비누와(Ⅱ)음 이온성 합성세제 및 또는 산 형태의 음이온성합성세제 및 또는 로진을 함유하며, (Ⅰ) 대 (Ⅱ)의 비는 최소한 1 : 2 이며 혼합물을 중화시키기에 필요한 최소한의 화학량적 분량에 해당하는 량의 알칼리와 혼합물을 혼합시켜 만들며, 바 형태로 제조하기에 적합한 세제성분의 제조방법.Neutralize the mixture containing at least one acid, contain (I) fatty acids and / or soaps, (II) anionic synthetic detergents and / or anionic synthetic detergents and / or rosin in acid form, (I) vs. (II) ) Is a ratio of at least 1: 2 and is made by mixing a mixture of alkali and a mixture corresponding to the minimum stoichiometric amount necessary to neutralize the mixture, and a method for preparing a detergent component suitable for preparing in a bar form. 청구범위 10항에 있어서, 상기 혼합물은 중화작용이 발생하는 동안 50 내지 150℃의 온도에 유지시키는 것을 특징으로 하는 제조 방법.The process according to claim 10, wherein the mixture is maintained at a temperature of 50 to 150 ° C. while neutralization takes place. 청구범위 10항 또는 11항에 있어서, 중화된 혼합물은 40℃ 또는 그 이하로 냉각시키는 것을 특징으로 하는 제조방법.Process according to claim 10 or 11, characterized in that the neutralized mixture is cooled to 40 ° C or below. 청구범위 12항에 있어서, 중화된 혼합물은 30초 내에 40℃ 내지 0℃사이로 냉각시키는 것을 특징으로 하는 제조방법.The method of claim 12, wherein the neutralized mixture is cooled to between 40 ° C. and 0 ° C. in 30 seconds. 청구범위 10항 내지 13항 중 하나에 있어서, 산형태의 음이온성세제는 설폰산 아릴알킬, 설폰산 아킬, 설폰산아릴, 설포호박산 디알킬, 설폰산 알파올레핀 및 그 혼합물로 구성된 군에서 선택되며, 그리고 또는 음이온성세제는 상기 산들의 염으로 구성된 군에서 선택되는 것을 특징으로 하는 제조방법.The method of claim 10, wherein the anionic detergent in acid form is selected from the group consisting of arylalkyl sulfonic acid, aryl sulfonic acid, aryl sulfonic acid, dialkyl sulfobacteric acid, sulfonic acid alphaolefin, and mixtures thereof. And or anionic detergent is selected from the group consisting of salts of the acids. 청구범위 10항 내지 제14항 중 하나에 있어서 (Ⅰ)의 지방산 부분의 함량은 최소한 16개의 탄소원자를 가진 포화지방산 최소한 20중량%인 것을 특징으로 하는 제조방법.The process according to claim 10, wherein the content of the fatty acid moiety of (I) is at least 20% by weight of saturated fatty acids having at least 16 carbon atoms. 청구범위 10항에 있어서 (Ⅰ)의 지방산 부분의 함량은 최소한 16개의 탄소원자를 가진 포화지방산 최소한 30중량%인 것을 특징으로 하는 제조방법.The process according to claim 10, wherein the content of the fatty acid moiety of (I) is at least 30% by weight of saturated fatty acids having at least 16 carbon atoms. 청구범위 10항 내지 16항 중 하나에 있어서, 지방산중 최소한 일부분은 탤로우, 종려기름, 수소화반응시킨 트리글리세라이드기름, 수소화반응시킨 지방산, 분별화트리글리세라이드 기름, 분별화지방산 및 그 혼합물로 구성된 군에서 유도해 내는 것을 특징으로 하는 제조방법.The group of claims 10-16 wherein at least a portion of the fatty acids is composed of tallow, palm oil, hydrogenated triglyceride oil, hydrogenated fatty acid, fractionated triglyceride oil, fractionated fatty acid and mixtures thereof. Manufacturing method characterized in that derived from. 청구범위 10항 내지 16항 중 하나에 있어서, 비누의 최소한 일부분은 탤로우, 종려기름, 수소화반응된 트리글리세라이드 기름, 수소화반응된 지방산, 분별화 트리글리세라이드 기름, 분별화지방산 및 그 혼합물로부터 유도해 내는 것을 특징으로 하는 제조방법.The method of claim 10, wherein at least a portion of the soap is derived from tallow, palm oil, hydrogenated triglyceride oil, hydrogenated fatty acid, fractionated triglyceride oil, fractionated fatty acid and mixtures thereof. The manufacturing method characterized by the above-mentioned. 청구범위 10항 내지 18항중 하나에 있어서, (Ⅰ) 대 (Ⅱ)의 비는 8:1이하인 것을 특징으로 하는 제조방법.Process according to one of claims 10 to 18, characterized in that the ratio of (I) to (II) is no more than 8: 1. 청구범위 19항에 있어서, 상기 비는 5:1이하인 것을 특징으로 하는 제조방법.The method of claim 19, wherein the ratio is no greater than 5: 1. 청구범위 19항에 있어서, 상기 비는 2:1이하인 것을 특징으로 하는 제조방법.20. The method of claim 19, wherein the ratio is no greater than 2: 1. 청구범위 10항 내지 21항 중 하나에 있어서 중화된 혼합물은 혼합물 대비누의 중량비 1:4이상의 비로 비누와 혼합되는 것을 특징으로 하는 제조방법.Method according to one of claims 10 to 21, characterized in that the neutralized mixture is mixed with soap in a ratio of at least 1: 4 by weight of the silk relative to the mixture. 청구범위 10항 내지 22항 중 하나에 있어서, 중화된 혼합물로 구성된 바를 성형시키는 것을 특징으로 하는 제조방법.23. A process according to any one of claims 10 to 22, characterized in that the bars are composed of neutralized mixtures. 중화된 세제성분으로서 그 제조방법은 청구범위 10항 내지 22항에 의하는 중화된 세제성분.A neutralized detergent component, the method for producing the neutralized detergent component according to claims 10 to 22. 바형태로 제조된 청구범위 24항 또는 1항 내지 9항 중 하나에 따른 중화된 세제성분의 용도.Use of a neutralized detergent component according to one of claims 24 or 1 to 9, prepared in the form of a bar. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019860008663A 1985-10-16 1986-10-16 Detergent component and process for making a detergent component KR900008342B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB85-25503 1985-10-16
GB858525503A GB8525503D0 (en) 1985-10-16 1985-10-16 Detergent component

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KR870004129A true KR870004129A (en) 1987-05-07
KR900008342B1 KR900008342B1 (en) 1990-11-15

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KR (1) KR900008342B1 (en)
BR (1) BR8605039A (en)
GB (2) GB8525503D0 (en)
IN (1) IN165628B (en)
OA (1) OA08431A (en)
TR (1) TR26586A (en)
ZA (1) ZA867819B (en)
ZW (1) ZW20686A1 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996035772A1 (en) * 1995-05-12 1996-11-14 The Procter & Gamble Company Soap-based laundry bars with improved firmness
DE19620792A1 (en) * 1996-05-23 1997-11-27 Zschimmer & Schwarz Gmbh & Co Binary mixtures for making semi synthetic toilet soaps
WO2016162344A1 (en) * 2015-04-09 2016-10-13 Akzo Nobel Chemicals International B.V. Collector composition for reverse flotation

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US2005160A (en) * 1931-11-13 1935-06-18 Procter & Gamble Process of producing high-percentage transparent soaps
GB403590A (en) * 1933-07-25 1933-12-28 Archibald Walter Keeble Improvements in and relating to the production of soap
GB432227A (en) * 1934-02-24 1935-07-23 Edward Henry Taylor Improvements in and relating to the manufacture of cold-process soaps
FR961442A (en) * 1943-07-01 1950-05-11
GB575949A (en) * 1944-02-24 1946-03-12 Walter Henry Elliott Improvements in the manufacture of soap
GB597322A (en) * 1945-08-14 1948-01-22 Unilever Ltd Improvements in the manufacture of soap bars or tablets
LU28982A1 (en) * 1947-04-09
FR969622A (en) * 1948-07-17 1950-12-22 Sinnova Ou Sadic Process for manufacturing a product having the appearance of soap and usable in sea water
GB695702A (en) * 1949-06-29 1953-08-19 Ernest Segessemann Improved tall oil treatment
LU29815A1 (en) * 1949-10-10
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GB723925A (en) * 1951-10-06 1955-02-16 Colgate Palmolive Peet Co Process for preparing all-purpose detergent compositions
NL174446C (en) * 1951-12-10 Lindemann Maschfab Gmbh BALER FOR MANUFACTURING STRAPED BALES.
GB741453A (en) * 1953-04-13 1955-12-07 Diversey Corp Improvements in or relating to detergent compositions
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NL126922C (en) * 1968-07-22 Colgate Palmolive Co
GB1324365A (en) * 1969-11-07 1973-07-25 Unilever Ltd Soap tablet production
US3734859A (en) * 1971-10-12 1973-05-22 Westvaco Corp Dicarboxylic acid soaps
GB8327617D0 (en) * 1983-10-14 1983-11-16 Unilever Plc Detergent bars

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ZW20686A1 (en) 1988-05-25
TR26586A (en) 1994-04-25
KR900008342B1 (en) 1990-11-15
GB2181739A (en) 1987-04-29
GB2181739B (en) 1989-09-13
OA08431A (en) 1988-06-30
BR8605039A (en) 1987-07-14
IN165628B (en) 1989-11-25
GB8525503D0 (en) 1985-11-20
GB8624554D0 (en) 1986-11-19
ZA867819B (en) 1988-06-29

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