KR870003693A - 알칸술포네이트 유도체와 살충제, 살비제 또는 살선충제로서 이들 유도체의 용도 - Google Patents

알칸술포네이트 유도체와 살충제, 살비제 또는 살선충제로서 이들 유도체의 용도 Download PDF

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KR870003693A
KR870003693A KR1019860008468A KR860008468A KR870003693A KR 870003693 A KR870003693 A KR 870003693A KR 1019860008468 A KR1019860008468 A KR 1019860008468A KR 860008468 A KR860008468 A KR 860008468A KR 870003693 A KR870003693 A KR 870003693A
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substituted
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halogen
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쇼이찌 가또
시즈오 시마노
다쓰미 하야오까
아끼오 마스이
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사까노 쓰네까즈
니뽕 가야꾸 가부시끼 가이샤
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Priority claimed from JP22184685A external-priority patent/JPS6281377A/ja
Priority claimed from JP61107591A external-priority patent/JPS62265264A/ja
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Publication of KR870003693A publication Critical patent/KR870003693A/ko

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Abstract

내용 없음

Description

알칸술포네이트 유도체와 살충제, 살비제 또는 살선충제로서 이드 유도체의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 다음 일반식(Ⅰ)의 화합물
    R1-S(O)x-[Ar]-O-SO2-R2(Ⅰ)
    상기식에서, Ar은 피리딘고리 ; 피리다진고리 ; 피리마딘고리 ; 피라진고리 ; 이소퀴놀린고리 또는 티아졸고리 ; 또 할로겐, C1-C4알킬, C1-C4알콕시, CF3및 니트로로 구성되는 군으로부터 선정한 1개 내지 3개의 치환기로 치환될 수 있는 이들고리이고 ; R'은 C1-C8알킬 ; 1개 내지 4개의 F, C1 또는 Br, C1-C4알콕시 또는 C1-C4알킬티오로서 치환될 수 있는 C1-C7알킬 ; 1개 내지 4개의 F, Cl 또는 메틸로 치환될 수 있는 C3-C7사이클로알킬; 1개 내지 4개의 F,Cl,Br 또는 메틸로 치환될 수 있는 C3-C6사이클로알킬메틸; 알릴; 프로파르길; 페닐 또는 벤질이고; R2는 1개내지 3개의 F 또는 Cl로 치환될 수 있는 C1-C4알킬이고 ; X는 0, 1 또는 2의 정수로서, Ar이 2-및 6-위치에서 R1-S(O)x 및 -O-SO2R2로서 치환된 피리딘고리 또 R'이 C1-C7알킬 또 이 피리딘고리가 추가로 치환되지 않거나 또는 1개 내지 3개의 할로겐으로 치환된 경우는 제외된다.
  2. 제1항에 있어서, Ar이이고 ; X가 할로겐 ; Y2가 C1-C4알킬, C1-C4알콕시, CF3또는 니트로 ; m 및 n이 0,1,2 또는 3으로 (m+n)이 0-3이고 ; R'이 F 또는 Cl로 치환된 수 있는 C3-C5알킬 ; C3-C6사이클로알킬 또는 C3-C6사이클로알킬메틸 ; R2가 CH3, CH2Cl 또는 C2H5;X가 0, 1 또는 2인 화합물.
  3. 제1항에 있어서, Ar이고 ; Z2가 수소 ; 할로겐 ; 할로겐으로 치환될 수 있는 C1-C4알킬 ; R'이 F 또는 Cl로 치환될 수 있는 C2-C5알킬 ; C3-C6사이클로알킬 또는 C3-C6사이클로알킬메틸 ; 알릴이고 ; R2가 CH3·CH2Cl 또는 C2H5; X가 0,1 또는 2인 화합물.
  4. 제2항에 있어서, Ar이이고 ; R'이 n-C3H7, 이소-C3H7, 2급-C4H9, n-C4H9이소-C4-C9사이클로펜틸 또는 사이클로프로필메틸;R2가 CH3, CH2Cl 또는 C2H5; 또 X가 0, 1 또는 2인 화합물.
  5. 제3항에 있어서, Ar이이고 ; Z2가 수소 또는 브롬 ; R1이 C2H5n-C3H7, 이소-C3H7, n-C4H9, 2급-C4H9, 이소-C4H9, -CH2CH2CH2Cl, CH2CH2CH2F, -CH2CH=CH2, 사이클로펜틸 또는 사이클로프로필메틸 ; R2가 CH3또는 CH2Cl ; 또 X가 0, 1 또는 2인 화합물.
  6. 제4항에 있어서, 다음 일반식으로 표시되는 화합물 군으로 부터 선정한 화합물.
  7. 제5항에 있어서, 다음 일반식으로 표시되는 화합물군으로부터 선정한 화합물.
  8. 유효성분으로 효과량만큼의 다음 일반식(Ⅰ)화합물과 1개 또는 그 이상의 보조제를 포함하는 살충, 살비 또는 살선충제 조성물.
    상기식에서, Ar은 피리딘고리 ; 피리다진고리 ; 피리미딘고리 ; 피라진고리 ; 이소퀴놀린고리 또는 티아졸고리 ; 또 할로겐, C1-C4알킬, C1-C4알콕시, CF3및 니트로로 구성되는 군으로부터 선정한 1개 내지 3개의 치환기로 치환될 수 있는 이들고리이고 ; R1은 C1-C8알킬 ; 1개 내지 3개의 F, Cl 또는 Br, C1-C4알콕시 또는 C1-C4알킬티오로서 치환될 수 있는 C1-C7알킬 ; 1개 내지 4개의 F, Cl 또는 메틸로서 치환될 수 있는 C3-C7사이클로알킬 ; 1개 내지 4개의 F, Cl, Br 또는 메틸로 치환될 수 있는 C3-C6사이클로알킬메틸 ; 알릴 ; 프로파르길 ; 페닐 또는 벤질이고 ; R2는 1개 내지 3개의 F 또는 Cl로 치환될 수 있는 C1-C4알킬이고 ; X는 0, 1 또는 2의 정수로서, Ar이 2- 및 6-위치에서 R1-(oO)x 및 -O-SO2R2로서 치환된 피리딘 고리 또는 R1이 C1-C7알킬 또 이 피리딘고리가 추가로 치환된지 않거나 또는 1개 내지 3개의 할로겐으로 치환된 경우는 제외한다.
  9. 해충, 진드기 또는 선충에 효과량 만큼의 다음 일반식(Ⅰ)의 화합물을 사용해서 이들 해충, 진드기 또는 선충을 사멸시키는 방법.
    상기식에서, Ar은 피리딘고리 ; 피리다진고리 ; 피리미딘고리 ; 피라진고리 ; 이소퀴놀린고리 또는 티아졸고리 ; 또 할로겐, C1-C4알킬, C1-C4알콕시, CF3및 니트로로 구성되는 군으로부터 선정한 1개 내지 3개의 치환기로 치환될 수 있는 이들고리이고 ; R1은 C1-C8알킬 : 1개 내지 3개의 F, C1 또는 Br C1-C4알콕시 또는 C1-C4알킬티오로서 치환될 수 있는 C1-C7알킬; 1개 내지 4개의 F, Cl 또는 메틸로서 치환될 수 있는 C3-C7사이클로알킬 ; 1개 내지 4개의 F,Cl, Br 또는 메틸로 치환될 수 있는 C3-C6사이클로알킬메틸 ; 알릴 ; 프로파르길 ; 페닐 또는 벤질이고 ; R2는 1개 내지 3개의 F 또는 Cl로 치환될 수 있는 C1-C4알킬이고; X는 0.1 또는 2의 정수로서 Ar이 2-및 6-위치에서 R1-S(O)x- 및 -O-SO3R2로 서치환된 피리딘고리 또는 R1이 C1-C7알킬 또 이 피리딘고리가 추가로 치한된지 않거나 또는 1개 내지 3개의 할로겐으로 치환된 경우는 제외한다.
  10. 다음 일반식(Ⅱ)의 화합물 또는 다음 일반식(Ⅱ)의 화합물을 다음 일반식(Ⅲ)의 화합물 또는 다음 일반식(Ⅳ)의 화합물과, 필요한 경우 산결합제 존재하의 비활성용매 중에서 반응시켜 다음 일반식(Ⅰ)의 화합물을 제조하는 방법.
    상기 반응식에서, Ar은 피리딘고리 ; 피리다진고리 ; 피리미딘고리 ; 피라진고리 ; 이소퀴놀린고리 또는 티아졸고리 ; 또 할로겐, C1-C4알킬, C1-C4알콕시, CF3및 니트로로 구성되는 군으로부터 선정한 1개 내지 3개의 치환기로 치환될 수 있는 이들고리이고 ; R2은 C1-C8알킬 ; 1개 내지 3개의 F, C1 또는 Br, C1-C4알콕시 또는 C1-C4알키티오로서 치환될 수 있는 C1-C7아킬 ; 1개 내지 4개의 F, Cl 또는 메틸로서 치환될 수 있는 C3-C7사이클로알킬 ; 1개 내지 4개의 F, Cl, Br 또는 메틸로 치환될 수 있는 C3-C6사이클로알킬메틸 ; 알릴 ; 프로파르길 ; 페닐 또는 벤질이고; R2는 1개 내지 3개의 F 또는 Cl로 치환될 수 있는 C1-C4알킬이고 ; X는 0, 1 또는 2의 정수로서, Ar이 2-및 6-위치에서 R1-S(O)x 및 -O-SO2R2로서 치환된 피리딘고그 또는 R1이 C1-C7알킬 또는 피리딘고리가 추가로 치환되지 않거나 또는 1개 내지 3개의 할로겐으로 치환된 경우는 제외하며, Y1은 수소, 알카리 또는 알카리토금속 ; Z1은 할로겐;또는 Z2는 수소 ; 할로겐 ; 할로겐으로 치환될 수 있는 C1-C4알킬이다.
  11. 다음 일반식(V)의 화합물 1몰을 1 내지 3몰의 산화재와 바람직하게는 0 내지 60℃에서 반응시켜서 X가 1인 다음 일반식(Ⅰ)의 화합물을 제조하거나 ; 또는 다음 일반식(Ⅵ)의 화합물 1몰을 2 또는 5몰의 산화제와 바람직하게는 15 내지 90℃에서 반응시켜서 X가 2인 다음 일반식(Ⅰ)의 화합물을 제조함을 특징으로 해서 x가 1 또는 2인 다음 일반식(Ⅰ)의 화합물을 제조하는 방법.
    상기식에서, R1,R2및 Ar은 제10항에서의 정의와 동일하다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860008468A 1985-10-07 1986-10-07 알칸술포네이트 유도체와 살충제, 살비제 또는 살선충제로서 이들 유도체의 용도 KR870003693A (ko)

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JP61107591A JPS62265264A (ja) 1986-05-13 1986-05-13 アルカンスルホネ−ト誘導体およびそれを有効成分とする殺虫、殺ダニ、殺線虫組成物
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JP2020507625A (ja) 2017-02-07 2020-03-12 オブリーク セラピューティクス アーベー ヘテロアリールスルホニル置換ピリジンおよび癌の治療におけるそれらの使用
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