KR870001869A - 산형태의 부분-중화된 강산성 양이온-교환수지의 제조방법 - Google Patents

산형태의 부분-중화된 강산성 양이온-교환수지의 제조방법 Download PDF

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Publication number
KR870001869A
KR870001869A KR1019850005825A KR850005825A KR870001869A KR 870001869 A KR870001869 A KR 870001869A KR 1019850005825 A KR1019850005825 A KR 1019850005825A KR 850005825 A KR850005825 A KR 850005825A KR 870001869 A KR870001869 A KR 870001869A
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South Korea
Prior art keywords
exchange resin
cation
acid form
strongly acidic
resin
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KR1019850005825A
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KR890003703B1 (ko
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제이·파지오 마이클
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리챠드 지·워터맨
더 다우 캐미칼 캄파니
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08—Ion-exchange resins
    • B01J31/10—Ion-exchange resins sulfonated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J47/00—Ion-exchange processes in general; Apparatus therefor
    • B01J47/016—Modification or after-treatment of ion-exchangers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B01J2231/341—1,2-additions, e.g. aldol or Knoevenagel condensations
    • B01J2231/347—1,2-additions, e.g. aldol or Knoevenagel condensations via cationic intermediates, e.g. bisphenol A type processes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Phenolic Resins Or Amino Resins (AREA)

Abstract

내용 없음.

Description

산형태의 부분-중화된 강산성 양이온-교환수지의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 양이온-교환수지를 개질된 양이온-교환수지를 생성시키기에 충분한 반응 조건하에서 물의 존재하에 N-(2-메르캅토알킬) 아미드와 접촉시킴을 특징으로 하여 수지의 양이온-교환능을 아미노 알칸티올로 부분-중화시킴으로써 개질시킨 산형태의 불용성 강산성 양이온-교환수지를 제조하는 방법.
  2. 제1항에 있어서, N-(2-메르캅토알킬) 아미드가 하기 일반식을 갖는 방법.
    상기식에서, R,Ra,Rb,Rd 및 Re는 각기 독립적으로 H, 알킬 또는 아릴이다.
  3. 제2항에 있어서, R이 탄소수 1 내지 4의 알킬그룹인 방법.
  4. 제3항에 있어서, R이 메틸 또는 에틸이고, Ra,Rb,Rd 및 Re가 H인 방법.
  5. 제1항에 있어서, 부분 중화반응을 80 내지 110℃에서 수행시키는 방법.
  6. 제1항에 있어서, 부분-중화된 수지를 아미노알칸디올 잔기를 티아졸리딘잔기로 전환시키기에 충분한 반응조건하에서 알데히드 또는 케론과 접촉시키는 추가의 단계를 포함함을 특징으로 하는 방법.
  7. 제6항에 있어서, 케톤이 아세톤인 방법.
  8. 제6항에 있어서, 아미노알칸디올 잔기를 티아졸리딘 잔기로 전환시키는 반응을 25 내지 50℃에서 수행하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019850005825A 1984-08-13 1985-08-13 산 형태의 부분-중화된 강산성 양이온-교환수지의 제조방법 KR890003703B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US639980 1984-08-13
US06/639,980 US4595704A (en) 1984-08-13 1984-08-13 Preparation of ion-exchange catalysts

Publications (2)

Publication Number Publication Date
KR870001869A true KR870001869A (ko) 1987-03-28
KR890003703B1 KR890003703B1 (ko) 1989-09-30

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KR1019850005825A KR890003703B1 (ko) 1984-08-13 1985-08-13 산 형태의 부분-중화된 강산성 양이온-교환수지의 제조방법

Country Status (9)

Country Link
US (1) US4595704A (ko)
EP (1) EP0171758B1 (ko)
JP (1) JPH0627132B2 (ko)
KR (1) KR890003703B1 (ko)
CN (1) CN1005777B (ko)
AU (1) AU576881B2 (ko)
CA (1) CA1258342A (ko)
DE (1) DE3586641T2 (ko)
IN (1) IN164959B (ko)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3619450A1 (de) * 1986-06-10 1987-12-17 Bayer Ag Mit mercaptoaminen modifizierte ionenaustauscher
US5212206A (en) * 1986-06-10 1993-05-18 Bayer Aktiengesellschaft Ion exchange modified with mercapto amines
US5284981A (en) * 1986-06-10 1994-02-08 Bayer Aktiengesellschaft Ion exchangers modified with mercapto amines
CN1034398C (zh) * 1991-09-16 1997-04-02 中国石油化工总公司 合成双酚用离子交换树脂催化剂的制取工艺
CN1080914A (zh) * 1993-02-17 1994-01-19 中国石油化工总公司 一种2,2-二(4-羟基苯基)丙烷的制造方法
EP0693957B1 (en) * 1993-02-17 1998-01-21 China Petro-Chemical Corporation A multiple stage suspended reactive stripping process and apparatus
JPH06340564A (ja) * 1993-06-01 1994-12-13 Chiyoda Corp ビスフェノールａの製造方法
JP3753455B2 (ja) * 1995-06-01 2006-03-08 三菱化学株式会社 ビスフェノールａ製造用触媒の再生方法
ATE424925T1 (de) 2000-09-19 2009-03-15 Dow Global Technologies Inc Verfahren zur herstellung eines starksauren kationenaustauscherharzes
JP4042325B2 (ja) * 2000-12-07 2008-02-06 三菱化学株式会社 アミノチオール変性スルホン酸型陽イオン交換樹脂の保存方法
US6586640B2 (en) * 2001-06-26 2003-07-01 E. I. Du Pont De Nemours And Company Decomposition of organic hydroperoxides in the presence of a particulate catalyst containing highly fluorinated polymer having sulfonic acid groups and process for the manufacture of bisphenol A
US6620939B2 (en) 2001-09-18 2003-09-16 General Electric Company Method for producing bisphenol catalysts and bisphenols
US7112702B2 (en) * 2002-12-12 2006-09-26 General Electric Company Process for the synthesis of bisphenol
US7132575B2 (en) * 2003-07-01 2006-11-07 General Electric Company Process for the synthesis of bisphenol
US8735634B2 (en) 2011-05-02 2014-05-27 Sabic Innovative Plastics Ip B.V. Promoter catalyst system with solvent purification
US9290618B2 (en) 2011-08-05 2016-03-22 Sabic Global Technologies B.V. Polycarbonate compositions having enhanced optical properties, methods of making and articles comprising the polycarbonate compositions
EP2810309A1 (en) 2012-02-03 2014-12-10 SABIC Innovative Plastics IP B.V. Light emitting diode device and method for production thereof containing conversion material chemistry
EP2820106B1 (en) 2012-02-29 2017-11-22 SABIC Global Technologies B.V. Polycarbonate compositions containing conversion material chemistry and having enhanced optical properties, methods of making and articles comprising the same
EP2819981B1 (en) 2012-02-29 2016-12-21 SABIC Global Technologies B.V. Process for producing low sulfur bisphenol a, processes for producing polycarbonate, articles made from polycarbonate
US9346949B2 (en) 2013-02-12 2016-05-24 Sabic Global Technologies B.V. High reflectance polycarbonate
WO2014066784A1 (en) 2012-10-25 2014-05-01 Sabic Innovative Plastics Ip B.V. Light emitting diode devices, method of manufacture, uses thereof
CN102936310B (zh) * 2012-11-26 2014-07-02 山东华夏神舟新材料有限公司 一种全氟离子交换树脂及其制备方法
WO2014186548A1 (en) 2013-05-16 2014-11-20 Sabic Innovative Plastics Ip B.V. Branched polycarbonate compositions having conversion material chemistry and articles thereof
US9772086B2 (en) 2013-05-29 2017-09-26 Sabic Innovative Plastics Ip B.V. Illuminating devices with color stable thermoplastic light transmitting articles
CN108602057B (zh) * 2015-12-09 2022-01-18 Ptt全球化学公共有限公司 用于生产双酚的离子交换树脂
KR20190100920A (ko) * 2016-12-30 2019-08-29 다우 글로벌 테크놀로지스 엘엘씨 촉진제와 산화방지제를 함유한 수지

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2597438A (en) * 1951-05-12 1952-05-20 Rohm & Haas Cation-exchange polymers of the sulfonic type
US2642417A (en) * 1952-05-21 1953-06-16 Dow Chemical Co Process for making anionexchange resins
BE590370A (ko) * 1959-04-29 1900-01-01
US3394089A (en) * 1964-12-02 1968-07-23 Dow Chemical Co Ion exchange catalyst for the preparation of bisphenols
US3676500A (en) * 1967-01-26 1972-07-11 Du Pont Tertiary aldehyde compounds
GB1183564A (en) * 1968-05-29 1970-03-11 Dow Chemical Co An Ion Catalyst for the Manufacture of Bisphenols
US3760006A (en) * 1970-03-06 1973-09-18 Dow Chemical Co Ion exchange catalysts for the preparation of bisphenols
US3634341A (en) * 1970-03-06 1972-01-11 Dow Chemical Co Ion exchange catalysts for the preparation of bisphenols
US3944561A (en) * 1972-07-04 1976-03-16 Givaudan Corporation 2-Methyl-2-acetyl-thiazolidine
US4115297A (en) * 1975-05-12 1978-09-19 Ici Australia Limited Thermally regenerable amphoteric ion exchangers prepared by sequential treatment of polymeric beads with two reagents of opposing acid base character
US4086274A (en) * 1975-06-23 1978-04-25 The Dow Chemical Company N-(2-mercapto-ethyl)alkanamides from H2 S and 2-H-2-oxazolines or 2-alkyl-2-oxazolines
US4303551A (en) * 1976-02-23 1981-12-01 Varen Technology Supported catalyst
US4053522A (en) * 1976-05-21 1977-10-11 Shell Oil Company Preparation of bisphenols
GB1578225A (en) * 1977-07-11 1980-11-05 Shell Int Research Preparation of bisphenols
DE2860850D1 (en) * 1977-11-09 1981-10-22 Shell Int Research Preparation of bisphenols
US4262041A (en) * 1978-02-02 1981-04-14 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Process for preparing a composite amphoteric ion exchange membrane
US4308405A (en) * 1978-07-05 1981-12-29 Shell Oil Company Preparation of bisphenols
US4239919A (en) * 1979-06-12 1980-12-16 The Dow Chemical Company Process for obtaining bisphenols
DE2931036A1 (de) * 1979-07-31 1981-02-26 Bayer Ag Katalysator fuer die herstellung von bisphenolen
US4346247A (en) * 1979-12-13 1982-08-24 General Electric Company Method and catalyst for making bisphenol
US4294995A (en) * 1979-12-13 1981-10-13 General Electric Company Method and catalyst for making bisphenol
US4424283A (en) * 1979-12-13 1984-01-03 General Electric Company Catalyst for synthesizing bisphenol and method for making same
US4330654A (en) * 1980-06-11 1982-05-18 The Dow Chemical Company Novel polymers having acid functionality
US4423252A (en) * 1980-08-07 1983-12-27 Mitsubishi Chemical Industries Limited Process for preparing bisphenols
US4396728A (en) * 1980-09-30 1983-08-02 General Electric Company Method and catalyst for making bisphenol
US4365099A (en) * 1981-05-12 1982-12-21 General Electric Company Process for the production of bisphenols
US4400555A (en) * 1981-10-06 1983-08-23 General Electric Company Ion exchange catalyzed bisphenol synethesis
US4391997A (en) * 1981-10-23 1983-07-05 General Electric Company Ion exchange catalyzed bisphenol process

Also Published As

Publication number Publication date
CN85106111A (zh) 1987-03-04
AU576881B2 (en) 1988-09-08
DE3586641D1 (de) 1992-10-22
JPH0627132B2 (ja) 1994-04-13
KR890003703B1 (ko) 1989-09-30
DE3586641T2 (de) 1993-07-01
US4595704A (en) 1986-06-17
EP0171758A2 (en) 1986-02-19
CA1258342A (en) 1989-08-08
AU4560385A (en) 1986-02-20
IN164959B (ko) 1989-07-15
CN1005777B (zh) 1989-11-15
EP0171758A3 (en) 1988-11-09
EP0171758B1 (en) 1992-09-16
JPS61118407A (ja) 1986-06-05

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