KR870001769A - 유기 인산 디티오에스테르, 그 제조방법 및 디티오에스테르를 함유하는 살충제 - Google Patents
유기 인산 디티오에스테르, 그 제조방법 및 디티오에스테르를 함유하는 살충제 Download PDFInfo
- Publication number
- KR870001769A KR870001769A KR1019860006667A KR860006667A KR870001769A KR 870001769 A KR870001769 A KR 870001769A KR 1019860006667 A KR1019860006667 A KR 1019860006667A KR 860006667 A KR860006667 A KR 860006667A KR 870001769 A KR870001769 A KR 870001769A
- Authority
- KR
- South Korea
- Prior art keywords
- group
- ethyl
- general formula
- halide
- dithioester
- Prior art date
Links
- 239000012988 Dithioester Substances 0.000 title claims 3
- 125000005022 dithioester group Chemical group 0.000 title claims 3
- 239000000575 pesticide Substances 0.000 title 1
- 238000002360 preparation method Methods 0.000 title 1
- -1 ethyl mercaptoethyl halide Chemical class 0.000 claims 6
- 238000000034 method Methods 0.000 claims 6
- 125000001544 thienyl group Chemical group 0.000 claims 4
- LFTMJBWNOFFSRW-UHFFFAOYSA-N 1,2-Butanedithiol Chemical class CCC(S)CS LFTMJBWNOFFSRW-UHFFFAOYSA-N 0.000 claims 3
- CDORMHOMZPDZQV-UHFFFAOYSA-N 5-hydroxy-1,4,2,3,5$l^{5}-dioxadithiaphospholane 5-oxide Chemical compound OP1(=O)OSSO1 CDORMHOMZPDZQV-UHFFFAOYSA-N 0.000 claims 3
- 125000004414 alkyl thio group Chemical group 0.000 claims 3
- 150000003839 salts Chemical class 0.000 claims 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 3
- 239000002253 acid Substances 0.000 claims 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 2
- 150000001340 alkali metals Chemical group 0.000 claims 2
- 125000005843 halogen group Chemical group 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- 239000004480 active ingredient Substances 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 239000002917 insecticide Substances 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/26—Oxidation products of dithiocarbamic acid derivatives, e.g. thiuram sulfides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/1651—Esters of thiophosphoric acids with hydroxyalkyl compounds with further substituents on alkyl
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
내용 없음.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (11)
- 하기 일반식 (Ⅰ)로 나타내는 유기 인산 디티오에스테르.(상기 식중 R은 저급 알킬 메트캅토기, 티오페닐기 또는 티오벤질기를 나타낸다.)
- 제 1항에 있어서, R이 SCH3, SC2H5, 으로 이루어진 군으로부터 선택된 유기 인산 디티오에스테르.
- 하기일발식 (Ⅱ)의 O-에틸·S-노르말프로필디티오인산염을 하기 일반식 (Ⅲ)의 치환된 에틸메르캅토에틸할라이드, 반응 시킴을 특징으로 하는 하기 일반식 (Ⅰ)의 유기 인산 디티오에스테르의 제조방법.(상기 식중, M은 알칼리 금속 원자 또는 암모늄기를 나타내고, X는 할로겐원자를 나타내고, R은 저급 알킬 메르캅토기, 티오페닐기 또는 티오벤질기를 나타낸다.)
- 제 3항에 있어서, 치환된 에틸메르캅토에틸 할라이드에 대한 O-에틸·S-노르말 프로필디티오 인산염의 물비율이 0.5∼3임을 특징으로 하는 방법.
- 제 3항에 있어서, 치환된 에틸메르캅토에틸 할라이드에 대한 O-에틸·S-노르말 프로필디티오인산염의 물비율이 1∼1.5임을 특징으로 하는 방법.
- 하기 일반식 (Ⅳ)의 O-에틸·S-노르말프로필티오인산 할라이드를 하기 일반식 (Ⅴ)의 치환된 에틸메르캅토에틸메르캅탄 또는 그 염과 반응시킴을 특징으로 하기 하기 일반식 (Ⅰ)의 유기 인산 디티오에스테르의 제조방법.(상기식중, X는 할로겐 원자를 나타내고, M′은 수소 또는 알칼리 금속원자를 나타내고, R은 저급알킬메르캅토기, 티오페닐기 또는 티오벤질기를 나타낸다.
- 제 6항에 있어서, O-에틸·S-노르말프로필 티오 인산 할라이드에 대한 치환된 에틸메르캅토에틸 메로캅탄 또는 그 염의 물비율이 0.5~3임을 특징으로 하는 방법.
- 제 6항에 있어서, O-에틸·S-노르말프로필디 티오 인산 할라이드에 대한 치환된 에틸메르캅토에틸 메르캅탄 또는 그 염의 몰비율이 1∼1.5임을 특징으로 하는 방법.
- 제 6내지 8항중 어느 하나에 있어서， 가수소인 방법.
- 제 9항에 있어서 ，반응을 산 수용체의 존재하에 실시함을 특징으로 하는 방법.
- 하기 일반식 (Ⅰ)의 유기 인산 디티오에스테르를 유효 성분으로 함유함을 특징으로 살충제.(식중, R은 저급 알킬 메르캅토기, 티오페닐기 또는 티오벤질기를 나타낸다.)※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP176868 | 1985-08-13 | ||
| JP60176868A JPS6239595A (ja) | 1985-08-13 | 1985-08-13 | 有機リン酸ジチオエステル、その製造方法及び殺虫、殺ダニ剤 |
| JP176868/85 | 1985-08-13 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR870001769A true KR870001769A (ko) | 1987-03-28 |
| KR910000881B1 KR910000881B1 (ko) | 1991-02-12 |
Family
ID=16021206
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019860006667A KR910000881B1 (ko) | 1985-08-13 | 1986-08-13 | 유기인산 디티오에스테르, 그 제조방법 및 디티오에스테르를 함유하는 살충제 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4694095A (ko) |
| EP (1) | EP0215570B1 (ko) |
| JP (1) | JPS6239595A (ko) |
| KR (1) | KR910000881B1 (ko) |
| CN (1) | CN1024248C (ko) |
| DE (1) | DE3668624D1 (ko) |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2571989A (en) * | 1949-09-28 | 1951-10-16 | Bayer Ag | Neutral esters of thiophosphoric acid |
| US2894973A (en) * | 1955-09-07 | 1959-07-14 | Bayer Ag | Thiophosphoric acid esters and their production |
| CH480799A (de) * | 1966-07-26 | 1969-11-15 | Wolfen Filmfab Veb | Schädlingsbekämpfungsmittel |
| DE2119211A1 (en) * | 1970-05-09 | 1971-12-02 | Farbenfabriken Bayer Ag, 5090 Leverkusen | Organophosphates - active against insects and nematodes |
| JPS4922691B1 (ko) * | 1970-05-11 | 1974-06-11 |
-
1985
- 1985-08-13 JP JP60176868A patent/JPS6239595A/ja active Granted
-
1986
- 1986-08-08 DE DE8686306156T patent/DE3668624D1/de not_active Expired - Fee Related
- 1986-08-08 EP EP86306156A patent/EP0215570B1/en not_active Expired - Lifetime
- 1986-08-08 US US06/894,646 patent/US4694095A/en not_active Expired - Lifetime
- 1986-08-12 CN CN86106243A patent/CN1024248C/zh not_active Expired - Fee Related
- 1986-08-13 KR KR1019860006667A patent/KR910000881B1/ko not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| US4694095A (en) | 1987-09-15 |
| CN86106243A (zh) | 1987-03-04 |
| EP0215570B1 (en) | 1990-01-31 |
| DE3668624D1 (de) | 1990-03-08 |
| EP0215570A1 (en) | 1987-03-25 |
| JPS6239595A (ja) | 1987-02-20 |
| JPH0469635B2 (ko) | 1992-11-06 |
| CN1024248C (zh) | 1994-04-20 |
| KR910000881B1 (ko) | 1991-02-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR870008879A (ko) | 티아제핀류의 제조 방법 | |
| KR860000243A (ko) | 아민유도체의 제조방법 | |
| KR910000947A (ko) | 금속 안료 조성물 | |
| KR870001769A (ko) | 유기 인산 디티오에스테르, 그 제조방법 및 디티오에스테르를 함유하는 살충제 | |
| KR840000874A (ko) | 알파-분지된 알킬티오포스페이트의 제조방법 | |
| KR860002517A (ko) | 트리스(β,β-디메틸펜에틸) 주석 화합물의 제조방법 | |
| KR830007590A (ko) | 카르바모일 옥시이속사졸 유도체의 제조법 | |
| KR870000866A (ko) | S,s-디-(제3알킬) 티오인산염 살충제 조성물 및 그 제조방법 | |
| KR900014355A (ko) | 티오펜-2,5-디카르복실산디에스테르, 테트라하이드로티오펜-2,5-디카르복실산디에스테르 및 디벤즈옥사졸일 티오펜의 제조방법 | |
| KR850002979A (ko) | 1,2,3-트리티안화합물의 신규 제조방법 | |
| KR850006191A (ko) | 티오시아노 피리미딘 유도체의 제조방법 | |
| ATE1148T1 (de) | 6-fluorpyridyl-(di)(thio)phosphorsaeureester, verfahren zu ihrer herstellung und ihre verwendung zur bekaempfung von schaedlingen. | |
| KR920009833A (ko) | 3-알콕시메틸 세파로스포린 유도체의 제조방법 | |
| KR850004470A (ko) | 유기 화합물의 제조방법 | |
| KR840003627A (ko) | 4-피페라지닐-4-페닐 퀴나졸린 유도체의 제조방법 | |
| KR840005153A (ko) | 신규 유기인산염의 농약의 제조방법 | |
| PT82590B (pt) | Processo de preparacao de 4-oxido-2-carboxipirazinas | |
| GB1531053A (en) | Preparation of 2,6-dialkyl-4-hydroxyl-phenylsulphenyl chlorides | |
| KR830009127A (ko) | 시아노히드린 포스페이트의 제조방법 | |
| KR870003102A (ko) | 트리아진 유도체의 제조방법 및 그것을 유효성분으로 하는 제초제 | |
| KR860006474A (ko) | 유기 인산염의 제조방법 | |
| KR870006068A (ko) | 살충성 유기인 화합물 및 그의 제조방법 | |
| KR900018126A (ko) | 옥시미노인산 및-포스폰산 유도체, 그의 제조를 위한 전구체 및 해충 방제를 위한 그의 용도 | |
| KR840006490A (ko) | 디티올 포스포릭산 에스테르의 제조방법 | |
| KR890002062A (ko) | 6-클로로벤족사졸릴-옥시아세트아닐리드 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| E902 | Notification of reason for refusal | ||
| G160 | Decision to publish patent application | ||
| E701 | Decision to grant or registration of patent right | ||
| GRNT | Written decision to grant | ||
| FPAY | Annual fee payment |
Payment date: 19950117 Year of fee payment: 5 |
|
| LAPS | Lapse due to unpaid annual fee |