KR870001290A - 혼합 금속 적층 수산화물-점토 부가물의 제조 방법 - Google Patents

혼합 금속 적층 수산화물-점토 부가물의 제조 방법 Download PDF

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KR870001290A
KR870001290A KR1019860005436A KR860005436A KR870001290A KR 870001290 A KR870001290 A KR 870001290A KR 1019860005436 A KR1019860005436 A KR 1019860005436A KR 860005436 A KR860005436 A KR 860005436A KR 870001290 A KR870001290 A KR 870001290A
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clay
hydroxide
laminated
anion
mixed metal
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KR1019860005436A
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KR940002568B1 (ko
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엘. 부르바 3세 존
엘. 바네스 오드리
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더 다우 케미칼 캄파니
원본미기재
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
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    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00Silicon; Compounds thereof
    • C01B33/20Silicates
    • C01B33/26Aluminium-containing silicates, i.e. silico-aluminates
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    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00Silicon; Compounds thereof
    • C01B33/20Silicates
    • C01B33/36Silicates having base-exchange properties but not having molecular sieve properties
    • C01B33/38Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
    • C01B33/40Clays
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    • C01B33/00Silicon; Compounds thereof
    • C01B33/20Silicates
    • C01B33/36Silicates having base-exchange properties but not having molecular sieve properties
    • C01B33/38Layered base-exchange silicates, e.g. clays, micas or alkali metal silicates of kenyaite or magadiite type
    • C01B33/44Products obtained from layered base-exchange silicates by ion-exchange with organic compounds such as ammonium, phosphonium or sulfonium compounds or by intercalation of organic compounds, e.g. organoclay material
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
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  • Health & Medical Sciences (AREA)
  • Ceramic Engineering (AREA)
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  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Colloid Chemistry (AREA)
  • Lubricants (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pens And Brushes (AREA)
  • Preparation Of Clay, And Manufacture Of Mixtures Containing Clay Or Cement (AREA)
  • Laminated Bodies (AREA)

Abstract

내용 없음.

Description

혼합 금속 적층 수산화물-점토 부가물의 제조 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (13)

  1. 적층 수산화물의 수성 겔 또는 분산물을 점토의 수성 분산물과 반응시켜 점토 음이온과 적층 수산화물 음이온간의 이온교환으로 점도로부터의 금속이온과 적층 수산화물로부터의 음이온을 수용액중에 유리시키고, 혼합 금속 적층 수산화물과 점토와의 부가물을 형성함을 특징으로 하여 실험식(I)의 단일분산 단일층 혼합 금속 적층 수산화물을 광물 점토와 반응시키는 방법.
    LimDdT(OH)(m+2d+3+na)Aa n·qH2O (I)
    상기식에서, D는 2가의 금속이온이고; T는 3가의 금속이온이고; A는 OH-를 제외한 1가 또는 다가의 음이온이고; m은 0 내지 약 1이고;d는 0 내지 약 4이고; a는 A의 이온 수이고; n은 A의 원자가이고; na는 0 내지 약 -3이고; q는 0 내지 약 6이고; (m+d)는 0보다 크고; (m+2d+3+na)는 3이상이다.
  2. 제1항에 있어서, m이 0.5 내지 0.75인 방법.
  3. 제1항에 있어서, d가 1 내지 3인 방법.
  4. 제1항에 있어서, D가 Mg, Ca, Ba, Sr, Mn, Fe, Co, Ni, Cu 및 Zn중의 적어도 하나인 방법.
  5. 제1항 또는 제4항에 있어서, D가 Mg 및 Ca중의 적어도 하나인 방법.
  6. 제1항에 있어서, T가 Al, Ga, Cr 및 Fe중의 적어도 하나인 방법.
  7. 제1항 또는 제6항에 있어서, T가 Al 또는 Fe인 방법.
  8. 제1항에 있어서, A가 할라이드, 황산염, 질산염, 인산염, 탄산염, 글리콜레트, 리그노설포네이트, 폴리카복실레이트, 폴리아크릴레이트 또는 나트륨 폴리아크릴레이트의 적어도 하나의 1가 또는 다가 음이온인 방법.
  9. 제1항에 있어서, 광물점토가 벤토나이트, 카올리나이트, 할로이사이트, 스메크타이트, 일라이트, 몬모릴로나이트, 사코나이트, 베르미쿨라이트, 클로라이트, 애터펄자이트, 세피올라이트, 팔리고르스카이트 및 표포토중의 적어도 하나인 방법.
  10. 제1항에 있어서, 광물점토가 알로판 그룹의 무정형 점토류, 및 2층형, 3층형, 팽창형, 비팽창형, 신장형, 규칙적 혼합층형 또는 쇄구조형의 결정성 점토류중의 적어도 하나인 방법.
  11. 제1항 또는 제9항에 있어서, 광물점토가 벤토나이트인 방법.
  12. 제1항에 있어서, 적층 수산화물/점토의 중량비율이 0.02/1 내지 1/1인 방법.
  13. 제1항에 있어서, 혼합 금속 적층 수산화물이 MgAl(OH)4.7Cl0.3이고, 점토가 벤토나이트인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860005436A 1985-07-05 1986-07-05 혼합 금속 적층 수산화물-점토 부가물의 제조방법 KR940002568B1 (ko)

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AU5975686A (en) 1987-01-22
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IL79303A0 (en) 1986-10-31
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BR8603135A (pt) 1987-02-24
US4790954A (en) 1988-12-13
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NO862725L (no) 1987-01-06
AU580432B2 (en) 1989-01-12
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