KR870001282A - 구조 보강처리된 라텍스미립 및 이의 제조방법 - Google Patents

구조 보강처리된 라텍스미립 및 이의 제조방법 Download PDF

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KR870001282A
KR870001282A KR1019860006215A KR860006215A KR870001282A KR 870001282 A KR870001282 A KR 870001282A KR 1019860006215 A KR1019860006215 A KR 1019860006215A KR 860006215 A KR860006215 A KR 860006215A KR 870001282 A KR870001282 A KR 870001282A
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mentioned
monomer
polymer
process according
parts
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KR1019860006215A
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KR920000194B1 (ko
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씨. 매카티 애쇽
이도익
엘. 애쉬 메지
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리챠드 지. 워터맨
더 다우 케미칼 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/902—Core-shell

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
  • Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
  • Reinforced Plastic Materials (AREA)

Abstract

내용 없음.

Description

구조 보강처리된 라텍스미립 및 이의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명의 구조 보강처리된 라텍스필름 및 대조용 균일질 라텍스 필름의 응력-변형 곡선을 도시한 것이다.

Claims (10)

  1. (a) 제1단량체 공급물을 중합시켜 코어대역을 형성하고, (b) 라텍스미립중의 단량체 100부당 5 내지 30부의 제2단량체 공급물[여기서, 제2단량체의 중합체는 언급된 (a)보다 높은 유리전이온도(Tg)를 갖는다]을 언급된 (a)의 존재하에 중합시키고, (c) 상기 (a)와 (b)의 존재하에, 제3단량체 공급물[여기서, 제3단량치의 중합체는 언급된 (b)보다 낮은 Tg를 갖는다]을 중합시켜 셀대역을 형성함을 특징으로 하는 유액중합 방법으로 제조된, 개선된 인장 및 신장특성을 갖는 필름으로 제조할 수 있는 구조 보강처리된 라텍스미립의 제조방법.
  2. 제1항에 있어서, 언급된 (b)로부터 제조된 중합체가 25℃ 이상의 Tg를 갖는 방법.
  3. 제1항에 있어서, 언급된 단량체 공급물(a) 및 (c)로부터 제조된 중합체가 동일한 Tg를 갖는 방법.
  4. 제3항에 있어서, 언급된 단량체 공급물(a) 및 (c)가 동일조성인 방법.
  5. 제1항에 있어서, 언급된 단량체 공급물(a) 및 (C)가 스티렌과 부타디엔과의 혼합물인 방법.
  6. 제1항에 있어서, 언급된 제2단량체 공급물(b)가 언급된 라텍스미립중의 단량체 100부당 15 내지 25부의 양인 방법.
  7. 제1항에 있어서, 언급된 단량체 공급물(b)가 이의 중합체가 25℃ 이상의 Tg를 갖는 스티렌 또는 이의 혼합물인 방법.
  8. 전술된 항들중 어느 하나의 항의 방법으로 제조됨을 특징으로 하는, 개선된 인장 및 신장 특성을 갖는 필름으로 제조할 수 있는 구조 보강처리된 라텍스 미립.
  9. (i) 제1 내지 7항중 어느 하나의 항의 방법으로 제조된 개선된 인장 및 신장 특성을 갖는 구조 보강 처리된 라텍스미립, 및 (ii) 증점제로 이루어짐을 특징으로 하는 감압성 접착제.
  10. 제9항에 있어서, 언급된 증점제가 감압성 접착성 제형중의 고체 기준으로 1 내지 90중량%를 구성하는 감압성 접착제.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860006215A 1985-07-29 1986-07-29 구조 보강 라텍스 미립자, 이의 제조방법 및 이를 함유하는 감압성 접착제 KR920000194B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US06/759,994 US4717750A (en) 1985-07-29 1985-07-29 Structure reinforced latex particles
US759,994 1985-07-29
US759994 1985-07-29

Publications (2)

Publication Number Publication Date
KR870001282A true KR870001282A (ko) 1987-03-12
KR920000194B1 KR920000194B1 (ko) 1992-01-10

Family

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Family Applications (1)

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KR1019860006215A KR920000194B1 (ko) 1985-07-29 1986-07-29 구조 보강 라텍스 미립자, 이의 제조방법 및 이를 함유하는 감압성 접착제

Country Status (13)

Country Link
US (1) US4717750A (ko)
EP (1) EP0215241B1 (ko)
JP (1) JPH075693B2 (ko)
KR (1) KR920000194B1 (ko)
AR (1) AR242596A1 (ko)
AT (1) ATE60614T1 (ko)
AU (1) AU595520B2 (ko)
BR (1) BR8603557A (ko)
CA (1) CA1308835C (ko)
DE (1) DE3677298D1 (ko)
ES (1) ES2001040A6 (ko)
FI (1) FI90245C (ko)
MX (1) MX165323B (ko)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4701493A (en) * 1986-07-14 1987-10-20 Atlantic Richfield Company Acrylic modified N-arylmaleimide copolymer molding composition
US4923919A (en) * 1986-08-22 1990-05-08 S. C. Johnson & Son, Inc. Pressure sensitive adhesive compositions
US4806207A (en) * 1987-02-15 1989-02-21 The Dow Chemical Company Structured latex particles having reinforcing and opacity characteristics
US4939190A (en) * 1987-05-25 1990-07-03 Dainippon Ink And Chemicals, Inc. Aqueous emulsion-type pressure sensitive adhesives
US4888395A (en) * 1987-07-02 1989-12-19 Mobil Oil Corporation Core/shell polymers and improved sealable articles treated with the same
GB8718036D0 (en) * 1987-07-30 1987-09-03 Tioxide Group Plc Polymeric particles
GB8729399D0 (en) * 1987-12-17 1988-02-03 Tioxide Group Plc Polymeric particles & their preparation
US5008324A (en) * 1989-04-11 1991-04-16 Rohm And Haas Company Novel damping compositions
US5066708A (en) * 1989-04-11 1991-11-19 Rohm And Haas Company Novel damping compositions
GB9007199D0 (en) * 1990-03-30 1990-05-30 Tioxide Group Plc Preparation of polymeric particles
US5700852A (en) * 1994-04-06 1997-12-23 Japan Synthetic Rubber Co., Ltd. Paper coating composition
US5824748A (en) † 1996-06-03 1998-10-20 Minnesota Mining And Manufacturing Company Composite pressure sensitive adhesive microspheres
DE19632202A1 (de) 1996-08-09 1998-02-12 Basf Ag Haftklebstoffe auf Basis mehrstufig aufgebauter Polymerisate
KR100264512B1 (ko) * 1998-02-14 2000-09-01 박찬구 스티렌-부타디엔계라텍스
US6180307B1 (en) 1999-11-23 2001-01-30 Xerox Corporation Layered polymer particles, toner formed therefrom and methods for forming the same
US6355720B1 (en) 2000-05-12 2002-03-12 Johnson Polymer, Inc. Latex formulations with reduced yellowing
JP4917268B2 (ja) * 2005-04-13 2012-04-18 旭化成ケミカルズ株式会社 感熱記録紙塗工用組成物
EP1911771A1 (en) * 2006-10-09 2008-04-16 Cytec Surface Specialties, S.A. Acqueous polymer dispersion and process
BR102012012742B1 (pt) * 2012-05-28 2022-03-08 Instituto De Pesquisas Tecnológicas Do Est. S. Paulo S/a Ipt Método de produção de borracha na forma sólida microparticulada
CN115947884B (zh) * 2022-12-20 2024-03-05 山东万达化工有限公司 一种大粒径聚丁二烯胶乳的合成方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2144273C3 (de) * 1971-09-01 1975-09-25 Japan Synthetic Rubber Co., Ltd., Tokio Verfahren zur Herstellung eines Pfropfpolymerisates und Verwendung desselben in Formmassen auf Polyvinylchlorid-Basis
FR2239488B1 (ko) * 1973-07-11 1976-04-30 Rhone Progil
US4289823A (en) * 1980-09-30 1981-09-15 Rohm And Haas Company Calenderable acrylic polymers and textiles treated therewith
IE57758B1 (en) * 1983-08-31 1993-03-24 Mitsubishi Rayon Co Impact modifier and thermoplastic resin compositions using the same
US4537916A (en) * 1984-06-25 1985-08-27 The Dow Chemical Company Structured latex particles which are film forming and a process for their preparation

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Publication number Publication date
FI90245B (fi) 1993-09-30
JPH075693B2 (ja) 1995-01-25
AR242596A1 (es) 1993-04-30
BR8603557A (pt) 1987-03-04
ATE60614T1 (de) 1991-02-15
MX165323B (es) 1992-11-05
EP0215241B1 (en) 1991-01-30
AU595520B2 (en) 1990-04-05
AU6045886A (en) 1987-02-05
FI863060A (fi) 1987-01-30
US4717750A (en) 1988-01-05
DE3677298D1 (de) 1991-03-07
ES2001040A6 (es) 1988-04-16
FI863060A0 (fi) 1986-07-25
KR920000194B1 (ko) 1992-01-10
FI90245C (fi) 1994-01-10
CA1308835C (en) 1992-10-13
JPS6236413A (ja) 1987-02-17
EP0215241A1 (en) 1987-03-25

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