KR860006337A - 시트-상 구조물 및 이의 제조방법 - Google Patents

시트-상 구조물 및 이의 제조방법 Download PDF

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KR860006337A
KR860006337A KR1019860000737A KR860000737A KR860006337A KR 860006337 A KR860006337 A KR 860006337A KR 1019860000737 A KR1019860000737 A KR 1019860000737A KR 860000737 A KR860000737 A KR 860000737A KR 860006337 A KR860006337 A KR 860006337A
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sheet
film layer
fluorine
peak
thin polymer
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KR1019860000737A
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KR900000237B1 (ko
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다까오 아까기
다까오 아까기 (외 2)
이쯔끼 사까모도
신지 야마구찌
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구라레 가부시끼가이샤
나까무라 히사오
구라레 가부시끼 가이샤
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Priority claimed from JP60021350A external-priority patent/JPS61186578A/ja
Priority claimed from JP60186028A external-priority patent/JPS6245784A/ja
Application filed by 구라레 가부시끼가이샤, 나까무라 히사오, 구라레 가부시끼 가이샤 filed Critical 구라레 가부시끼가이샤
Publication of KR860006337A publication Critical patent/KR860006337A/ko
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Publication of KR900000237B1 publication Critical patent/KR900000237B1/ko

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/047Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with fluoropolymers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/18Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
    • D06N3/183Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials the layers are one next to the other
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/26Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/263Coating layer not in excess of 5 mils thick or equivalent
    • Y10T428/264Up to 3 mils
    • Y10T428/2651 mil or less
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/3154Of fluorinated addition polymer from unsaturated monomers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31551Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31565Next to polyester [polyethylene terephthalate, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31551Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31573Next to addition polymer of ethylenically unsaturated monomer
    • Y10T428/3158Halide monomer type [polyvinyl chloride, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31551Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31598Next to silicon-containing [silicone, cement, etc.] layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31652Of asbestos
    • Y10T428/31663As siloxane, silicone or silane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31652Of asbestos
    • Y10T428/31667Next to addition polymer from unsaturated monomers, or aldehyde or ketone condensation product
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31786Of polyester [e.g., alkyd, etc.]
    • Y10T428/31797Next to addition polymer from unsaturated monomers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2861Coated or impregnated synthetic organic fiber fabric

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Laminated Bodies (AREA)

Abstract

내용 없음

Description

시트-상 구조물 및 이의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (15)

  1. 분산염료로 착색된 폴리에스테르 섬유를 10중량% 이상 함유하는 섬유상 구조물, 이 구조물의 적어도 한면상에 코팅된 수지층, 및 이 수지층의 적어도 한면상에 형성된 두께 100 내지 10000Å의 얇은 중합체 필름층으로 이루어지는, 분산염료의 이염 및 승화방지효과가 우수한 시트-상(sheet-like)구조물.
  2. 제1항에 있어서, 얇은 중합체층이 불소화합물의 유도체인 시트-상 구조물.
  3. 제1항에 있어서, 얇은 중합체 필름층이 불소화합물의 유도체이며, X-선 광전자분광기에 의해 측정된 불소Fis피이크 면적으로부터 계산된 불소원자의 수를 동일한 방법으로 계산된 탄소 Cis원자의 수로 나누어 얻어진 값인, 상기 얇은 필름층의 불화율, 즉 α=F/C가 0.2α1.8의 범위내인 시트-상 구조물.
  4. 제1항에 있어서, 얇은 중합체 층이 불소화합물로 제조되고, 상기 얇은 필름층의 불화율, 즉 α=F/C가 0.2α1.3의 범위내이며, X-선 광전자분광기에 의해 측정된 산소 Ois피이크 면적으로부터 계산된 산소원자수의 수를 동일한 방법으로 계산된 탄소 CIS원자의 수로 나누어 얻어진 값인, 산화율, 즉 β=O/C가 0.05β0.35의 범위내인 시트 - 상 구조물.
  5. 제1항에 있어서, 얇은 중합체 필름층이 10%〈A〈70%, 10%〈B〈35%, 10%〈C〈35%, 5%〈D〈30% 및 0%〈E〈20%[여기에서, A, B, C, D 및 E는, 얇은 필름을 X-선 광전자 분광 분석하여 얻어진 탄소 Cis차트를 이 차트상에서 피이크에 상응하는 각 결합에너지를 중심으로 하여 몇 개의 파 형태로 분리하는 방법(파-형분리법)을 수행하고, 이 파 형태의 면적을 총 Cis면적으로 나누어 얻어진 값에 100을 곱하여 유도된 백분율로서, A는 피이크가 약 285 전자볼트(eV)인 파형에 대한 백분율이고, B는 피이크가 약 287±0.5eV인 파형에 대한 것이고, C는 피이크가 약 289±0.5eV인 파형에 대한 것이고, D는 피이크가 약 291.6±0.5eV인 파형에 대한 것이며, E는 피이크가 약 293.8±0.5eV인 파형에 대한 것이다]의 조건을 만족시키는 시트-상 구조물.
  6. 제1항에 있어서, 얇은 중합체 필름층이 (B+8)%〉(C+3)%〉D%〉E% 및 B%〉(E+6)%의 조건을 만족시키는 시트-상 구조물.
  7. 제1항에 있어서, 얇은 중합체 필름층이 실리콘-함유 화합물의 유도체인 시트-상 구조물.
  8. 제1항에 있어서, 수지층이 폴리우레탄, 아크릴성 중합체, 비닐클로라이드 중합체 및 합성고무로 구성되는 그룹에서 선택된 중합체로 제조된 시트-상 구조물.
  9. 제1항에 있어서, 하기 부등식을 만족시키는 시트-상 구조물.
    y〉-x+500(x0, y0)
    상기 식에서, y는 JIS Z-0208에 따라 측정한 시트-상 구조물의 수증기 투과성(g/㎡/24h)을 나타내며, x는 JIS L-1092에 따라 측정한 시트-상 구조물의 내수도(resistance to hydro-static pressure)(mm)를 나타낸다.
  10. 분산염료-착색 폴리에스테르 섬유를 10중량% 이상 함유하며, 수지코팅처리에 의해 그의 적어도 한면상에 수지층이 제공된 시트-상 구조물을, 용해도 파라메터(SP) 치가 상기 분산염료의 SP치보다 적어도 0.5(cal/㎤)1/2정도 낮은 단량체성 화합물을 사용하여 저온 플라스마 중합처리시켜 상기 시트-상 구조물의 수지층의 적어도 한면상에 두께 100 내지 10000Å의 얇은 필름층을 형성시킴을 특징으로하여, 분산염료의 이염 및 승화 방지 효과가 우수한 시트-상 구조물을 제조하는 방법.
  11. 제10항에 있어서, 단량체성 화합물이 불소-함유 단량체인 방법.
  12. 제11항에 있어서, 불소-함유 단량체를 C2F4,C3F6,C3F8,C4F8,C3F6O 및 C2H4F2로 구성되는 그룹에서 선택하는 방법.
  13. 제10항에 있어서, 불소-함유 단량체 및 수소나 불소-함유 단량체 및 비중합성 가스로 이루어진 혼합가스를 저온 플라스마 중합반응의 수행에 사용하는 방법.
  14. 제10항에 있어서, 단량체성 화합물이 실리콘-함유 단량체인 방법.
  15. 제10항에 있어서, 저온 플라스마 중합반응을 캔-형 몸체로부터 전기적으로 절연된 비접지 전극을 갖는 저온 플라스마 장치에서 수행하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860000737A 1985-02-05 1986-02-04 시트-상 구조물 및 이의 제조방법 KR900000237B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP60-21350 1985-02-05
JP21350 1985-02-05
JP60021350A JPS61186578A (ja) 1985-02-05 1985-02-05 シ−ト状構造物及びその製造方法
JP60186028A JPS6245784A (ja) 1985-08-23 1985-08-23 シ−ト状構造物及びその製造方法
JP60-186028 1985-08-23

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KR860006337A true KR860006337A (ko) 1986-09-09
KR900000237B1 KR900000237B1 (ko) 1990-01-24

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US (1) US4728564A (ko)
EP (1) EP0190721B1 (ko)
KR (1) KR900000237B1 (ko)
CN (1) CN1005736B (ko)
AU (1) AU576933B2 (ko)
DE (1) DE3681803D1 (ko)

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US4728564A (en) 1988-03-01
EP0190721A3 (en) 1988-10-05
AU576933B2 (en) 1988-09-08
EP0190721B1 (en) 1991-10-09
AU5217786A (en) 1986-08-14
CN1005736B (zh) 1989-11-08
CN86100950A (zh) 1986-11-05
EP0190721A2 (en) 1986-08-13
KR900000237B1 (ko) 1990-01-24

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