KR850004719A - 합성된 실리코포스포알루미네이트 결정체 - Google Patents

합성된 실리코포스포알루미네이트 결정체 Download PDF

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KR850004719A
KR850004719A KR1019840008130A KR840008130A KR850004719A KR 850004719 A KR850004719 A KR 850004719A KR 1019840008130 A KR1019840008130 A KR 1019840008130A KR 840008130 A KR840008130 A KR 840008130A KR 850004719 A KR850004719 A KR 850004719A
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crystalline
cation
valent
less
crystalline material
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KR1019840008130A
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KR920005939B1 (ko
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게라르드 데로우안(외1) 에릭
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에드워드 하치 발렌스
모빌 오일 코오포레이숀
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/12—Compounds containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
    • C01B33/28—Base exchange silicates, e.g. zeolites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
    • C01B37/08—Silicoaluminophosphates [SAPO compounds], e.g. CoSAPO

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Analytical Chemistry (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Analysing Materials By The Use Of Radiation (AREA)

Abstract

내용 없음

Description

합성된 실리코포스포알루미네이트 결정체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 본 명세서의 표 1-A에 명시된 바와같은 X선 회전패턴을 지니는 것을 특징으로하는 실리콘, 인 및 알루미늄으로 구성된 결정질의 합성물질.
  2. 제1항에 있어서, 하소후, 본 명세서의 표 1-B에 명시된 바와 같은 X-선 회절패턴을 지니는 것을 특징으로 하는 결정질의 합성물질.
  3. 제1항에 있어서, 하기의 조성으로 구성되는 것을 특징으로하는 결정질의 합성물질.
    상기식에서, M은 m가의 양이온이며, N은 n가의 음이온이며, A는 유기물질이며, v는 A의 몰수이며, w는 H2O의 몰수이며, x와 y는 -1 보다 크며 +1보다 적은 수로서, (1) x가 0인경우 y는 0가 아니며 (2) y가 0인 경우 x는 0가 아니며, (3) 는 x+y는 0.001보다 크고 1보다 작다는 관계를 만족함.
  4. 제2항에 있어서, 무수상태에서 하기와 같은 조성으로 구성되는 것을 특징으로하는 결정질의 합성물질.
    상기식에서, M은 m가의 양이온이며, N은 n가의 음이온이며, x와 y는 -1보다 크며 +1 보다 작은 수로서, (1) x가 0인경우 y는 0가 아니며 (2) y가 0인 경우 x는 0가 아니며, (3) 는 x+y는 0.001보다 크고 1보다 작다는 관계를 만족함.
  5. 제1항-제4항의 어느한 항에 있어서, 원래의 양이온이 수소, 수소선구물질, 회토류금속 및 원소주기율표의 제 IA, ⅡA, ⅢA, ⅣA, IB, ⅡB, ⅢB, ⅣB 및 Ⅷ족 금속으로 구성되는 그룹으로부터 선택된 양이온 또는 양이온 혼합물로 치환된 결정물질.
  6. 제5항에 있어서, 결정물질을 열처리하는 것을 특징으로하는 결정물질.
  7. 1-90중량 퍼센트의 상기 제 1-6항중 어느한항의 결정물질과 10-99중량퍼센트의 매트릭스물질로 구성되는 것을 특징으로하는 촉매조성물.
  8. 유기화합물의 전화용 촉매로서의 상기 제 1-7항중 어느한 항의 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019840008130A 1983-12-19 1984-12-19 합성된 실리코포스포알루미네이트 결정체 KR920005939B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US56277583A 1983-12-19 1983-12-19
US56267383A 1983-12-19 1983-12-19
US562673 1983-12-19
US562775 1983-12-19

Publications (2)

Publication Number Publication Date
KR850004719A true KR850004719A (ko) 1985-07-27
KR920005939B1 KR920005939B1 (ko) 1992-07-25

Family

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KR1019840008130A KR920005939B1 (ko) 1983-12-19 1984-12-19 합성된 실리코포스포알루미네이트 결정체

Country Status (10)

Country Link
EP (1) EP0146389B1 (ko)
KR (1) KR920005939B1 (ko)
AR (1) AR245616A1 (ko)
AU (1) AU571619B2 (ko)
CA (1) CA1244219A (ko)
DE (1) DE3482255D1 (ko)
DK (1) DK606984A (ko)
ES (1) ES8606013A1 (ko)
IN (1) IN163775B (ko)
NZ (1) NZ210467A (ko)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ210464A (en) * 1983-12-19 1987-08-31 Mobil Oil Corp Crystalline silicophosphoaluminates and their use as catalysts
AU575985B2 (en) * 1984-08-21 1988-08-11 Mobil Oil Corporation Synthesis of silicophosphoaluminate
US5374411A (en) * 1987-08-28 1994-12-20 The Dow Chemical Company Crystalline aluminumphosphate compositions
AU614107B2 (en) * 1987-12-21 1991-08-22 Mobil Oil Corporation Crystalline molecular sieve
US5013535A (en) * 1989-04-20 1991-05-07 Uop Stabilized aluminophosphate compositions and process for preparing same
US5406012A (en) * 1989-05-23 1995-04-11 The Dow Chemical Company Heterocatalyst system
DD299288A5 (de) * 1989-07-07 1992-04-09 ���������������@����@�������������@�K@����������K@��������@�K@���@�K@���@M�����]k�� Verfahren zur herstellung eines kristallinen molekularsiebes
ES2052109T3 (es) * 1990-07-05 1994-07-01 Vaw Ver Aluminium Werke Ag Procedimiento para la fabricacion y utilizacion de un tamiz molecular de aluminofosfato con una estructura de espacios huecos microporosa.
GB9023847D0 (en) * 1990-11-02 1990-12-12 Shell Int Research Novel crystalline aluminophosphates and related compounds
FR2671790B1 (fr) * 1991-01-18 1993-04-16 Inst Francais Du Petrole Procede de preparation de composes aluminophosphates et derives substitues de type structural vfi invention de : jean-francois joly, herve cauffriez et jean-louis guth.
DE4138272A1 (de) * 1991-11-21 1993-07-01 Vaw Ver Aluminium Werke Ag Katalysatormaterial, seine verwendung sowie ein verfahren zur hydrodehalogenierung von organischen halogenverbindungen
DE4331116C2 (de) * 1993-09-14 1998-09-03 Alsi Penta Zeolithe Gmbh Verfahren zur Herstellung von Dimeren des alpha-Methylstyrols

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE754129A (fr) * 1969-07-30 1971-01-29 Union Carbide Corp Zeolite au phosphore et procede pour la preparer
DE2041377A1 (de) * 1969-08-28 1971-03-04 Union Carbide Corp Synthetische kristalline Aluminosilicophosphate mit zeolithischen Eigenschaften
DE2124795A1 (de) * 1970-06-26 1971-12-30 Union Carbide Corp Kristallines Aluminium-Silizium-Phosphat und Verfahren zu seiner Herstellung
US4385994A (en) * 1980-07-07 1983-05-31 Union Carbide Corporation Adsorptive use of crystalline metallophosphate compositions
US4440871A (en) * 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
NZ210463A (en) * 1983-12-19 1988-04-29 Mobil Oil Corp Crystalline silicophosphoaluminate and its use as a catalyst

Also Published As

Publication number Publication date
EP0146389A3 (en) 1987-05-13
AR245616A1 (es) 1994-02-28
DE3482255D1 (de) 1990-06-21
DK606984D0 (da) 1984-12-18
EP0146389A2 (en) 1985-06-26
ES8606013A1 (es) 1986-04-01
IN163775B (ko) 1988-11-05
KR920005939B1 (ko) 1992-07-25
AU3689484A (en) 1985-07-04
AU571619B2 (en) 1988-04-21
EP0146389B1 (en) 1990-05-16
DK606984A (da) 1985-06-20
ES538733A0 (es) 1986-04-01
NZ210467A (en) 1988-06-30
CA1244219A (en) 1988-11-08

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