KR850004720A - 결정성 실리코포스포알루미네이트 - Google Patents

결정성 실리코포스포알루미네이트 Download PDF

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Publication number
KR850004720A
KR850004720A KR1019840008131A KR840008131A KR850004720A KR 850004720 A KR850004720 A KR 850004720A KR 1019840008131 A KR1019840008131 A KR 1019840008131A KR 840008131 A KR840008131 A KR 840008131A KR 850004720 A KR850004720 A KR 850004720A
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South Korea
Prior art keywords
crystalline material
less
atomic ratio
synthetic crystalline
cation
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KR1019840008131A
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English (en)
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게라르드 데로우안(외1) 에릭
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에드워드 하치 발렌스
모빌 오일 코오포레이숀
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Publication of KR850004720A publication Critical patent/KR850004720A/ko

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/12—Compounds containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
    • C01B33/28—Base exchange silicates, e.g. zeolites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
    • C01B37/08—Silicoaluminophosphates [SAPO compounds], e.g. CoSAPO
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Analysing Materials By The Use Of Radiation (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

내용 없음

Description

결정성 실리코포스포 알루미네이트
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 명세서 표 1-A에 나타난 것과 같은 X-선 회절패턴을 보이는“MCM-4”로 명명된 실리콘, 인과 알루미늄으로 구성되는 합성 결정물질.
  2. 제1항에 있어서, 하소후에 명세서 표 1-B에 나타난 것과 같은 X-선 회절패턴을 보이는 합성 결정질 물질.
  3. 제1항에 있어서, 다음과 같은 조성을 갖는 합성 결정질물질.
    여기서, M은 m가의 양이온, N은 n가의 음이온, A는 유기시약, 또는 물에 섞이지 않는 유기용매, v는 A의 몰수, w는 H2O의 몰수이고 x와 y는 다음과계를 만족시키는 -1 - 내지 +1의 수이다:
    (1) x가 0이면 y는 0이 아니고, (2) y가 0이면 x는 0이 아니며, (3) A1/P의 원자비율이 1보다 크면, x+y는 0.001보다 크고 y+0.6x는 0.4보다 작으며, (4) A1/P의 원자비율이 1보다 작으면 x+y는 0.001보다 크고 x+0.5y는 0.5보다 작다.
  4. 제2항에 있어서, 무수물상태의 다음과 같은 조성을 갖는 합성결정질물질.
    여기서, M은 m가의 양이온, N은 n가의 음이온이고, x와 y는 다음단계를 만족시키는 -1 - +1의 수이다.
    (1) x가 0이면 y는 0이 아니고, (2) y가 0이면 x는 0이 아니며, (3) A1/P의 원자비율이 1보다 크면, x+y는 0.001보다 크고 y+0.6x는 0.4보다 작으며, (4) A1/P의 원자비율이 1보다 작으며 x+y는 0.001보다 크고 x+0.5y는 0.5보다 작다.
  5. 제1항 내지 4항중 어느 한항에 있어서, 원래의 양이온이 적어도 부분적으로 양이온 또는 수소 및 수소전구체, 회토류 금속과 주기율표의 ⅠA,ⅡA,ⅢA,ⅣA,ⅠB,ⅡB,ⅢB,ⅣB와 Ⅷ족의 금속류로 구성되는 그룹으로 부터 선택된 양이온의 혼합물로 대치되는 결정질물질.
  6. 제5항의 결정질 물질을 열처리하여 얻는 결정질 물질.
  7. 제1항-6항중 어느 한항의 결정질물질 1-90중량% 포함하며 매트릭스 물질을 10-99중량% 포함하는 촉매 조성물.
  8. 제1항 내지 7항중 어느 한항에 있어서 유기화합물의 전환을 위한 촉매로서의 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019840008131A 1983-12-19 1984-12-19 결정성 실리코포스포알루미네이트 KR850004720A (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US56267383A 1983-12-19 1983-12-19
US56262183A 1983-12-19 1983-12-19
US562673 1983-12-19
US562621 1983-12-19

Publications (1)

Publication Number Publication Date
KR850004720A true KR850004720A (ko) 1985-07-27

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ID=27073005

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Application Number Title Priority Date Filing Date
KR1019840008131A KR850004720A (ko) 1983-12-19 1984-12-19 결정성 실리코포스포알루미네이트

Country Status (8)

Country Link
EP (1) EP0146387A3 (ko)
KR (1) KR850004720A (ko)
AR (1) AR246197A1 (ko)
AU (1) AU571040B2 (ko)
CA (1) CA1244221A (ko)
DK (1) DK606784A (ko)
ES (1) ES8607050A1 (ko)
NZ (1) NZ210465A (ko)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ210461A (en) * 1983-12-19 1988-06-30 Mobil Oil Corp Synthesis of silicophosphoaluminate molecular sieves and ion-exchangers
ATE99646T1 (de) * 1990-07-05 1994-01-15 Vaw Ver Aluminium Werke Ag Verfahren zur herstellung eines weitporigen kristallinen molekularsiebes.

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE754129A (fr) * 1969-07-30 1971-01-29 Union Carbide Corp Zeolite au phosphore et procede pour la preparer
DE2041377A1 (de) * 1969-08-28 1971-03-04 Union Carbide Corp Synthetische kristalline Aluminosilicophosphate mit zeolithischen Eigenschaften
DE2124795A1 (de) * 1970-06-26 1971-12-30 Union Carbide Corp Kristallines Aluminium-Silizium-Phosphat und Verfahren zu seiner Herstellung
US4310440A (en) * 1980-07-07 1982-01-12 Union Carbide Corporation Crystalline metallophosphate compositions
NZ210464A (en) * 1983-12-19 1987-08-31 Mobil Oil Corp Crystalline silicophosphoaluminates and their use as catalysts
US4898722A (en) * 1984-12-19 1990-02-06 Mobil Oil Corp. Synthesis of crystalline SAPO-37

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Publication number Publication date
DK606784D0 (da) 1984-12-18
NZ210465A (en) 1988-02-29
ES8607050A1 (es) 1986-05-16
DK606784A (da) 1985-06-20
AR246197A1 (es) 1994-07-29
AU571040B2 (en) 1988-03-31
ES538731A0 (es) 1986-05-16
EP0146387A3 (en) 1987-04-22
CA1244221A (en) 1988-11-08
AU3689084A (en) 1985-07-04
EP0146387A2 (en) 1985-06-26

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