KR850003152A - Heat resistant molding material - Google Patents

Heat resistant molding material Download PDF

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KR850003152A
KR850003152A KR1019840006341A KR840006341A KR850003152A KR 850003152 A KR850003152 A KR 850003152A KR 1019840006341 A KR1019840006341 A KR 1019840006341A KR 840006341 A KR840006341 A KR 840006341A KR 850003152 A KR850003152 A KR 850003152A
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molding material
material according
butadiene
heat
heat resistant
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아르 란디 빈센트 (외 1)
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리차아드 씨 · 베리
로저스 코오포레이션
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L59/00—Compositions of polyacetals; Compositions of derivatives of polyacetals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
    • C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
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Abstract

내용 없음No content

Description

내열성 성형물질Heat resistant molding material

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

제1도는 본 발명에 따르는 몇종의 제제에 대하여 270℃에서 중량손실 백분율대 숙성시간을 대수(對數)플로트한 도면.1 is a plot of the weight loss percentage versus maturation time at 270 ° C. for several formulations according to the invention.

제2도는 몇종의 제제중 하나가 본 발명의 것일때 중량보유백분율대 숙성시간을 플로트한 도면.2 is a plot of the weight-bearing percentage versus maturation time when one of several formulations is of the present invention.

제3도는 몇종의 제제중 하나가 본 발명의 것일ㄸㅒ 굴곡강도대 시간을 플트로한 도면.Figure 3 is a plot of flexural strength versus time when one of several formulations is of the present invention.

Claims (29)

열경화성 페놀수지와; 섬유보강물질과; 가열하면 부서지게 되는 고무조성물과 유황화합물로 구성되는 군에서 선택된 적어도 일종의 열안정화합물로 구성되는 것을 특징으로 하는 내열성 성형물질.Thermosetting phenol resins; Fiber reinforcing material; Heat-resistant molding material, characterized in that composed of at least one thermally stable compound selected from the group consisting of a rubber composition and a sulfur compound that breaks when heated. 제1항에 있어서, 상기 열경화성 페놀수지가, 레졸, 경화제를 갖는 노블락, 경화제를 갖는 레졸과 노블락, 또는 경화제를 갖는 페놀-포름알데히드로 구성되는 군으로부터 선택된 적어도 일종의 페놀수지인 것을 특징으로 하는 내열성 성형물질.The heat-resistant phenolic resin according to claim 1, wherein the thermosetting phenol resin is at least one kind of phenol resin selected from the group consisting of resol, a noblock having a curing agent, a resol having a curing agent and a noblock, or a phenol-formaldehyde having a curing agent. Molding material. 제1항에 있어서, 상기 열경화성 페놀수지가 전체 성형물질의 15내지 40중량%인 것을 특징으로 하는 내열성 성형물질.The heat resistant molding material according to claim 1, wherein the thermosetting phenol resin is 15 to 40% by weight of the total molding material. 제1항에 있어서, 상기 섬유보강물질이 유리, 아라미드, 석면, 탄소 셀룰로즈 또는 세라믹으로 구성되는 군으로부터 선택된 적어도 일종의 섬유물질인 것을 특징으로 하는 내열성 성형물질.The heat resistant molding material according to claim 1, wherein the fiber reinforcing material is at least one kind of fiber material selected from the group consisting of glass, aramid, asbestos, carbon cellulose or ceramics. 제1항에 있어서, 상기 섬유보강물질이 분쇄된 형태 또는 절단된 가닥형태인 것을 특징으로 하는 내열성 성형물질.The heat-resistant molding material according to claim 1, wherein the fiber reinforcing material is in a pulverized form or a cut strand form. 제1항에 있어서, 상기 섬유보강물질이 전체 성형물질이 10 내지 40중량%인 것을 특징으로 하는 내열성 성형물질.The heat-resistant molding material according to claim 1, wherein the fiber reinforcing material is 10 to 40% by weight of the total molding material. 제1항에 있어서, 상기 조성물이 부타디엔고무 화합물인 것을 특징으로 하는 내열성 성형물질.The heat-resistant molding material according to claim 1, wherein the composition is a butadiene rubber compound. 제7항에 있어서, 상기 부타디엔고무 화합물이 아크릴로니트릴/ 부타디엔 공중합체 라텍스, 분말화된 아크릴로니트릴/ 부타디엔 공중합체(예비가교-결합된 것), 부타디엔/스티렌/비닐피리딘 3량중합체 라텍스, 부타디엔/ 스티렌 공중합체 라텍스 및 카르복시말단 부타디엔/스틸렌 공중합체 라텍스로 구성되는 군으로부터 선택된 적어도 일종의 부타디엔 화합물인 것을 특징으로 하는 내열성 성형물질.The method of claim 7, wherein the butadiene rubber compound is acrylonitrile / butadiene copolymer latex, powdered acrylonitrile / butadiene copolymer (pre-crosslinked), butadiene / styrene / vinylpyridine terpolymer latex, At least one butadiene compound selected from the group consisting of butadiene / styrene copolymer latex and carboxy-terminated butadiene / styrene copolymer latex. 제1항에 있어서, 상기 고무조성물이 전체성형물질의 유효중량%인 것을 특징으로 하는 내열성 성형물질.The heat resistant molding material according to claim 1, wherein the rubber composition is an effective weight% of the total molding material. 제9항에 있어서, 상기 유효한 고무조성물이 전체성형물질의 3 내지 8중량%인 것을 특징으로 하는 내열성 성형물질.10. The heat resistant molding material according to claim 9, wherein the effective rubber composition is 3 to 8% by weight of the total molding material. 제1항에 있어서, 상기 유황화합물이 분자상 유황이나 유황공여 화합물로 구성되는 군으로부터 선택된 적어도 일종의 유황화합물인 것을 특징으로 하는 내열성 성형물질.The heat-resistant molding material according to claim 1, wherein the sulfur compound is at least one sulfur compound selected from the group consisting of molecular sulfur and a sulfur donor compound. 제11항에 있어서, 상기 유황공여화합물이, 테트라메틸티우람 또는 2,2'-디티오비스멘조티아졸, 2황화모르폴린(Sulfasan R), 황화테트라메틸티우람(Unads), 6황화디펜타메틸렌티우람(Tetrone A)으로 구성되는 군으로부터 선택된 적어도 일종의 유황공여화합물인 것을 특징으로 하는 내열성 성형물질.12. The sulfur donor compound according to claim 11, wherein the sulfur donor compound is tetramethylthiuram or 2,2'-dithiobismenzothiazole, morphosulphide (Sulfasan R), tetramethylthiuram sulfide (Unads), or dipenta sulfide. At least one sulfur donor compound selected from the group consisting of methylene thiuram (Tetrone A). 제1항에 있어서, 상기 유황화합물이 전체 성형물질의 유효중량%인 것을 특징으로 하는 내열성 성형물질.The heat-resistant molding material according to claim 1, wherein the sulfur compound is an effective weight percentage of the entire molding material. 제12항에 있어서, 상기 유효유황 화합물이 전체 성형물질의 0.19 내지 1.6중량%인 것을 특징으로 하는 내열성 성형물질.13. The heat resistant molding material according to claim 12, wherein the effective sulfur compound is 0.19 to 1.6% by weight of the total molding material. 제1항에 있어서, 충전재, 경화촉진제, 이완제, 안료 및 결합제 등으로 구성되는 군으로부터 선택된 첨가물질을 함유하는 것을 특징으로 하는 내열성 성형물질.The heat-resistant molding material according to claim 1, which contains an additive selected from the group consisting of fillers, curing accelerators, relaxants, pigments, binders and the like. 열경화성 페놀수지와; 섬유보강물질과; 가열하면 취약성으로 되는 고무조성물과; 분자상 유황이나 유황공여화합물로 구성되는 군으로부터 선택된 최소 일종의 유황화합물로 구성되는 것을 특징으로 하는 내열성 성형물질.Thermosetting phenol resins; Fiber reinforcing material; A rubber composition that becomes brittle when heated; A heat resistant molding material comprising at least one sulfur compound selected from the group consisting of molecular sulfur and sulfur donor compounds. 제16항에, 상기 열경화성 페놀수지가, 경화제를 갖는 레졸, 경화제를 갖는 노볼락, 경화제를 갖는 페졸과 노볼락 또는 경화제를 갖는 페놀-포름알데히드로 구성되는 군으로부터 선택된 적어도 일종의 페놀수지인 것을 특징으로 하는 내열성 성형물질.The thermosetting phenol resin according to claim 16, wherein the thermosetting phenol resin is at least one phenol resin selected from the group consisting of resol having a curing agent, novolac having a curing agent, phenazole having a curing agent and phenol-formaldehyde having a novolak or curing agent. Heat-resistant molded material made of. 제16항에 있어서, 상기 열경화성수지가 전체 성형물질의 15내지 40중량%인 것을 특징으로 하는 내열성 성형물질.17. The heat resistant molding material according to claim 16, wherein the thermosetting resin is 15 to 40% by weight of the total molding material. 제16항에 있어서, 상기 섬유보강물질이 유리, 아라미드, 석면, 탄소, 셀루로즈 또는 세라믹으로 구성되는 군으로부터 선택된 적어도 일종의 섬유물질인 것을 특징으로 하는 내열성 성형물질.17. The heat resistant molding material according to claim 16, wherein the fiber reinforcing material is at least one kind of fiber material selected from the group consisting of glass, aramid, asbestos, carbon, cellulose or ceramic. 제16항에 있어서, 상기 섬유보강물질이 분쇄된 형태이거나 절단된 가닥형태인 것을 특징으로 하는 내열성 성형물질.17. The heat resistant molding material according to claim 16, wherein the fiber reinforcing material is in the form of pulverized or cut strands. 제16항에 있어서, 상기 섬유보강물질이 전체 성형물질의 10 내지 40중량%인 것을 특징으로 하는 내열성 성형물질.The heat resistant molding material according to claim 16, wherein the fiber reinforcing material is 10 to 40% by weight of the total molding material. 제16항에 있어서, 상기 고무조성물이 부타디엔고무 화합물인 것을 특징으로 하는 내열성 성형물질.17. The heat resistant molding material according to claim 16, wherein the rubber composition is a butadiene rubber compound. 제16항에 있어서, 상기 부타디엔 고무 화합물이, 아크릴로니트릴/부타디엔 공중합체 라텍스, 분말화된 아크릴로나트릴/부타디엔 공중합체(예비가교-결합된 것), 부타디엔/스티렌/비닐피리딘 3량중하체 라텍스, 부타디엔/스티렌 공중합체 라텍스 및 카르복시 말단 부타디엔/스티렌 공중합체 라텍스로 구성되는 군으로부터 선택된 적어도 일종의 부타디엔 화합물인 것을 특징으로 하는 내열성 성형물질.17. The butadiene rubber compound according to claim 16, wherein the butadiene rubber compound is acrylonitrile / butadiene copolymer latex, powdered acrylonitrile / butadiene copolymer (pre-crosslinked), butadiene / styrene / vinylpyridine tripolymer latex And at least one butadiene compound selected from the group consisting of butadiene / styrene copolymer latex and carboxy-terminated butadiene / styrene copolymer latex. 제16항에 있어서, 상기 고무조성물이 전체 성형물질의 유효중량%인 것을 특징으로 하는 내열성 성형물질.The heat resistant molding material according to claim 16, wherein the rubber composition is an effective weight% of the total molding material. 제24항에 있어서, 상기 유효고무 조성물이 전체 성형물질의 3 내지 8중량%인 것을 특징으로 하는 내열성 성형물질.The heat resistant molding material according to claim 24, wherein the effective rubber composition is 3 to 8% by weight of the total molding material. 제16항에 있어서, 상기 유황공여화합물이 테트라메틸티우람이나 2,2'-디티오비스벤조티아졸, 2황화모르폴린(sulfasan R), 황화테트라메틸티우람(Unads), 6황화디펜타메틸렌티우람으로 구성되는 군으로부터 선택된 적어도 일종의 유황공여화합물인 것을 특징으로 하는 내열성 성형물질.The method of claim 16, wherein the sulfur donor compound is tetramethylthiuram or 2,2'-dithiobisbenzothiazole, morphosulphide (sulfasan R), tetramethylthiuram sulfide (Unads), dipentamethylene hexasulfide At least one sulfur donor compound selected from the group consisting of thiuram. 제16항에 있어서, 상기 유황화합물이 전체 성형물질의 유효중량%인 것을 특징으로 하는 내열성 성형물질.17. The heat resistant molding material according to claim 16, wherein the sulfur compound is an effective weight% of the total molding material. 제27항에 있어서, 상기 유효유황 화합물이 전체 성형물질의 0.19 내지 1.6중량%인 것을 특징으로 하는 내열성 성형물질.28. The heat resistant molding material according to claim 27, wherein the effective sulfur compound is 0.19 to 1.6% by weight of the total molding material. 제1항에 있어서, 충전체, 경화촉진제, 이완제, 안료 및 결합제로 구성되는 군으로부터 선택된 첨가물질을 함유하는 것을 특징으로 하는 내열성 성형물질.The heat resistant molding material according to claim 1, which contains an additive selected from the group consisting of a filler, a curing accelerator, a releasing agent, a pigment and a binder. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019840006341A 1983-10-14 1984-10-13 Heat resistant molding material KR850003152A (en)

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KR100454672B1 (en) * 2001-07-12 2004-11-03 주식회사 나노코 A non-combustible Constructional Material using cold-setting phenol resin and A Method to Manufacture the said non-combustible Constructional Material

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FR2553424B1 (en) 1993-05-07
JPH0562139B2 (en) 1993-09-07
JPS60108459A (en) 1985-06-13
DE3437547C2 (en) 1994-06-23
GB2147904B (en) 1987-08-05
BE900821A (en) 1985-02-01
FR2553424A1 (en) 1985-04-19
GB2147904A (en) 1985-05-22
GB8425790D0 (en) 1984-11-21
DE3437547A1 (en) 1985-04-25

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