KR850001143A - 올레핀계모노 첨가생성물(Monoadducts of Olefines)과 이와 반응적인 텔로겐(Telogen)의 제조방법 - Google Patents
올레핀계모노 첨가생성물(Monoadducts of Olefines)과 이와 반응적인 텔로겐(Telogen)의 제조방법 Download PDFInfo
- Publication number
- KR850001143A KR850001143A KR1019840003900A KR840003900A KR850001143A KR 850001143 A KR850001143 A KR 850001143A KR 1019840003900 A KR1019840003900 A KR 1019840003900A KR 840003900 A KR840003900 A KR 840003900A KR 850001143 A KR850001143 A KR 850001143A
- Authority
- KR
- South Korea
- Prior art keywords
- telogen
- compound
- phosphorus
- olefin
- group
- Prior art date
Links
- 230000003797 telogen phase Effects 0.000 title claims 13
- 238000000034 method Methods 0.000 claims 14
- -1 phosphorus (V) compound Chemical class 0.000 claims 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 10
- 150000001336 alkenes Chemical class 0.000 claims 8
- 238000006243 chemical reaction Methods 0.000 claims 8
- 239000002184 metal Substances 0.000 claims 8
- 229910052751 metal Inorganic materials 0.000 claims 8
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 7
- 150000003839 salts Chemical class 0.000 claims 7
- 229910052742 iron Inorganic materials 0.000 claims 5
- 239000007791 liquid phase Substances 0.000 claims 5
- 239000000463 material Substances 0.000 claims 5
- 239000007788 liquid Substances 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 4
- 229910052698 phosphorus Inorganic materials 0.000 claims 4
- 239000011574 phosphorus Substances 0.000 claims 4
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 3
- 239000005977 Ethylene Substances 0.000 claims 3
- 150000001350 alkyl halides Chemical class 0.000 claims 3
- 229910052799 carbon Inorganic materials 0.000 claims 3
- 150000008064 anhydrides Chemical class 0.000 claims 2
- 239000000126 substance Substances 0.000 claims 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 229910000975 Carbon steel Inorganic materials 0.000 claims 1
- 229910001018 Cast iron Inorganic materials 0.000 claims 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims 1
- 229910001209 Low-carbon steel Inorganic materials 0.000 claims 1
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 229910000754 Wrought iron Inorganic materials 0.000 claims 1
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 125000005600 alkyl phosphonate group Chemical group 0.000 claims 1
- 125000004104 aryloxy group Chemical group 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 239000010962 carbon steel Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 125000004970 halomethyl group Chemical group 0.000 claims 1
- YVWGMAFXEJHFRO-UHFFFAOYSA-N halopropane Chemical compound FC(F)C(F)(F)CBr YVWGMAFXEJHFRO-UHFFFAOYSA-N 0.000 claims 1
- 229950000188 halopropane Drugs 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 229950011008 tetrachloroethylene Drugs 0.000 claims 1
- 125000004953 trihalomethyl group Chemical group 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C19/00—Acyclic saturated compounds containing halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
- C07C17/272—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by addition reactions
- C07C17/275—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by addition reactions of hydrocarbons and halogenated hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Polymerisation Methods In General (AREA)
- Catalysts (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (21)
- 반응활성제로서 유효한 금속철을 제공하는 물질과 포스포릴기를 가지는 포스포러스(V) 화합물로 된 반응촉진제 존재하에 텔로겐과 탁소겐과의 반응으로 구성된 탁소겐 및 탁소겐과 반응성이 있는 텔로겐 모노첨가 생성물의 제조방법.
- 제1항에 있어서, 탁소겐은 올레핀이라는 것.
- 제2항에 있어서, 올레핀은 탄화수소라는 것.
- 제1항에 있어서, 텔로겐은 알킬할라이드인 것.
- 제4항에 있어서, 알킬할라이드는 트리할로 메틸기나 터미날할로 메틸기라는 것.
- 제1항에 있어서, 텔로겐은 카본테트라할라이드나 할로포름으로 구성된 기로부터 선택된다는 것.
- 제1항에 있어서, 포스포러스화합물을 포스페이트에스테르포스포러스펜톡사이드, 포스포릴 할라이드로 구성된 기와 다음의 구조식을 가지는 포스포릴화합물로부터선택된다는 것. " T-1 " 여기에서 R7은 치환되거나 또는 치환되지 않은 하이드로 카빌기이며, R8과 R9은 하이드록시, 알콕시, 아릴옥시와 치환되거나 치환되지 않은 하이드록 카빌로 구성된 것들로부터 관계없이 선택할 수 있다는 것.
- 제7항에 있어서, 포스포러스화합물은 알킬포스페이트와 알킬포스포네이트로 구성된 것들로부터 선택된다는 것.
- 제1항에 있어서, 금속철을 제공하는 물질은 탄소강, 주철과 연철(wrought iron)로부터 선택된다는 것.
- 제1항에 있어서, 금속철을 제공하는 물질은 연강(mild steel)이라는 것.
- 텔로겐과, 포스포릴기로 구성되고 텔로겐과 양립할 수 있는 포스포러스(V) 화합물을 포함하는 반응촉진제로 구성된 액체상과 반응활성제로 유용한 금속을 제공하는 물질과 상기 액체상이 접촉하는 반응계에서 텔로겐과 올레핀을 반응시킴으로써 고분자 단쇄중합 생성물의 형성을 결과적으로 제거할 수 있는 탁소겐과 텔로겐의 모노첨가 생생물의 제조방법.
- 제11항에 있어서, 반응계는 금속을 제공하는 물질과 접촉하는 포스포러스(V) 화합물과 텔로겐으로 된 액체상으로 구성한 후 여기에 올레핀을 도입시켜 텔로겐과 반응시킴으로서 얻어진다는 것.
- 제12항에 있어서, 제2철염을 반응이 개시되기 전에 액체상에 용해시킨다는 것.
- 제13항에 있어서, 텔로겐과 반응촉진제 존재하에 금속철을 제공하는 물질을 가열시켜 올레핀이 도입되기 전에 제2철염을 제조한다는 것.
- 제13항에 있어서, 제2철염은 실질적으로 무수물이라는 것.
- 제13항에 있어서, 포스포러스(V) 화합물은 제2철염에 대하여 처음부터 과잉몰 존재한다는 것.
- 제16항에 있어서, 액체혼합물은 카본테트라할라이드, 포스포러스(V) 화합물과 염화 제2철로 제조하고, 이 액체 혼합물에 에틸렌과 프로필렌으로 구성된 그룹으로 부터 선택된 올레핀으로 된 가스를 도입하고, 올레핀을 금속철을 제공하는 물질의 존재하에서 카본테트라할라이드와 반응시켜 모노첨가 생성물을 제조한다는 것.
- 제17항에 있어서, 올레핀은 에틸렌과 1,1,1,3-테트라 할로프로판으로 구성된 모노첨가 생성물로 구성된다는 것.
- 제17항에 있어서, 액체 혼합물은 사염화탄소, 포스포러스 화합물과 무수염화 제2철을 혼합함으로써 얻어진다는 것.
- 제17항에 있어서, 올레핀은 에틸렌과 사염화탄소로 된 텔로겐 이라는 것.
- 제17항에 있어서, 무수 제2철염은 액체상에 용해된다는 것.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US51113083A | 1983-07-06 | 1983-07-06 | |
| US511130 | 1995-08-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR850001143A true KR850001143A (ko) | 1985-03-16 |
Family
ID=24033575
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019840003900A KR850001143A (ko) | 1983-07-06 | 1984-07-05 | 올레핀계모노 첨가생성물(Monoadducts of Olefines)과 이와 반응적인 텔로겐(Telogen)의 제조방법 |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP0131561B1 (ko) |
| JP (1) | JPS6036428A (ko) |
| KR (1) | KR850001143A (ko) |
| AT (1) | ATE22877T1 (ko) |
| AU (1) | AU3031784A (ko) |
| DE (1) | DE3460965D1 (ko) |
| DK (1) | DK329884A (ko) |
| HU (1) | HUT34421A (ko) |
| IL (1) | IL72320A0 (ko) |
| ZA (1) | ZA845182B (ko) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100969939B1 (ko) * | 2008-12-26 | 2010-07-14 | 한전원자력연료 주식회사 | 핵연료 피복관 내면 코팅장치 |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3511153A1 (de) * | 1985-03-27 | 1986-10-02 | Wacker-Chemie GmbH, 8000 München | Verfahren zur herstellung von verbindungen mit mehrfach durch chlor substituiertem alkylrest |
| JP2000086545A (ja) * | 1998-09-18 | 2000-03-28 | Asahi Glass Co Ltd | １，１，１，３，３−ペンタクロロプロパンの製造方法 |
| DE60011118T2 (de) | 1999-10-06 | 2005-07-07 | Solvay (Société Anonyme) | Verfahren zur herstellung von halogenierten kohlenwasserstoffen |
| US6313360B1 (en) * | 2000-09-29 | 2001-11-06 | Vulcan Materials Company | Process for the manufacture of 1, 1, 1, 3, 3-pentachloropropane |
| US6500995B1 (en) * | 2001-06-14 | 2002-12-31 | Vulcan Chemicals | Water-enhanced production of 1,1,1,3,3,-pentachloropropane |
| US7094936B1 (en) | 2001-07-20 | 2006-08-22 | Great Lakes Chemical Corporation | Process for preparing halogenated alkanes |
| US20040225166A1 (en) * | 2003-05-05 | 2004-11-11 | Vulcan Chemicals A Business Group Of Vulcan Materials Company | Method for producing 1,1,1,3-tetrachloropropane and other haloalkanes with iron catalyst |
| JP4723920B2 (ja) * | 2005-06-08 | 2011-07-13 | 積水化学工業株式会社 | アンカーボルト位置決め装置 |
| US9738577B2 (en) | 2006-10-11 | 2017-08-22 | Honeywell International Inc. | Process for the manufacture of 1,1,1,3,3-pentachloropropane |
| JP4838281B2 (ja) * | 2008-04-25 | 2011-12-14 | ミサワホーム株式会社 | シース管保持治具 |
| US8877990B2 (en) * | 2009-06-24 | 2014-11-04 | Tokuyama Corporation | Process of making a chlorinated hydrocarbon |
| US8586804B2 (en) * | 2010-12-01 | 2013-11-19 | E. I. Du Pont De Nemours And Company | Synthesis of 1,1,3-trichloro-1-propene |
| US8835702B2 (en) * | 2011-06-03 | 2014-09-16 | Honeywell International Inc. | Method for mitigating the formation of by-products during the production of haloalkane compounds |
| US9289758B2 (en) | 2013-01-22 | 2016-03-22 | Axiall Ohio, Inc. | Processes for producing chlorinated hydrocarbons and methods for recovering polyvalent antimony catalysts therefrom |
| US8889930B2 (en) * | 2013-01-22 | 2014-11-18 | Axiall Ohio, Inc. | Process for producing chlorinated hydrocarbons |
| US8889927B2 (en) * | 2013-03-12 | 2014-11-18 | Honeywell International Inc. | Method to reduce the formation of high boiling compounds during the dehydrochlorination of 1,1,1,3-tetrachloropropane |
| US9139497B2 (en) | 2013-10-23 | 2015-09-22 | Axiall Ohio, Inc. | Process for producing chlorinated hydrocarbons in the presence of a polyvalent bismuth compound |
| US9896400B2 (en) | 2014-10-16 | 2018-02-20 | Spolek Pro Chemickou A Hutni Vyrobu A.S. | Process for producing a chlorinated C3-6 alkane |
| JP7168321B2 (ja) | 2014-10-16 | 2022-11-09 | スポレク プロ ヘミコウ アー フツニ ブイロブ，アクツィオバ スポレチェノスト | 方法 |
| WO2016064809A1 (en) | 2014-10-22 | 2016-04-28 | Axiall Ohio, Inc. | Process for producing chlorinated hydrocarbons in the presence of a polyvalent molybdenum compound |
| CN106146247A (zh) * | 2015-03-24 | 2016-11-23 | 中化近代环保化工(西安)有限公司 | 一种连续法制备1,1,1,3-四氯丙烷的工艺方法 |
| JP7017555B2 (ja) * | 2016-07-26 | 2022-02-08 | オキシデンタル ケミカル コーポレーション | 塩素化プロパンの製造、調整、及び精製方法 |
| CN116265097A (zh) * | 2021-12-17 | 2023-06-20 | 中国科学院宁波材料技术与工程研究所 | 用于气固相反应连续生产1,1,1,3-四氯丙烷的催化剂、其制备方法与应用 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2658930A (en) * | 1949-03-22 | 1953-11-10 | Universal Oil Prod Co | Production of polyhaloalkanes |
| JPS5259103A (en) * | 1975-11-10 | 1977-05-16 | Shin Etsu Chem Co Ltd | Process for preparation of tetrachloroalkane |
-
1984
- 1984-07-04 DE DE8484870094T patent/DE3460965D1/de not_active Expired
- 1984-07-04 EP EP84870094A patent/EP0131561B1/en not_active Expired
- 1984-07-04 AT AT84870094T patent/ATE22877T1/de active
- 1984-07-05 KR KR1019840003900A patent/KR850001143A/ko not_active IP Right Cessation
- 1984-07-05 HU HU842649A patent/HUT34421A/hu unknown
- 1984-07-05 AU AU30317/84A patent/AU3031784A/en not_active Abandoned
- 1984-07-05 JP JP59138113A patent/JPS6036428A/ja active Pending
- 1984-07-05 ZA ZA845182A patent/ZA845182B/xx unknown
- 1984-07-05 DK DK329884A patent/DK329884A/da not_active Application Discontinuation
- 1984-07-06 IL IL72320A patent/IL72320A0/xx unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100969939B1 (ko) * | 2008-12-26 | 2010-07-14 | 한전원자력연료 주식회사 | 핵연료 피복관 내면 코팅장치 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3460965D1 (en) | 1986-11-20 |
| DK329884D0 (da) | 1984-07-05 |
| ZA845182B (en) | 1985-03-27 |
| EP0131561A1 (en) | 1985-01-16 |
| EP0131561B1 (en) | 1986-10-15 |
| JPS6036428A (ja) | 1985-02-25 |
| IL72320A0 (en) | 1984-11-30 |
| ATE22877T1 (de) | 1986-11-15 |
| HUT34421A (en) | 1985-03-28 |
| AU3031784A (en) | 1985-01-10 |
| DK329884A (da) | 1985-01-07 |
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