KR840007737A - 다성분 무용매 실리콘 탈형 피복 조성물 - Google Patents

다성분 무용매 실리콘 탈형 피복 조성물 Download PDF

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KR840007737A
KR840007737A KR1019840000176A KR840000176A KR840007737A KR 840007737 A KR840007737 A KR 840007737A KR 1019840000176 A KR1019840000176 A KR 1019840000176A KR 840000176 A KR840000176 A KR 840000176A KR 840007737 A KR840007737 A KR 840007737A
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유진 그레노블(외 1) 머리스
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샘슨 헬프고트
제네랄 일렉트릭 캄파니
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Abstract

내용 없음.

Description

다성분 무용매 실리콘 탈형 피복 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (21)

  1. (a) 100중량부의 성분 A를 5내지 100부의 성분 B 및 3내지 10부의 성분 C와 혼합시키고, (여기서, 성분 A는 올레핀 오가노폴리실록산 또는 실란올말단 오가노폴리실록산 기본중합체이고. 성분 B는 비닐실리콘 유체에 분산시킨 귀금속 또는 귀금속 착화물 촉매이며, 성분 C는 오가노하이드로겐 폴리실록산 가교 결합제이다) ; (b) 성분 A, 성분 B 및 성분 C로 이루어진 혼합물을 적당한 지질상에 피복시키고 ; (c) 언급된 기질상의 피복을 경화시키는 단계로 이루어짐을 특징으로 하여 실리콘 탈형 피복조성물이 경화된 기질을 제조하는 방법.
  2. 제1항에 있어서, 언급된 기본 중합체가 하기 일반식(I)의 구조적 유니트를 갖는 올레핀 오가노폴리실록산(25℃에서의 점도 약 10 내지 약 5,000 센티포이즈)이거나, 하기 일반식(Ia)의 실란을 말단오가노폴리실록산(25℃에서의 점도 : 약 10 내지 5,000 센티포이즈)인 제조 방법 :
    상기식에서, R은 C-Si 결합에 의하여 실리콘 원자에 결합되는 탄소수 1내지 30의 유기 라디칼로서, 1가의 탄화수소라디칼, 할로겔화 1가의 탄화수소라디칼, 및 시아노알킬 라디칼 및 이들의 혼합물로부터 선택되며, R1은 1내지 20개의 탄소원자를 갖는 올레핀계 탄화수소 라디칼이며, a는 0내지 3이고, b는 약 0.005 내지 약2.0(단, a와 b의 합은 0.8 내지 3이다)이며, X는 실란올 말단 오가노폴리실록산의 25℃에서의 점도가 약 10내지 5,000 센티포이즈가 될 수 있는 값이다.
  3. 제1항에 있어서, 언급된 오가노하아드로겐 폴리실록산 가교결합제가 하기 일반식(II)의 구조적 유니트를 가지며, 25℃에서의 점도가 약 10내지 5,000 센티포이즈인 제조방법 ;
    상기식에서, R은 1가의 탄화수소라디칼, 할로겐화 1가의 탄화수소 라디칼, 및 시아노 알킬라디칼 및 이들의 혼합물로 부터 선택되는 탄소수 1내지 30의 유기라디칼이며, a는 0내지 3이고, b는 약 0.005 내지 약 2.0(단, a와 b의 합은 0.8 내지 3이다)이다.
  4. 제2항에 있어서, R이 메틸인 제조방법.
  5. 제3항에 있어서, R이 메틸인 제조방법.
  6. 제2항에 있어서, R1이 비닐 또는 알릴인 제조방법.
  7. 제1항에 있어서, 언급된 올레핀 오가노폴리실록산이 최고 2.5중량%까지의 비닐을 함유하는 디메틸비닐 말단디메틸메틸비닐폴리실록산 공중합체 유체(25℃에서의 점도 100 내지 1,000 센티포이즈)인 제조방법
  8. 제1항에 있어서, 언급된 오가노하이드로겐 폴리실록산이 약 0.1 내지 1.67중량%의 수소를 함유하는 트리메틸 말단 메틸하이드로겐 폴리실록산 유체(25℃에서의 점도 : 약 10 내지 500 센티포이즈)인 제조방법.
  9. 제1항에 있어서, 언급된 귀금속 촉매가 플라티늄금속, 로듐금속, 플라티늄금속의 착화물 및 로듐금속의 착화물인 제조방법.
  10. 제9항에 있어서, 언급된 귀금속촉매가 기본중합체 1,000,000부당 약 5내지 500부의 플라티늄 또는 로듐금속이 제공되기에 충분한 양으로 존재하는 제조방법.
  11. 제1항에 있어서, 성분 A, 성분 B 및 성분 C의 혼합물 100부에 0.1 내지 5부의 성분 D(여기서, 성분 D는 주위온도에서 하이드로실레이션 경화반응의 억제에는 효과적이지만, 상승된 온도에서의 언급된 반응은 억제하지 않는 억제제이다)를 혼합시키는 단계를 추가로 포함하는 제조방법.
  12. 제11항에 있어서, 언급된 억제제가 불포화탄소를 함유하는 디알킬카복실에스테르, 아세틸렌 그룹을 함유하는 화합물, 지방족, 알콜의 올레핀계 카복실산 에스테르(여기서, 지방족알콜은 1내지 4개의 탄소원자를 가지며, 올레핀계 카복실산은 2내지 10개의 탄소 원자를 갖는다), 알케닐 이소시아누레이트(여기서, 알케닐 그룹은 3내지 8개의 탄소원자를 갖는다), 디알킬아세틸렌디카복실레이트 및 불포화탄소를 함유하는 디알킬 카복실에스테르와 지방족 알콜의 올레핀계 카복실산 에스테르의 혼합물(여기서, 지방족 알콜은 1내지 4개의 탄소 원자를 가지며, 올레핀계 카복실산은 2내지 10개의 탄소 원자를 갖는다.)로 부터 선택되는 제조방법.
  13. 제11항에 있어서, 언급된 억제제가 불포화 탄소를 함유하는 디알킬 카복실 에스테르와 지방족 알콜의 올레핀계 카복실산 에스테르(여기서, 지방족 알콜은 1내지 4개의 탄소원자를 가지며, 올레핀계 카복실산은 2내지 10개의 탄소자원를 갖는다)의 혼합물인 제조방법.
  14. 제13항에 있어서, 언급된 디알킬카복실 에스테르가 디알릴말레에이트 ; 부틸알릴말레에이트, 디알릴석 시네이트 ; 및 디메틸말레에이트, 디에틸 말레에이트 및 실일말레에이트로 부터 선택된 말레산의 디알킬에스테르로부터 선택되는 제조방법.
  15. 제13항에 있어서, 언급된 지방족 알콜의 올레핀계 카복실산 에스테르가 비닐 아세테이트인 제조방법.
  16. 제13항에 있어서, 언급된 디알킬 카복실 에스테르와 지방족 알콜의 올레핀계 카복실산 에스테르를 약 1 : 24내지 약 1 : 1로 혼합시키는 제조방법.
  17. 제13항에 있어서, 언급된 디알킬 카복실 에스테르와 지방족 알콜의 올레핀계 카복실산 에스테르를 약 1 : 3의 비율로 혼합시키는 제조방법.
  18. 제13항에 있어서, 언급된 디알릴말레에이트와 비닐 아세테이트를 약 1 : 3의 비율로 혼합시키는 방법.
  19. 제11항에 있어서, 혼합물에 약 0.05 내지 2중량%량으로 존재하기에 충분한 억제제가 성분 D에 존재하는 제조방법.
  20. 제1항에 있어서, 성분 A, 성분 B 및 성분 C의 혼합물 100부에 0.1 내지 10부의 성분 E(여기서 성분 E는 언급된 부가 경화성 탈형피복조성물의 경화촉진에 효과적인 비닐 고무 경화촉진제이며, 고무의 평균분자량은 약 200,000 내지 400,000이다)를 혼합시키는 단계를 추가로 포함하는 제조방법.
  21. 제20항에 있어서, 언급된 고무가 부가 경화성 탈형피복조성물의 0.5중량% 이상의 량으로 혼합물에, 존재하는 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019840000176A 1983-01-17 1984-01-17 다성분 무용매 실리콘 탈형 피복 조성물 KR840007737A (ko)

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US06/458,421 US4448815A (en) 1983-01-17 1983-01-17 Multi-component solventless silicone release coating system

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AU2353584A (en) 1984-07-19
FI840154A0 (fi) 1984-01-16
JPH0136871B2 (ko) 1989-08-02
DE3470550D1 (en) 1988-05-26
EP0116290B1 (en) 1988-04-20
US4448815A (en) 1984-05-15
FI840154A (fi) 1984-07-18
ATE33667T1 (de) 1988-05-15
EP0116290A1 (en) 1984-08-22
JPS59149961A (ja) 1984-08-28

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