KR880000520A - 유연재료 피복용 중첨가 유기폴리실록산 조성물 - Google Patents

유연재료 피복용 중첨가 유기폴리실록산 조성물 Download PDF

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KR880000520A
KR880000520A KR1019870006291A KR870006291A KR880000520A KR 880000520 A KR880000520 A KR 880000520A KR 1019870006291 A KR1019870006291 A KR 1019870006291A KR 870006291 A KR870006291 A KR 870006291A KR 880000520 A KR880000520 A KR 880000520A
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South Korea
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composition
organopolysiloxane
radicals
organopolysiloxane composition
per unit
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KR1019870006291A
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English (en)
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까베쟌 쟈끄
포 알랭
솔다 앙드레
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쟝-루이쓰네
롱-쁠랑 쉬미
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Publication of KR880000520A publication Critical patent/KR880000520A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/549—Silicon-containing compounds containing silicon in a ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/12—Polysiloxanes containing silicon bound to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/24—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen halogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/70—Siloxanes defined by use of the MDTQ nomenclature

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Paper (AREA)

Abstract

내용 없음

Description

유연재료 피복용 중첨가 유기폴리실록산 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 히드로실릴화 반응에 의해 얇은막내에서 교차 결합을 형성할 수 있는, 유연재료 피복용 유기폴리실록산 조성물에 있어서, A) 단위분자당 2개 이상의 SiVi기를 함유하는 1종 이상의 유기폴리실록산, B) 단위분자당 3개 이상의 SiH기를 함유하는 1종 이상의 유기히드로폴리실록산, 및 C) 백금군 금속 화합물인 히드로실릴화촉매의 촉매학적 유효량으로 이루어지며, 및 조성물내에 존재하는 SiVi기수의 0.5-60%, 바람직하기로는 1.5~20%가 하기 일반식을 갖는 비닐화 시클로트리실록산으로부터 유래된 것임으로 특징으로 하는 유기폴리실록산 조성물.
    〔R(CH2=CH)SiO〕3
    (식중, R은 C1~C4알킬 라디칼, 페닐 라디칼 및 3,3,3-트리플루오로프로필 라디칼로부터 선택되며, 바람직하기로는 메틸라디칼이다)
  2. 제1항에 있어서, 일반식(Ⅰ)내에서 R이 메틸 라디칼임을 특징으로 하는 유기폴리실록산 조성물.
  3. 제1 또는 2항에 있어서, 문-용매 상태의 조성물로서 성분(A) 및 (B)의 점도가 조성물의 점도가 40~5.00mPa가 되도록 선택되며, 및 조성물이 부가적으로, D) 주변온도에서 겔의 형성을 방지하는데 유효하나 교차 결합 처리 동안 히드로실릴화 반응을 억제하기에는 불충분한 양의억제제를 함유함을 특징으로 하는 유기폴리실록산 조성물.
  4. 제1 또는 2항에 있어서, 실리콘과 병용 가능한 유기용매내에 분산된 상태임을 특징으로 하는 유기폴리실록산 조성물.
  5. 제1 또는 2항에 있어서, 수화 에멀션 상태임을 특징으로 하는 유기폴리실록산 조성물.
  6. 제1 또는 2항에 있어서, 25℃에서 1~100mPa의 점도 및 1~10%의 OH 중량 함량을 갖는 알파, 오메가-디히드록시디메틸폴리실록산 오일을 성분(A) 100중량부당 0.1~5중량부 함유함을 특징으로 하는 유기폴리실록산 조성물.
  7. 히드로실릴화 반응에 의해 얇은막내에서 교차 결합을 형성할 수 있는, 유연 재료 피복용 유기폴리실록산 조성물에 있어서, A) 단위 분자당 2개 이상의 SiVi기를 함유하는 1종 이상의 유기폴리실록산, B) 단위 분자당 3개 이상의 SiH기를 함유하는 1종 이상의 유기히드로폴리실록산, 및 C) 백금군 금속 화합물인 히드로실릴화 촉매의 촉매학적 유효량을 함유하며, 조성물내의 SiVi기들의 수의 0.5~60%, 바람직하기로는 1.5~20%가 일반식〔R(CH2=CH)SiO〕3(식중, R은 알킬 라디칼, 페닐 라디칼 및 3,3,3-트리플루오로프로필라디칼로부터 선택되며, 바람직하기로는 메틸 라디칼이다)을 갖는 비닐화 시클로트리실록산으로부터 유래된 것임을 특징으로 하는 유기폴리실록산 조성물을 피복시키고자 하는 표면 단위 m2당 0.1~10g의 양으로 도포하고, 이어서 상기 조성물을 교차 결합시킴을 특징으로 하는 유연재료의 시이트로 하여금 통상적으로 그들이 부착되기 쉬운 표면에 대하여 비부착성을 갖도록 하는 방법.
  8. 히드로실릴화 반응에 의해 얇은막내에서 교차 결합을 형성할 수 있는, 유연재료 피복용 유기폴리실록산 조성물에 있어서, A) 단위 분자당 2개 이상의 SiVi기를 함유하는 1종 이상의 유기폴리실록산, B) 단위 분자당 3개 이상의 SiH기를 함유하는 1종 이상의 유기히드로폴리실록산, 및 C) 백금군 금속 화합물인 히드로실릴화 촉매의 촉매학적 유효량을 함유하며, 조성물내의 SiVi기들의 수의 0.5~60%, 바람직하기로는 1.5~20%가 일반식〔R(CH2=CH)SiO〕3(식중, R은 알킬 라디칼, 페닐 라디칼 및 3,3,3-트리플루오로프로필 라디칼로부터 선택되며, 바람직하기로는 메틸 라디칼이다)을 갖는 비닐화 시클로트리실록산으로부터 유래된 것임을 특징으로 하는 유기폴리실록산 교차결합된 조성물로 피복시킨 유연재료.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870006291A 1986-06-24 1987-06-20 유연재료 피복용 중첨가 유기폴리실록산 조성물 KR880000520A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR86/09311 1986-06-24
FR8609311A FR2600661B1 (fr) 1986-06-24 1986-06-24 Compositions organopolysiloxanes polyaddition pour l'enduction de materiaux souples

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KR880000520A true KR880000520A (ko) 1988-03-26

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EP (1) EP0252858A1 (ko)
JP (1) JPS636054A (ko)
KR (1) KR880000520A (ko)
AR (1) AR245751A1 (ko)
AU (1) AU7456487A (ko)
BR (1) BR8703172A (ko)
FI (1) FI872777A (ko)
FR (1) FR2600661B1 (ko)
NO (1) NO872597L (ko)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2600660B1 (fr) * 1986-06-24 1988-11-18 Rhone Poulenc Chimie Emulsions aqueuses de compositions organopolysiloxane polyaddition pour l'enduction de materiaux souples
US5225283A (en) * 1987-04-24 1993-07-06 Allied-Signal Inc. Coating for protecting a carbon-carbon composite from oxidative degradation
FR2619388A1 (fr) * 1987-08-14 1989-02-17 Rhone Poulenc Chimie Article stratifie souple pour adhesif de transfert
FR2624873B1 (fr) * 1987-12-18 1992-01-10 Rhone Poulenc Chimie Particules composites magnetisables a base d'organopolysiloxane reticule, leur procede de preparation et leur application en biologie
JPH0791471B2 (ja) * 1988-11-25 1995-10-04 東レ・ダウコーニング・シリコーン株式会社 剥離性皮膜形成用オルガノポリシロキサン組成物
JP2808001B2 (ja) * 1988-11-25 1998-10-08 東レ・ダウコーニング・シリコーン株式会社 剥離性硬化皮膜形成用オルガノポリシロキサン組成物
US4865911A (en) * 1989-01-09 1989-09-12 Dow Corning Corporation Curable silicone coated gasket and composition
DE19618718B4 (de) * 1996-05-09 2005-01-13 3M Espe Ag Verfahren zur Anmischung von Abformmassen
WO2020035149A1 (de) * 2018-08-17 2020-02-20 Wacker Chemie Ag Vernetzbare organosiloxan-zusammensetzungen

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5232393B2 (ko) * 1972-11-22 1977-08-20
US4057596A (en) * 1973-06-11 1977-11-08 Shinetsu Chemical Company Anti-sticking silicone compositions of non-solvent type
JPS50132062A (ko) * 1974-04-08 1975-10-18
US4472563A (en) * 1984-02-06 1984-09-18 Dow Corning Corporation Heat curable silicones having improved room temperature stability

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Publication number Publication date
AR245751A1 (es) 1994-02-28
NO872597D0 (no) 1987-06-22
FR2600661A1 (fr) 1987-12-31
BR8703172A (pt) 1988-03-08
EP0252858A1 (fr) 1988-01-13
FR2600661B1 (fr) 1988-11-10
FI872777A (fi) 1987-12-25
JPS636054A (ja) 1988-01-12
FI872777A0 (fi) 1987-06-23
NO872597L (no) 1987-12-28
AU7456487A (en) 1988-01-07

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