KR840006749A - N-설포닐-이미노-티오카르본산 디에스테르를 함유하는 해독제 조성물 - Google Patents

N-설포닐-이미노-티오카르본산 디에스테르를 함유하는 해독제 조성물 Download PDF

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KR840006749A
KR840006749A KR1019830005726A KR830005726A KR840006749A KR 840006749 A KR840006749 A KR 840006749A KR 1019830005726 A KR1019830005726 A KR 1019830005726A KR 830005726 A KR830005726 A KR 830005726A KR 840006749 A KR840006749 A KR 840006749A
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퇴플 베르너
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아놀드 자일러 에른스트 알테르
시바 가이기 에이 지
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Abstract

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Description

N-설포닐-이미노-티오카르본산 디에스테르를 함유하는 해독제 조성물
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Claims (10)

  1. 해독성이 있는 하기식(Ⅰ)의 N-설포닐-이미노-티오카르본산디 에스테르와 불활성 첨가제 및 보호성이 필요한 제초제로 구성된, 제초제의 식물독성으로부터 벼작물을 보호하기 위한 해독제 조성물.
    상기식에서, n은 0,1,2 또는 3, R은할로겐,시아노,니트로,Y-C1-C4-알킬, -Y-C3-C6-알케닐, -Y-C3-C6-알키닐, -Y-페닐 또는 -Y-아랄킬 라디칼인데 각각은 할로겐, 시아노, 니트로,C1-C4-알콕시, C1-C4-알콕시 카르보닐, 카르바모일, 설파모일, C1-C4-모노 또는 디알킬 카르바모일, C1-C4-모노-또는 디알킬 설파모일로 치환되거나 치환되지 않는다. 또는 -COOR3, -NR3R4, -Conr3R4, -NHCONR3R 또는 -SO2NR3R4라디칼 이거나 또는 이웃되는 2개의 R들은 3-4-원소의 포화 또는 불포화 탄화수소 사슬을 형성하는데 이러한 사슬원소들은 산소 또는 황으로 1번 혹은 질소에 의하여 1-3번 치환된다.
    R1과 R2는 독자적으로 각각 C1-C4-알킬, C3-C6-알케닐, C3-C6-알키닐, 페닐 또는 알킬기인데 각각은 할로겐, 사아노, 니트로, C1-C4-알킬, C1-C4-할로알킬, C1-C4알콕시로 치환되거나 되지 않으며, 또는 R1과 R2중 1개는 수소이거나 탄소에 의해 포화 또는 불포화된 5-또는 6-원소의 헤테로고리인데 1-3에테로 원자를 함유하며 벤젠고리에 고리모양으로 연결될 수 있는데 할로겐 및/혹은 메틸로 치환될 수 있다.
    R3은 C1-C4-알킬, C3-C6-알케닐, C3-C6-알키닐 또는 C3-C6-시클로알케닐기인데 각각은 할로겐, 시아노, 니트로, 또는 C1-C4-알킬로 치환될 수 있다. R4는 할로겐, R3과 같거나 페닐 또는 아딩킬인데 할로겐, 시아노, 니트로, C1-C4-알킬, C1-C4-할로알킬 또는 C1-C4-알콕시로 치환되거나, R3과 R4는 질소원자와 함께 5-6-원소의 포화 또는 불포화 헤테로 고리를 형성하는데 고리원소로서 산소, 황, 질소 또는 메틸이미노기를 함유하기도 한다. X는 산소 또는 황, Y는 직접 결합 또는 산소, 황, 설피닐, 설포닐, 이미노 또는 메틸이미노다리.
  2. 제1항에 있어서, 최소한 1개의 X가 황이고 R, R1,R2와 n이 상기 정의된 것과 같은 식(Ⅰ)의 N-설포닐-이미노-티오카르 본산디에스테르를 해독제로 함유하는 조성물.
  3. 제1항에 있어서, X가 황이고 n이 1또는 2, R, R1,과 R2가 상기 정의된것과 같은 식(Ⅰ)의 N-설포닐-이미노-티오카르본산 디에스테르를 해독제로 함유하는 조성물.
  4. 제1항에 있어서, n이 0, 1, 2 또는 3, R은 설포닐기의 파라-또는 메타위치에 있으며, 할로겐, 시아노, C1-C4-알킬, C1-C4-할로알킬, C1-C4-알콕시, C1-C4-할로알콕시, C1-C4-알킬티오, C1-C4-알킬설포닐, 설프아모일 또는 C1-C4-디알킬 설포아모일, R1과 R2는 각각 독자적으로 C1-C4-알킬, C2-C5-알콕시 알킬, C1-C4-할로알킬, C3-C6-알케닐, C3-C6-할로알케닐 또는 C3-C6-알키닐, X는 산소 또는 황인 식(Ⅰ)의 N-설포닐-이미노-티오카르본산 디에스테르를 해독제로 함유하는 조성물.
  5. 제1항에 있어서, X가 황, n이 1 또는 2, R이 설포닐기의 파라- 또는 메타-위치에 있으며 R1과 R2가 제1항에서 정의된 것과 같은 식(Ⅰ)의 N-설포닐-이미노-티오카르본산 디에스테르를 해독제로 함유하는 조성물.
  6. 제1항에 있어서, X가 황, n이 1 또는 2, R이 할로겐 또는 -Y-C1-C4-알킬, -Y-C1-C4-할로알킬, 시아노 또는 니트로, Y는 직접결합 또는 산소, R1과 R2가 제1항에서 정의된 것과 같은 식(Ⅰ)의 N-설포닐-이미노-티오카르본산 디에스테르를 해독제로 함유하는 조성물.
  7. 제1항에 있어서, X가 황, R1과 R2가 각각 메틸, R과 n이 제1항에서 정의된 것과 같은 식(Ⅰ)의 N-설포닐-이미노-티오카르본산 디에스테르를 해독제로 함유하는 조성물.
  8. 제1항에 있어서 N-(4-클로로벤젠설포닐)-이미노-디티오카르본산 디메틸에스테르를 해독제로 함유하는 조성물.
  9. 제1항에 있어서 N-(4-브로모벤젠설포닐)-이미노-디티오카르본산 디에스테르를 해독제로 함유하는 조성물.
  10. 제1항에 있어서 N-(3,4-디클로로벤젠설포닐)-이미노-디티오카르본산 디에스테르를 해독제로 함유하는 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019830005726A 1982-12-03 1983-12-03 해독제로서 n-설포닐-이미노-티오카르본산 디에스테르를 함유하는 제초제 조성물 KR940001945B1 (ko)

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CH704882 1982-12-03
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DE3731053A1 (de) * 1987-09-16 1989-03-30 Bayer Ag Sulfonyliso(thio)harnstoffe sowie ein verfahren und neue zwischenprodukte zu ihrer herstellung
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US5175289A (en) * 1989-01-11 1992-12-29 Ciba-Geigy Corporation 1,2,4-triazolo-[1,5a]pyrimidin-2-yl derivatives
BR9200508A (pt) * 1991-02-15 1992-10-20 Kumiai Chemical Industry Co Composicao herbicida na forma de solucao estavel ou concentrado emulsificavel de propanil
DE19532061A1 (de) * 1995-08-31 1997-03-06 Bayer Ag N-Sulfonyliminodithioverbindungen
WO2006082051A1 (en) * 2005-02-04 2006-08-10 Syngenta Participations Ag Process for the control of undesired plant growth in rice
US8165186B2 (en) * 2005-08-12 2012-04-24 Qualcomm Incorporated Channel estimation for wireless communication
US11219216B2 (en) 2015-04-02 2022-01-11 The Board Of Trustees Of The University Of Arkansas Method of improving tolerance of plants to herbicides using seed insecticide treatments
EP4043434A1 (en) 2021-02-10 2022-08-17 Karl-Franzens-Universität Graz Novel sulfonylimines

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MA19962A1 (fr) 1984-07-01
KR940001945B1 (ko) 1994-03-12
PH22662A (en) 1988-11-14
US4740236A (en) 1988-04-26
DK555883D0 (da) 1983-12-02
EP0112289B1 (de) 1987-09-09
AU559777B2 (en) 1987-03-19
EP0112289A1 (de) 1984-06-27
ES527724A0 (es) 1985-12-01
DK555883A (da) 1984-06-04
IL70358A (en) 1988-03-31
GR79433B (ko) 1984-10-22
IL70358A0 (en) 1984-03-30
AU2189283A (en) 1984-06-07
JPS59110601A (ja) 1984-06-26
JPH0545561B2 (ko) 1993-07-09
ES8602643A1 (es) 1985-12-01
OA07601A (fr) 1985-03-31
CA1208925A (en) 1986-08-05
BR8306652A (pt) 1984-07-10
NZ206468A (en) 1985-09-13
ZA838993B (en) 1984-10-31
DE3373404D1 (en) 1987-10-15
ATE29365T1 (de) 1987-09-15

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