KR840006491A - 인산에스테르 조성물 및 그 제조 방법 - Google Patents
인산에스테르 조성물 및 그 제조 방법 Download PDFInfo
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- KR840006491A KR840006491A KR1019830004891A KR830004891A KR840006491A KR 840006491 A KR840006491 A KR 840006491A KR 1019830004891 A KR1019830004891 A KR 1019830004891A KR 830004891 A KR830004891 A KR 830004891A KR 840006491 A KR840006491 A KR 840006491A
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- Prior art keywords
- alkyl
- phenyl
- halogen
- substituted
- alkoxy
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- -1 Phosphate ester Chemical class 0.000 title claims 8
- 238000004519 manufacturing process Methods 0.000 title claims 4
- 229910019142 PO4 Inorganic materials 0.000 title 1
- 239000010452 phosphate Substances 0.000 title 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 19
- 229910052736 halogen Inorganic materials 0.000 claims 11
- 150000002367 halogens Chemical class 0.000 claims 11
- 229910052739 hydrogen Inorganic materials 0.000 claims 8
- 239000001257 hydrogen Substances 0.000 claims 8
- 150000003839 salts Chemical class 0.000 claims 8
- 239000002253 acid Substances 0.000 claims 7
- 125000000217 alkyl group Chemical group 0.000 claims 7
- 150000002431 hydrogen Chemical class 0.000 claims 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 6
- 125000003943 azolyl group Chemical group 0.000 claims 6
- 150000001875 compounds Chemical class 0.000 claims 6
- 229910052760 oxygen Inorganic materials 0.000 claims 6
- 239000001301 oxygen Substances 0.000 claims 6
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 5
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 4
- 125000005843 halogen group Chemical group 0.000 claims 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 4
- 229910052717 sulfur Inorganic materials 0.000 claims 4
- 239000011593 sulfur Substances 0.000 claims 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 3
- 150000003863 ammonium salts Chemical group 0.000 claims 3
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 claims 3
- 239000002184 metal Substances 0.000 claims 3
- 238000000034 method Methods 0.000 claims 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 2
- 235000010290 biphenyl Nutrition 0.000 claims 2
- 239000004305 biphenyl Substances 0.000 claims 2
- 125000006267 biphenyl group Chemical group 0.000 claims 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 2
- 229910052794 bromium Inorganic materials 0.000 claims 2
- 229910052801 chlorine Inorganic materials 0.000 claims 2
- 239000000460 chlorine Chemical group 0.000 claims 2
- 150000004696 coordination complex Chemical group 0.000 claims 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims 2
- 125000001624 naphthyl group Chemical group 0.000 claims 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims 2
- 229920006395 saturated elastomer Polymers 0.000 claims 2
- 150000003464 sulfur compounds Chemical class 0.000 claims 2
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 claims 1
- 125000002373 5 membered heterocyclic group Chemical group 0.000 claims 1
- 125000004070 6 membered heterocyclic group Chemical group 0.000 claims 1
- 125000006374 C2-C10 alkenyl group Chemical group 0.000 claims 1
- 125000005865 C2-C10alkynyl group Chemical group 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical group FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 125000001309 chloro group Chemical group Cl* 0.000 claims 1
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical group C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 claims 1
- 229910052731 fluorine Inorganic materials 0.000 claims 1
- 239000011737 fluorine Chemical group 0.000 claims 1
- 125000005842 heteroatom Chemical group 0.000 claims 1
- 125000004433 nitrogen atom Chemical group N* 0.000 claims 1
- JVJQPDTXIALXOG-UHFFFAOYSA-N nitryl fluoride Chemical group [O-][N+](F)=O JVJQPDTXIALXOG-UHFFFAOYSA-N 0.000 claims 1
- 150000002894 organic compounds Chemical class 0.000 claims 1
- 239000003960 organic solvent Substances 0.000 claims 1
- 150000003014 phosphoric acid esters Chemical class 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/24—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing heterocyclic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/645—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having two nitrogen atoms as the only ring hetero atoms
- C07F9/6503—Five-membered rings
- C07F9/6506—Five-membered rings having the nitrogen atoms in positions 1 and 3
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6515—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having three nitrogen atoms as the only ring hetero atoms
- C07F9/6518—Five-membered rings
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (5)
- 하기식(Ⅱ)의 알코홀과 하기식(Ⅲ)의 포스포릴할라이드를 불활성 유기용매되는 희석제의 존재하 또는 부재하에서, -20°∼+150℃의 온도 범위하에 유기 또는 부기 염기 존재하에서 반응시키고, 생성된 유리화합물을 산부가염 또는 4차 아졸륨 또는 암모늄 또는 산부가염을 유리화합물, 그외의 산부가염, 4차 아졸륨 또는 암모늄으로 전환시키거나 생성된 유기화합물 또는 염을 금속 착물로 전화시키는 것으로 구성된 하기식(Ⅰ)의 인산 에스테르 또는 산부가염, 4차 아졸륨 또는 암모늄염 또는 그들이 금속착물의 제조방법.상기식에서, X 는 다리 원소 -CH=또는 -N= Ar은 페닐, 디페닐 또는 나프틸기 R R2와 R3는 각각 독자적으로 수소, 니트로, 할로겐 C1-C3알킬, C1-C3알콕시 또는 C1-C3할로알킬, R은 -COOR4, -COSR5,또는 -CN중의 1개R4는 치환되지 않았거나 할로겐으로 치환된 C2-C10알케닐 : 치환되지 않았거나 치환된 C2-C10알키닐 : 또는 할로겐, C1-C4알킬, C1-C4알콕시, -CN 또는 -CF3로 치환되었건 치환되지 않은 페닐기 또는 C3-C8시클로알킬기 : C2알킬부티가 산소 또는 황에 의하여 삽입된 그리고 할로겐, 페닐, -COO-C1-C4알킬-CO-C1-C4알킬, -C10-페닐, 헤테로원자로서 황 또는 산소를 함유하는 포화된 또는 불포화된 5-또는 6-원소의 고리로 치환되었거나 치환되지 않은 C1-C12알킬 사슬인데 각각의 페닐는 하나 또는 그 이상의 상이한 또는 같은 할로겐 원자로 치환되거나 되지 않는다.R5는 C1-C10알킬, 또는 페닐 또는 벤질기인데 각각은 할로겐 C1-C4알킬, C1-C4알콕시, -CN또는 -CF3로 치환되거나 치환되지 않는다.R6과 R7은 각각 독자적으로 수소, C1-C6알킬 C3-C7시클로알킬, 또는 페닐 또는 벤질기인데 각각의 방향족 고리는 할로겐, C1-C4알킬, C1-C4알콕시, -CN또는 -CF3로 치환되었거나 되지 않으며, R6과 R7중 1개는 또한 -N(R8)(R9)이거나 둘이 함께 1 또는 2개의 부가적 N-원자를 함유하는 포화되지 않은 또는 포화된 5-또는 6-원소의 헤테로 시클릭고리이다.R8과 R9는 각각 수소, C1-C4알킬 또는 페닐라디킬인데 할로겐, C1-C4알킬, -CN 또는 CF3로 치환되거나 되지 않는다.R10은 C1-C12알킬, R11은 -YR12, C1-C12알킬 또는 페닐, R12는 C1-C12알킬, Y은 산소 또는 황, Hal은 할로겐 원자.
- 제 1항에 있어서, 하기식(Ⅰ*)화합물의 또는 농업적으로 적당한 산부가염, 4차 아졸륨 또는 암모늄 또는 그들의 금속착물의 제조방법.상기식에서, X, 다리원소 -CH=또는 -N=1 Ar은 페닐, 디페닐 또는 나프틸기, R1, R2와 R3는 각각 독자적으로 수소, 니트로, 할로겐, C1-C3알킬, C1-C3알콕시 또는 C1-C3할로 알킬 R4는 C1-C4알킬, 페닐 또는 1개 또는 그 이상의 니트로기, 할로겐 원자 및 혹은 메틸기로 치환된 벤질 똔느 페닐, R10은 C1-C6알킬 R11은 -YR12, C1-C6알킬 또는 페닐, R12는 C1-C6알킬, Y는 산소 또는 황.
- 제 1항에 있어서, X가 다리원소 -CH= 또는 -N=; Ar이 페닐기, 오르토-위치의 R1은 수소, 니트로, 할로겐, C1-C3알킬, C1-C3알콕시, C1-C3할로알킬, 파라-위치의 R2는 수소 니트로, 할로겐, C1-C3알킬, C1-C3알콕시 또는 C1-C3할로알킬 : R3은 수소, 메틸 또는 할로겐 : R은 -COOR4, COSR5, -CON,-CN R4는 -C1-C4알킬, 페닐 또는 1개 또는 그 이상의 니트로기, 할로겐원자 및/ 혹은 메틸기로 치환된 페닐 또는 벤질.R5 는 C 1-C10알킬 또는 할로겐, C1 -C 4알킬 C1 -C 4 알콕시, -CN, -CF 3 로 치환되었거나 치환되지않은 벤질 또는 페닐, R 6 과 R 7 은 각각이 수소, C 1 -C 3 알킬, C 3 -C 7 시클로알킬, 페닐 또는 벤질, R 10 은 C 1 -C 4 알킬 R 11 은 -YR 12 , C 1 -C 4 알킬 또는 페닐 R 12 는 C 1 -C 4 알킬 Y는 산소 또는 황인식(Ⅰ)의 화합물 또는 산부가염, 4차 아졸륨 또는 암모늄염 또는 그들의 금속착물의 제조방법.
- 제 3항에 있어서, X가 다리원소은 오르포-및/ 혹은 파라-위치가 니트로, 불소, 염소, 브롬, 메틸 메톡시 및 혹은 CF3로 치환된 페닐기, R은 -COOR4R4는 C1-C4알킬, 페닐 또는 니트로, 염소, 브롬, 불소 및-혹은 메틸로 치환된 벤질 또는 페닐, R10은 C1-C4알킬, R11은 -YR12, C-C4알킬 또는 페닐 R12는 C1-C4알킬, Y는 산소 또는 황인식(Ⅰ)의 화합물 또는 산부가염, 4차 아졸륨 또는 암모늄염 또는 금속착물의 제조방법.
- 제 4항에 있어서, 하기의 화합물 4.3, 1.19, 1.12, 1.51로 구성된 군에서 선택된 식(Ⅰ) 화합물의 제조방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH6021/82-2 | 1982-10-15 | ||
CH602182 | 1982-10-15 |
Publications (1)
Publication Number | Publication Date |
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KR840006491A true KR840006491A (ko) | 1984-11-30 |
Family
ID=4302935
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019830004891A KR840006491A (ko) | 1982-10-15 | 1983-10-15 | 인산에스테르 조성물 및 그 제조 방법 |
Country Status (8)
Country | Link |
---|---|
US (1) | US4528284A (ko) |
EP (1) | EP0106807B1 (ko) |
JP (1) | JPS5989696A (ko) |
KR (1) | KR840006491A (ko) |
DE (1) | DE3363599D1 (ko) |
ES (1) | ES526462A0 (ko) |
GB (1) | GB2128193B (ko) |
PH (1) | PH20735A (ko) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9602080D0 (en) * | 1996-02-02 | 1996-04-03 | Pfizer Ltd | Pharmaceutical compounds |
JP3196747B2 (ja) * | 1998-12-18 | 2001-08-06 | 三菱マテリアル株式会社 | 移動無線機、基地局無線機、及び、その記録媒体 |
JP4644750B1 (ja) * | 2010-04-23 | 2011-03-02 | 一 小金 | 溶接治具及びそれを用いた溶接方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3046329A1 (de) * | 1980-12-09 | 1982-07-15 | Hoechst Ag, 6000 Frankfurt | "derivate des 1,2,4-triazols und imidazols, verfahren zu ihrer herstellung und ihre verwendung als schaedlingsbekaempfungsmittel" |
DE3046309A1 (de) * | 1980-12-09 | 1982-07-08 | Volkswagenwerk Ag, 3180 Wolfsburg | Massenausgleichseinrichtung |
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1983
- 1983-10-05 US US06/539,217 patent/US4528284A/en not_active Expired - Fee Related
- 1983-10-10 DE DE8383810470T patent/DE3363599D1/de not_active Expired
- 1983-10-10 EP EP83810470A patent/EP0106807B1/de not_active Expired
- 1983-10-11 GB GB08327110A patent/GB2128193B/en not_active Expired
- 1983-10-14 ES ES526462A patent/ES526462A0/es active Granted
- 1983-10-15 JP JP58193332A patent/JPS5989696A/ja active Pending
- 1983-10-15 KR KR1019830004891A patent/KR840006491A/ko not_active Application Discontinuation
- 1983-10-17 PH PH29707A patent/PH20735A/en unknown
Also Published As
Publication number | Publication date |
---|---|
ES8505172A1 (es) | 1985-05-16 |
GB8327110D0 (en) | 1983-11-09 |
GB2128193B (en) | 1986-06-11 |
JPS5989696A (ja) | 1984-05-23 |
US4528284A (en) | 1985-07-09 |
DE3363599D1 (en) | 1986-06-26 |
EP0106807A1 (de) | 1984-04-25 |
GB2128193A (en) | 1984-04-26 |
PH20735A (en) | 1987-04-02 |
ES526462A0 (es) | 1985-05-16 |
EP0106807B1 (de) | 1986-05-21 |
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