KR840002858A - 피바로락톤을 기초로 한 브럭 공중합체 및 이들의 제조방법 - Google Patents
피바로락톤을 기초로 한 브럭 공중합체 및 이들의 제조방법 Download PDFInfo
- Publication number
- KR840002858A KR840002858A KR1019820005810A KR820005810A KR840002858A KR 840002858 A KR840002858 A KR 840002858A KR 1019820005810 A KR1019820005810 A KR 1019820005810A KR 820005810 A KR820005810 A KR 820005810A KR 840002858 A KR840002858 A KR 840002858A
- Authority
- KR
- South Korea
- Prior art keywords
- process according
- carried out
- moiety
- aromatic
- temperature range
- Prior art date
Links
- 229920001400 block copolymer Polymers 0.000 title claims 5
- 238000002360 preparation method Methods 0.000 title 1
- 238000000034 method Methods 0.000 claims 16
- 229920000642 polymer Polymers 0.000 claims 5
- -1 isopropenyl aromatic compound Chemical class 0.000 claims 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 3
- 125000000217 alkyl group Chemical group 0.000 claims 3
- 125000003118 aryl group Chemical group 0.000 claims 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 3
- 229920002554 vinyl polymer Polymers 0.000 claims 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims 2
- 238000010306 acid treatment Methods 0.000 claims 2
- 125000001931 aliphatic group Chemical group 0.000 claims 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 2
- 150000001340 alkali metals Chemical class 0.000 claims 2
- 150000001408 amides Chemical class 0.000 claims 2
- 239000003125 aqueous solvent Substances 0.000 claims 2
- 125000002897 diene group Chemical group 0.000 claims 2
- 238000007306 functionalization reaction Methods 0.000 claims 2
- 150000004678 hydrides Chemical class 0.000 claims 2
- 239000000178 monomer Substances 0.000 claims 2
- 239000002904 solvent Substances 0.000 claims 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 2
- BOGRNZQRTNVZCZ-AATRIKPKSA-N (3e)-3-methylpenta-1,3-diene Chemical compound C\C=C(/C)C=C BOGRNZQRTNVZCZ-AATRIKPKSA-N 0.000 claims 1
- AHAREKHAZNPPMI-AATRIKPKSA-N (3e)-hexa-1,3-diene Chemical compound CC\C=C\C=C AHAREKHAZNPPMI-AATRIKPKSA-N 0.000 claims 1
- BOGRNZQRTNVZCZ-UHFFFAOYSA-N 1,2-dimethyl-butadiene Natural products CC=C(C)C=C BOGRNZQRTNVZCZ-UHFFFAOYSA-N 0.000 claims 1
- XIRPMPKSZHNMST-UHFFFAOYSA-N 1-ethenyl-2-phenylbenzene Chemical group C=CC1=CC=CC=C1C1=CC=CC=C1 XIRPMPKSZHNMST-UHFFFAOYSA-N 0.000 claims 1
- UGWOAPBVIGCNOV-UHFFFAOYSA-N 5-ethenyldec-5-ene Chemical compound CCCCC=C(C=C)CCCC UGWOAPBVIGCNOV-UHFFFAOYSA-N 0.000 claims 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 1
- 239000001569 carbon dioxide Substances 0.000 claims 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
- 150000001993 dienes Chemical class 0.000 claims 1
- 239000003999 initiator Substances 0.000 claims 1
- 125000000555 isopropenyl group Chemical group [H]\C([H])=C(\*)C([H])([H])[H] 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000003505 polymerization initiator Substances 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 150000005621 tetraalkylammonium salts Chemical class 0.000 claims 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims 1
- 230000007704 transition Effects 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerization Catalysts (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (24)
- Ax는 방향족을 폴리비닐이나 폴리이소프로페닐이고 By는 디엔 부분 또는 수소화된 것이며, Cz는 폴리피바로락톤 부분으로서 식중 x,y,z는 각 부분내 단량체 단위를 나타내는 정수이고 140℃나 그 이상인 Ax부분의 전이온도를 갖는 AxByC|z형태의 브럭 공중합체.
- Ax부분이 비닐이나 이소프로페닐 방향족 화합물이 알파메틸스티렌, 비닐비페닐, 이소프로페닐, 비페닐비닐나프타렌 및 이소프로페닐나프타렌으로부터 선택한 청구범위 1에 따른 브럭 공중 합체.
- By부분의 디엔 화합물이 1,3-부티디엔, 이소프렌, 2,3-디메틸,-1,3-부타디엔, 3-메틸-1,3-펜타디엔, 1,3-헥사디엔, 2-메틸-1,3-헥사디엔 및 3-부틸-1,3-옥타디엔으로 부터 선택한 청구범위 1에 따른 브럭 공중합체.
- 디엔부분이 수소화된 청구범위 1에 따른 브럭 공중합체.
- a) 비닐 또는 이소프로페닐 방향족 단향체의 중합. b) a) 단계에서 얻은 생성물에 디엔의 첨가 c) 처음이 리빙 AB중합체를 이산화탄소와 반응시킨 다음 산처리에 의하여 카르복실기능을 유리시킴에 의하여 b) 단계에서 얻은 리빙 AB 중합체를 카르복실기로 기능화 d) c) 단계에서 얻은 중합체에 피바로락톤의 첨가하는 단계들로 구성된 청구범위 1과 4에 따른 중합합체의 제조방법.
- a) 단계가 지방족, 환상 지방적, 방향족 및 알킬 방향족, 극성, 비수 용매의 존재하에 실시되는 청구범위 5에 따른 방법.
- a) 단계가 알카리 금속의 알킬, 하이드라이드나 아미드로 구성된 시발제의 존재하에 실시되는 청구범위 5에 따른 방법.
- 중합 시발제가 특히 Li-sec. 부틸인 청구범위 7에 따른 방법.
- a) 단계가 -80℃ -150℃의 온도범위에서 실시되는 청구범위 5에 따른 방법.
- 온도범위가 특히 -30℃ -+80℃인 청구범위 9에 따른 방법.
- b)단계가 지방족, 환상지방족, 방향족 및 알킬방향족, 극성 비수용매의 존재하에 실시되는 청구범위 5에 따른 방법.
- b) 단계가 알카리 금속의 알킬, 하이드라이드나 아미드의 존재하에 실시되는 청구범위 5에 따른 방법.
- b) 단계가 -50℃-+150℃의 온도범위에서 실시될 수 있는 청구범위 5항에 따른 방법.
- 온도범위가 0℃-+60℃에서 완전히 상승되는 청구범위 13항에 따른 방법.
- 카르복실기를 가진 AB중합체의 기능화인 c) 단계가 포화된 이산화탄소용액을 가지고 실시될 수 있는 청구범위 5항에 따른 방법.
- 용매가 알파틱 또는 시이클로 아파틱 용매로부터 완전히 추출될 수 있는 청구범위 15항에 따른 방법.
- 단계 c)가 실시온도 -50℃ -+20℃사이에서 상승될 수 있는 청구범위 5항에 따른 방법.
- 실시온도가 -5℃ -+5℃사이에서 완전히 상승될 수 있는 청구범위 17항에 따른 방법.
- 단계 c)가 카르복실기능 산처리에 의해 유리되는 청구범위 5항에 따른 방법.
- 단계 d)가 토루엔과 테트라하이드로푸란의 혼합에 따라 형성된 청구범위 5항에 따른 방법.
- 단계 d)가 하기 일반식을 가진 테트라알킬암모니움 염의 존재하에 형성된 청구범위 5항에 따른 방법.
-
- 각각으로부터 같거나 다른및는 1-8탄소원자로 부터 포함하는 알킬 연쇄임.
- ※참고사항:최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT25754/81A IT1196420B (it) | 1981-12-22 | 1981-12-22 | Copolimeri a blocchi a base di pivalolattone e processo per la loro preparazione |
| IT25754A/81 | 1981-12-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR840002858A true KR840002858A (ko) | 1984-07-21 |
Family
ID=11217638
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019820005810A KR840002858A (ko) | 1981-12-22 | 1982-12-24 | 피바로락톤을 기초로 한 브럭 공중합체 및 이들의 제조방법 |
Country Status (13)
| Country | Link |
|---|---|
| JP (1) | JPS58111816A (ko) |
| KR (1) | KR840002858A (ko) |
| AU (1) | AU9167182A (ko) |
| BE (1) | BE895447A (ko) |
| BR (1) | BR8207524A (ko) |
| CA (1) | CA1203336A (ko) |
| DE (1) | DE3247277C2 (ko) |
| ES (1) | ES518856A0 (ko) |
| FR (1) | FR2522668B1 (ko) |
| GB (1) | GB2112002B (ko) |
| IT (1) | IT1196420B (ko) |
| NL (1) | NL8204908A (ko) |
| ZA (1) | ZA829300B (ko) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1194408B (it) * | 1983-09-28 | 1988-09-22 | Anic Spa | Processo per la sintesi di copolimeri a blocchi a base di pivalolattone |
| GB8333697D0 (en) * | 1983-12-17 | 1984-01-25 | Exxon Research Engineering Co | Hydrocarbon resins |
| US4674030A (en) * | 1984-01-24 | 1987-06-16 | Bijur Lubricating Corp. | Lubricating system control circuit |
| JP2617908B2 (ja) * | 1984-09-27 | 1997-06-11 | 松下電器産業株式会社 | 投写光学装置 |
| JPH0627895B2 (ja) * | 1984-12-20 | 1994-04-13 | 松下電器産業株式会社 | 投写レンズ |
| JPH0627896B2 (ja) * | 1985-02-06 | 1994-04-13 | 松下電器産業株式会社 | 投写レンズ |
| JPH065322B2 (ja) * | 1988-03-23 | 1994-01-19 | 呉羽化学工業株式会社 | 光学材料の製造方法 |
| US5015695A (en) * | 1989-05-09 | 1991-05-14 | Shell Oil Company | Functionalized elastomeric polymer production |
| US4978719A (en) * | 1989-05-09 | 1990-12-18 | Shell Oil Company | Functionalized elastomeric polymers |
| JP2999250B2 (ja) * | 1990-11-30 | 2000-01-17 | 呉羽化学工業株式会社 | 新規なグラフト共重合体 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3557252A (en) * | 1969-01-17 | 1971-01-19 | Phillips Petroleum Co | Poly(vinyl halide) compositions |
| US3557255A (en) * | 1969-03-21 | 1971-01-19 | Du Pont | Pivalolactone-diene block copolymers and their preparation |
| US4034021A (en) * | 1973-11-06 | 1977-07-05 | E. I. Du Pont De Nemours And Company | Copolymers of pivalolactone and isoprene or butadiene |
-
1981
- 1981-12-22 IT IT25754/81A patent/IT1196420B/it active
-
1982
- 1982-12-17 ZA ZA829300A patent/ZA829300B/xx unknown
- 1982-12-20 AU AU91671/82A patent/AU9167182A/en not_active Abandoned
- 1982-12-20 GB GB08236144A patent/GB2112002B/en not_active Expired
- 1982-12-20 NL NL8204908A patent/NL8204908A/nl not_active Application Discontinuation
- 1982-12-21 BR BR8207524A patent/BR8207524A/pt unknown
- 1982-12-21 CA CA000418175A patent/CA1203336A/en not_active Expired
- 1982-12-21 DE DE3247277A patent/DE3247277C2/de not_active Expired
- 1982-12-21 FR FR8221465A patent/FR2522668B1/fr not_active Expired
- 1982-12-22 JP JP57225778A patent/JPS58111816A/ja active Pending
- 1982-12-22 ES ES518856A patent/ES518856A0/es active Granted
- 1982-12-22 BE BE0/209790A patent/BE895447A/fr not_active IP Right Cessation
- 1982-12-24 KR KR1019820005810A patent/KR840002858A/ko unknown
Also Published As
| Publication number | Publication date |
|---|---|
| IT1196420B (it) | 1988-11-16 |
| DE3247277A1 (de) | 1983-06-30 |
| FR2522668A1 (fr) | 1983-09-09 |
| ES8402599A1 (es) | 1984-02-01 |
| AU9167182A (en) | 1983-06-30 |
| DE3247277C2 (de) | 1986-09-04 |
| NL8204908A (nl) | 1983-07-18 |
| IT8125754A0 (it) | 1981-12-22 |
| BE895447A (fr) | 1983-06-22 |
| GB2112002B (en) | 1986-03-05 |
| JPS58111816A (ja) | 1983-07-04 |
| BR8207524A (pt) | 1983-10-25 |
| ES518856A0 (es) | 1984-02-01 |
| CA1203336A (en) | 1986-04-15 |
| ZA829300B (en) | 1983-11-30 |
| FR2522668B1 (fr) | 1986-11-21 |
| GB2112002A (en) | 1983-07-13 |
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